Seeds-assisted synthesis of Zr-based metal-organic framework (MIP-202) for efficient adsorption separation of CO2/CH4 and CO2/N2
Source abstract
Abstract
Nanoscale Zr-based metal-organic framework (MIP-202) particles were successfully prepared via a seeds-assisted hydrothermal secondary synthesis. The uniformly-shaped MIP-202 particles exhibit excellent performance on selective CO2 adsorption from CO2/CH4 and CO2/N2 mixtures. At 298 K and 1 bar, the uptake ratios of CO2/CH4 and CO2/N2 of MIP-202 particles are as high as 32.6 and 65.2, respectively. The IAST (ideal adsorbed solution theory)-predicted selectivities of CO2/N2 (50/50, v/v) and CO2/CH4 (50/50, v/v) reach to 4.5 × 1010 and 102.2, respectively. The breakthrough experiments further demonstrate that the CO2/CH4 and CO2/N2 mixtures can be efficiently separated through an adsorption column packed with MIP-202 particles. In addition, the as-prepared MIP-202 particles had a low iso-enthalpy of adsorption of CO2 of 32.95 kJ/mol, which is favorable for the regeneration of the adsorbent. Herein the as-prepared MIP-202 is a potential material for efficient separation of CO2 from CH4 or N2 through an energy- and cost-saving CO2 capture process.
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Research context
OpenAlex topics: Metal-Organic Frameworks: Synthesis and Applications · Carbon Dioxide Capture Technologies · Membrane Separation and Gas Transport
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
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