Carboxamide: based chemosensor grafted on SBA-15 nanostructure for selective detection of Hg2+ ion in an aqueous solution
Source abstract
Abstract
A new adeninecarboxamide ligand, N-(9 H-purin-6-yl) pyridine-2-carboxamide (H2pzac) has been synthesized by a green chemistry method using tetrabutylammunium bromide (TBAB) ionic liquid as an environmentally friendly reaction medium. The H2pzac ligand was anchored on modified SBA-15-Cl and utilized for detection of Hg2+ in aqueous solution. The as-constructed SBA-15@Hpzac sensor shows a high specific surface area as well as pore volume of 250 m2/g and 0.54 cm3/g, respectively. The fluorescence assessment indicated that the designed SBA-15@Hpzac sensor presented highly sensitive and selective behavior to Hg2+ ion over different cations including Zn2+, Ni2+, Co2+, Cu2+, Mn2+, Pb2+, Ba2+, Mg2+, Ca2+, Na+, Fe3+, Fe2+, Al3+, Cd2+ and K+. The fluorescence response of the SBA-15@Hpzac sensor for selective detection of Hg2+ ion is excellent with detection limit (LOD) of 1.07 × 10− 6 M. The application of the SBA-15@Hpzac sensor in determination of Hg2+ ions in two real water samples was also investigated.
Source: expertdata · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Molecular Sensors and Ion Detection · Electrochemical Analysis and Applications · Luminescence and Fluorescent Materials
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (39)
Show source-provided references
1. A. Badiei, B.V. Razavi, H. Goldooz et al., A novel fluorescent chemosensor assembled with 2,6-bis(2-benzimidazolyl)pyridine-functionalized nanoporous silica-type SBA-15 for recognition of Hg2+ ion in aqueous media. Int. J. Environ. Res. 12, 109–115 (2018). https://doi.org/10.1007/s41742-018-0075-110.1007/s41742-018-0075-1 ↗
2. J. Wang, X. Zhang, H.B. Liu et al., Aggregation induced emission active fluorescent sensor for the sensitive detection of Hg2+ based on organic–inorganic hybrid mesoporous material. Spectrochim. Acta Part A Mol. Biomol. Spectrosc. 227, 117585 (2020). https://doi.org/10.1016/j.saa.2019.11758510.1016/j.saa.2019.117585 ↗
3. E.F. Aboelfetoh, M.E. Zain Elabedien, E.Z.M. Ebeid, Effective treatment of industrial wastewater applying SBA-15 mesoporous silica modified with graphene oxide and hematite nanoparticles. J. Environ. Chem. Eng. 9, 104817 (2021). https://doi.org/10.1016/j.jece.2020.10481710.1016/j.jece.2020.104817 ↗
4. A. Shahat, S. Trupp, Sensitive, selective, and rapid method for optical recognition of ultra-traces level of hg(II), ag(I), au(III), and pd(II) in electronic wastes. Sens. Actuators B Chem. 245, 789–802 (2017). https://doi.org/10.1016/j.snb.2017.02.00810.1016/j.snb.2017.02.008 ↗
5. A. Shahat, S.A. Elsalam, J.M. Herrero-Martínez et al., Optical recognition and removal of hg(II) using a new self-chemosensor based on a modified amino-functionalized Al-MOF. Sens. Actuators B Chem. 253, 164–172 (2017). https://doi.org/10.1016/j.snb.2017.06.12510.1016/j.snb.2017.06.125 ↗
6. E.G. Pacyna, J.M. Pacyna, K. Sundseth et al., Global emission of mercury to the atmosphere from anthropogenic sources in 2005 and projections to 2020. Atmos. Environ. 44, 2487–2499 (2010). https://doi.org/10.1016/j.atmosenv.2009.06.00910.1016/j.atmosenv.2009.06.009 ↗
7. W. Abd El-Fattah, E.S. Al-Farraj, N. Hamadi, Ben et al., Functionalized MOF as a sensitive spectroscopic probe for Hg2+, Co2+, and Al3+ ions detection in aqueous media. ACS Omega 7, 17483–17491 (2022). https://doi.org/10.1021/ACSOMEGA.2C02021/ASSET10.1021/ACSOMEGA.2C02021/ASSET ↗
8. M.A. El-Bindarya, A. Shahat, I.M. El-Deen et al., Dual colorimetric and fluorometric monitoring of Cd2+ and Hg2+ ions in water using functionalized Zrmetal–organic frameworks chemosensors. Appl. Organomet. Chem. 37, e7070 (2023). https://doi.org/10.1002/AOC.707010.1002/AOC.7070 ↗
9. A. Radwan, I.M. El-Sewify, A. Shahat et al., Multiuse Al-MOF chemosensors for visual detection and removal of mercury ions in water and skin-whitening cosmetics. ACS Sustain. Chem. Eng. 8, 15097–15107 (2020). https://doi.org/10.1021/ACSSUSCHEMENG.0C03592/SUPPL_FILE/SC0C03592_SI_001.PDF10.1021/ACSSUSCHEMENG.0C03592/SUPPL_FILE/SC0C03592_SI_001.PDF ↗
10. X. He, J. Zhang, X. Liu et al., A novel BODIPY-based colorimetric and fluorometric dual-mode chemosensor for Hg2+ and Cu2+. Sens. Actuators B Chem. 192, 29–35 (2014). https://doi.org/10.1016/j.snb.2013.10.09310.1016/j.snb.2013.10.093 ↗
11. F. Shemirani, S.D. Abkenar, A. Khatouni, Determination of trace amounts of lead and copper in water samples by flame atomic absorption spectrometry after cloud point extraction. Bull. Korean Chem. Soc. 25, 1133–1136 (2004). https://doi.org/10.5012/bkcs.2004.25.8.113310.5012/bkcs.2004.25.8.1133 ↗
12. C. Detection, Determination of subnanomolar levels of iron. Society 63, 893–898 (1991)
13. P.L. Croot, M. Johansson, Determination of iron speciation by cathodic stripping voltammetry in seawater using the competing ligand 2-(2-thiazolylazo)-p-cresol (TAC). Electroanalysis 12, 565–576 (2000)10.1002/(SICI)1521-4109(200005)12:8<565::AID-ELAN565>3.0.CO;2-L ↗
14. N. Lashgari, A. Badiei, G. Mohammadi Ziarani, A novel functionalized nanoporous SBA-15 as a selective fluorescent sensor for the detection of multianalytes (Fe3+ and Cr2O72–) in water. J. Phys. Chem. Solids. 103, 238–248 (2017). https://doi.org/10.1016/j.jpcs.2016.11.02110.1016/j.jpcs.2016.11.021 ↗
15. C. Wang, F. Shang, X. Yu et al., Synthesis of bifunctional catalysts Al-SBA-15-NH2 with high aluminum content and the catalytic application for different one-pot reactions. Appl. Surf. Sci. 258, 6846–6852 (2012). https://doi.org/10.1016/j.apsusc.2012.03.11710.1016/j.apsusc.2012.03.117 ↗
16. A. Shakeri, R. Razavi, H. Salehi et al., Thin film nanocomposite forward osmosis membrane embedded with amine-functionalized ordered mesoporous silica. Appl. Surf. Sci. 481, 811–818 (2019). https://doi.org/10.1016/J.APSUSC.2019.03.04010.1016/J.APSUSC.2019.03.040 ↗
17. T. Das, D. Singha, A. Pal, M. Nandi, Mesoporous silica based recyclable probe for colorimetric detection and separation of ppb level Hg2+ from aqueous medium. Sci. Rep. 9, 1–11 (2019). https://doi.org/10.1038/s41598-019-55910-410.1038/s41598-019-55910-4 ↗
18. S. Masoudnia, M.H. Juybari, R.Z. Mehrabian et al., Efficient dye removal from wastewater by functionalized macromolecule chitosan-SBA-15 nanofibers for biological approaches. Int. J. Biol. Macromol. 165, 118–130 (2020). https://doi.org/10.1016/j.ijbiomac.2020.09.15810.1016/j.ijbiomac.2020.09.158 ↗
19. S.W. Song, K. Hidajat, S. Kawi, Functionalized SBA-15 materials as carriers for controlled drug delivery: influence of surface properties on matrix-drug interactions. Langmuir. 21, 9568–9575 (2005). https://doi.org/10.1021/la051167e10.1021/la051167e ↗
20. X. Wang, K.S.K. Lin, J.C.C. Chan, S. Cheng, Direct synthesis and catalytic applications of ordered large pore aminopropyl-functionalized SBA-15 mesoporous materials. J. Phys. Chem. B 109, 1763–1769 (2005). https://doi.org/10.1021/jp045798d10.1021/jp045798d ↗
21. L. Paul, S. Mukherjee, S. Chatterjee et al., Organically functionalized mesoporous SBA-15 type material bearing fluorescent sites for selective detection of HgII from aqueous medium. ACS Omega 4, 17857–17863 (2019). https://doi.org/10.1021/acsomega.9b0263110.1021/acsomega.9b02631 ↗
22. S. Meghdadi, M. Amirnasr, A. Amiri et al., Benign synthesis of N-(8-quinolyl)pyridine-2-carboxamide) ligand (Hbpq), and its Ni (II) and Cu (II) complexes. A fluorescent probe for direct detection of nitric oxide in acetonitrile solution based on Hbpq copper(II) acetate interaction. Comptes. Rendus Chim. 17, 477–483 (2014). https://doi.org/10.1016/j.crci.2013.10.00310.1016/j.crci.2013.10.003 ↗
23. G. Mohammadi, F. Mohajer, A. Badiei, Synthesis of SBA-Pr-NHC as a selective fluorescent sensor for the detection of ag + ion in aqueous media. Spectrochim. Acta Part A Mol. Biomol. Spectrosc. 267, 120580 (2022). https://doi.org/10.1016/j.saa.2021.12058010.1016/j.saa.2021.120580 ↗
24. G. Mohammadi Ziarani, R. Moradi, F. Mohajer, A. Badiei, 2-Chloroquinoline-3-carbaldehyde modified nanoporous SBA-15-propylamine (SBA-Pr-NCQ) as a selective and sensitive ag + ion sensor in aqueous media. J. Phys. Chem. Solids. 161, 110399 (2022). https://doi.org/10.1016/j.jpcs.2021.11039910.1016/j.jpcs.2021.110399 ↗
25. L. Zhao, J. Li, D. Sui, Y. Wang, Highly selective fluorescence chemosensors based on functionalized SBA-15 for detection of ag + in aqueous media. Sens. Actuators B Chem. 242, 1043–1049 (2017). https://doi.org/10.1016/j.snb.2016.09.14810.1016/j.snb.2016.09.148 ↗
26. G. Mohammadi Ziarani, S. Roshankar, F. Mohajer et al., The synthesis of SBA–Pr–N-Is–Bu–SO3H as a new Hg2+ fluorescent sensor. Inorg. Chem. Commun. (2022). https://doi.org/10.1016/j.inoche.2022.11010010.1016/j.inoche.2022.110100 ↗
27. X. Sun, W. Yu, J. Yan et al., Mesoporous silica-carbon composites fabricated by a universal strategy of hydrothermal carbonization: controllable synthesis and applications. RSC Adv. 8, 27207–27215 (2018). https://doi.org/10.1039/c8ra04641g10.1039/c8ra04641g ↗
28. Z. Dong, Z. Dong, J. Ren et al., A quinoline group modified SBA-15 INHIBIT logic gate with [Cu2+ and Zn2+] or [Cu2+ and Cd2+] as inputs. Microporous Mesoporous Mater. 135, 170–177 (2010). https://doi.org/10.1016/j.micromeso.2010.07.00610.1016/j.micromeso.2010.07.006 ↗
29. M. Jafari, A. Amiri, A. Badiei, A. Shayesteh, Fluorene-functionalized, dendrimer-modified SBA-15: detection of iron(III) and mercury (II) in aqueous media and logic gate studies. ChemistrySelect 4, 12559–12568 (2019). https://doi.org/10.1002/slct.20190197410.1002/slct.201901974 ↗
30. F. Zhang, Y. Yan, H. Yang et al., Understanding effect of wall structure on the hydrothermal stability of mesostructured silica SBA-15. J. Phys. Chem. B 109, 8723–8732 (2005). https://doi.org/10.1021/jp044632+10.1021/jp044632+ ↗
31. R.M. Melavanki, R.A. Kusanur, J.S. Kadadevaramath, M.V. Kulakarni, Quenching mechanisms of 5BAMC by aniline in different solvents using Stern–Volmer plots. J. Lumin. 129, 1298–1303 (2009). https://doi.org/10.1016/j.jlumin.2009.06.01110.1016/j.jlumin.2009.06.011 ↗
32. V. Srinivasan, M.A. Jhonsi, N. Dhenadhayalan et al., Pyrene-based prospective biomaterial: in vitro bioimaging, protein binding studies and detection of bilirubin and Fe3+. Spectrochim. Acta Part A Mol. Biomol. Spectrosc. 221, 117150 (2019). https://doi.org/10.1016/j.saa.2019.11715010.1016/j.saa.2019.117150 ↗
33. Z. Sun, G. Cui, H. Li et al., Multifunctional optical sensing probes based on organic-inorganic hybrid composites. J. Mater. Chem. B 4, 5194–5216 (2016). https://doi.org/10.1039/c6tb01468b10.1039/c6tb01468b ↗
34. Z. Sun, D. Guo, L. Zhang et al., Multifunctional fibrous silica composite with high optical sensing performance and effective removal ability toward Hg2+ ions. J. Mater. Chem. B 3, 3201–3210 (2015). https://doi.org/10.1039/c5tb00038f10.1039/c5tb00038f ↗
35. J.Y. Choi, W. Kim, J. Yoon, Rhodamine based fluorescent chemosensors for Hg2+ and its biological application. Bull. Korean Chem. Soc. 33, 2359–2364 (2012). https://doi.org/10.5012/bkcs.2012.33.7.235910.5012/bkcs.2012.33.7.2359 ↗
36. R. Martínez, A. Espinosa, A. Tárraga, P. Molina, A new bis(pyrenyl)azadiene-based probe for the colorimetric and fluorescent sensing of Cu(II) and hg(II). Tetrahedron. 66, 3662–3667 (2010). https://doi.org/10.1016/J.TET.2010.03.08010.1016/J.TET.2010.03.080 ↗
37. J. Weng, Q. Mei, Q. Ling et al., A new colorimetric and fluorescent ratiometric sensor for Hg2+ based on 4-pyren-1-yl-pyrimidine. Tetrahedron 68, 3129–3134 (2012). https://doi.org/10.1016/J.TET.2011.12.07110.1016/J.TET.2011.12.071 ↗
38. A. Caballero, R. Martínez, V. Lloveras et al., Highly selective chromogenic and redox or fluorescent sensors of Hg2+ in aqueous environment based on 1,4-disubstituted azines. J. Am. Chem. Soc. 127, 15666–15667 (2005). https://doi.org/10.1021/JA0545766/SUPPL_FILE/JA0545766SI20050907_042900.PDF10.1021/JA0545766/SUPPL_FILE/JA0545766SI20050907_042900.PDF ↗
39. N. Lashgari, A. Badiei, G. Mohammadi Ziarani, F. Faridbod, Isatin functionalized nanoporous SBA-15 as a selective fluorescent probe for the detection of Hg(II) in water. Anal. Bioanal. Chem. 409, 3175–3185 (2017). https://doi.org/10.1007/s00216-017-0258-110.1007/s00216-017-0258-1 ↗