journal article·2021-06Open access

Viscose‐based porous carbon fibers: improving yield and porosity through optimization of the carbonization process by design of experiment

Stefan Breitenbach, Christoph Unterweger, Alexander Lumetzberger, Jiri Duchoslav, David Stifter, Achim Walter Hassel, Christian Fürst

Journal of Porous Materials· Volume 28· Issue 3

Abstract

Abstract In this study, the production of porous carbon fibers from viscose fibers was investigated. The effects of final carbonization temperature (600–1000 °C) and heating rate (6–600 °C h−1), which determine the carbonization process, on carbon yield, and specific surface area were investigated using a central composite design. The statistical models found were then used to optimize both the yield and the porosity of the carbonized fibers, which are the most important factors for further use as precursors for activated carbon fibers. Despite the contrary effects, porous carbon fibers with a yield of 21.2% could be produced, which at the same time have a specific surface area of 175 m2 g−1. The fibers produced were also characterized by SEM, FTIR and Raman spectroscopy, XRD and CHNS analysis.
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Research context

OpenAlex topics: Supercapacitor Materials and Fabrication · Fiber-reinforced polymer composites · biodegradable polymer synthesis and properties

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References (64)

Show source-provided references
1. D. Klemm, B. Heublein, H.-P. Fink, A. Bohn, Cellulose: fascinating biopolymer and sustainable raw material. Angew. Chem. 44, 3358–3393 (2005). https://doi.org/10.1016/10.1002/anie.200460587 (International edition in English)10.1016/10.1002/anie.200460587 ↗
2. L. Li, M. Frey, K.J. Browning, Biodegradability study on cotton and polyester fabrics. J. Eng. Fibers Fabr. 5, 155892501000500 (2018). https://doi.org/10.1016/10.1177/15589250100050040610.1016/10.1177/155892501000500406 ↗
3. E. Frank, L.M. Steudle, D. Ingildeev, J.M. Spörl, M.R. Buchmeiser, Carbon fibers: precursor systems, processing, structure, and properties. Angew. Chem. 53, 5262–5298 (2014). https://doi.org/10.1016/10.1002/anie.201306129 (International edition in English)10.1016/10.1002/anie.201306129 ↗
4. F.M. Hämmerle, The cellulose gap: the future of cellulose fibres. Lenzing. Ber. 89, 12–21 (2011)
5. S. Breitenbach, A. Lumetzberger, M.A. Hobisch, C. Unterweger, S. Spirk, D. Stifter, C. Fürst, A.W. Hassel, Supercapacitor electrodes from viscose-based activated carbon fibers: significant yield and performance improvement using diammonium hydrogen phosphate as impregnating agent. C 6, 17 (2020). https://doi.org/10.3390/c602001710.1016/10.3390/c6020017 ↗
6. Y. Wang, Y. Song, Y. Xia, Electrochemical capacitors: mechanism, materials, systems, characterization and applications. Chem. Soc. Rev. 45, 5925–5950 (2016). https://doi.org/10.1016/10.1039/c5cs00580a10.1016/10.1039/c5cs00580a ↗
7. P. Simon, Y. Gogotsi, Materials for electrochemical capacitors. Nat. Mater. 7, 845–854 (2008). https://doi.org/10.1016/10.1038/nmat229710.1016/10.1038/nmat2297 ↗
8. C. Liang, N.J. Dudney, J.Y. Howe, Hierarchically structured sulfur/carbon nanocomposite material for high-energy lithium battery. Chem. Mater. 21, 4724–4730 (2009). https://doi.org/10.1016/10.1021/cm902050j10.1016/10.1021/cm902050j ↗
9. S. Wei, H. Zhang, Y. Huang, W. Wang, Y. Xia, Z. Yu, Pig bone derived hierarchical porous carbon and its enhanced cycling performance of lithium–sulfur batteries. Energy Environ. Sci. 4, 736 (2011). https://doi.org/10.1016/10.1039/c0ee00505c10.1016/10.1039/c0ee00505c ↗
10. I. Mochida, Y. Korai, M. Shirahama, S. Kawano, T. Hada, Y. Seo, M. Yoshikawa, A. Yasutake, Removal of SOx and NOx over activated carbon fibers. Carbon 38, 227–239 (2000). https://doi.org/10.1016/10.1016/S0008-6223(99)00179-710.1016/10.1016/S0008-6223(99)00179-7 ↗
11. J.Y. Yoo, C.J. Park, K.Y. Kim, Y.-S. Son, C.-M. Kang, J.M. Wolfson, I.-H. Jung, S.-J. Lee, P. Koutrakis, Development of an activated carbon filter to remove NO2 and HONO in indoor air. J. Hazard. Mater. 289, 184–189 (2015). https://doi.org/10.1016/10.1016/j.jhazmat.2015.02.03810.1016/10.1016/j.jhazmat.2015.02.038 ↗
12. A. Takdastan, A.H. Mahvi, E.C. Lima, M. Shirmardi, A.A. Babaei, G. Goudarzi, A. Neisi, M. Heidari Farsani, M. Vosoughi, Preparation, characterization, and application of activated carbon from low-cost material for the adsorption of tetracycline antibiotic from aqueous solutions. Water Sci. Technol. J. Int. Assoc. Water Pollut. Res. 74, 2349–2363 (2016). https://doi.org/10.1016/10.2166/wst.2016.40210.1016/10.2166/wst.2016.402 ↗
13. Y. Chen, Y. Zhu, Z. Wang, Y. Li, L. Wang, L. Ding, X. Gao, Y. Ma, Y. Guo, Application studies of activated carbon derived from rice husks produced by chemical–thermal process—a review. Adv. Colloid Interface Sci. 163, 39–52 (2011). https://doi.org/10.1016/10.1016/j.cis.2011.01.00610.1016/10.1016/j.cis.2011.01.006 ↗
14. M. Sevilla, R. Mokaya, Energy storage applications of activated carbons: supercapacitors and hydrogen storage. Energy Environ. Sci. 7, 1250–1280 (2014). https://doi.org/10.1016/10.1039/C3EE43525C10.1016/10.1039/C3EE43525C ↗
15. F. Gao, D.-L. Zhao, Y. Li, X.-G. Li, Preparation and hydrogen storage of activated rayon-based carbon fibers with high specific surface area. J. Phys. Chem. Solids 71, 444–447 (2010). https://doi.org/10.1016/10.1016/j.jpcs.2009.11.01710.1016/10.1016/j.jpcs.2009.11.017 ↗
16. T. Wang, K.S. Lackner, A. Wright, Moisture swing sorbent for carbon dioxide capture from ambient air. Environ. Sci. Technol. 45, 6670–6675 (2011). https://doi.org/10.1016/10.1021/es201180v10.1016/10.1021/es201180v ↗
17. V. Fierro, A. Szczurek, C. Zlotea, J.F. Marêché, M.T. Izquierdo, A. Albiniak, M. Latroche, G. Furdin, A. Celzard, Experimental evidence of an upper limit for hydrogen storage at 77 K on activated carbons. Carbon 48, 1902–1911 (2010). https://doi.org/10.1016/10.1016/j.carbon.2010.01.05210.1016/10.1016/j.carbon.2010.01.052 ↗
18. P.R. Shukla, S. Wang, H. Sun, H.M. Ang, M. Tadé, Activated carbon supported cobalt catalysts for advanced oxidation of organic contaminants in aqueous solution. Appl. Catal. B 100, 529–534 (2010). https://doi.org/10.1016/10.1016/j.apcatb.2010.09.00610.1016/10.1016/j.apcatb.2010.09.006 ↗
19. C.-Y. Lu, M.-Y. Wey, K.-H. Chuang, Catalytic treating of gas pollutants over cobalt catalyst supported on porous carbons derived from rice husk and carbon nanotube. Appl. Catal. B 90, 652–661 (2009). https://doi.org/10.1016/10.1016/j.apcatb.2009.04.03010.1016/10.1016/j.apcatb.2009.04.030 ↗
20. M.A. Yahya, Z. Al-Qodah, C.Z. Ngah, Agricultural bio-waste materials as potential sustainable precursors used for activated carbon production: a review. Renew. Sustain. Energy Rev. 46, 218–235 (2015). https://doi.org/10.1016/10.1016/j.rser.2015.02.05110.1016/10.1016/j.rser.2015.02.051 ↗
21. H. Marsh, F. Rodríguez-Reinoso, Activated Carbon, 1st edn. (Elsevier, Amsterdam, 2006).
22. T.K. Enock, C.K. King’ondu, A. Pogrebnoi, Y.A.C. Jande, Status of biomass derived carbon materials for supercapacitor application. Int. J. Electrochem. 2017, 1–14 (2017). https://doi.org/10.1016/10.1155/2017/645342010.1016/10.1155/2017/6453420 ↗
23. J. Yan, Q. Wang, T. Wei, Z. Fan, Recent advances in design and fabrication of electrochemical supercapacitors with high energy densities. Adv. Energy Mater. 4, 1300816 (2014). https://doi.org/10.1016/10.1002/aenm.20130081610.1016/10.1002/aenm.201300816 ↗
24. J. Wang, S. Kaskel, KOH activation of carbon-based materials for energy storage. J. Mater. Chem. 22, 23710 (2012). https://doi.org/10.1016/10.1039/c2jm34066f10.1016/10.1039/c2jm34066f ↗
25. H.O. Pierson, Handbook of Carbon, Graphite, Diamond and Fullerenes: Properties, Processing and Applications (Noyes Publishers, Park Ridge, 1993).
26. A. Demirbas, Effects of temperature and particle size on bio-char yield from pyrolysis of agricultural residues. J. Anal. Appl. Pyrolysis 72, 243–248 (2004). https://doi.org/10.1016/10.1016/j.jaap.2004.07.00310.1016/10.1016/j.jaap.2004.07.003 ↗
27. Z.Z. Chowdhury, M.Z. Karim, M.A. Ashraf, K. Khalid, Influence of carbonization temperature on physicochemical properties of biochar derived from slow pyrolysis of Durian wood (Durio zibethinus) sawdust. BioResources (2016). https://doi.org/10.1016/10.15376/biores.11.2.3356-337210.1016/10.15376/biores.11.2.3356-3372 ↗
28. S. Masoudi Soltani, S.K. Yazdi, S. Hosseini, Effects of pyrolysis conditions on the porous structure construction of mesoporous charred carbon from used cigarette filters. Appl. Nanosci. 4, 551–569 (2014). https://doi.org/10.1016/10.1007/s13204-013-0230-010.1016/10.1007/s13204-013-0230-0 ↗
29. Y. Meng, X. Wang, Z. Wu, S. Wang, T.M. Young, Optimization of cellulose nanofibrils carbon aerogel fabrication using response surface methodology. Eur. Polym. J. 73, 137–148 (2015). https://doi.org/10.1016/10.1016/j.eurpolymj.2015.10.00710.1016/10.1016/j.eurpolymj.2015.10.007 ↗
30. Technical Association of the Pulp and Paper Industry. T.A.P.P.I. Standards; T 211 om-02: Ash in Wood, Pulp, Paper and Paperboard: Combustion at 525 °C. (2003)
31. N.K. Sahu, A. Andhare, Design of experiments applied to industrial process, in Statistical Approaches with Emphasis on Design of Experiments Applied to Chemical Processes. ed. by V. Silva (InTech, London, 2018)
32. A. Sadezky, H. Muckenhuber, H. Grothe, R. Niessner, U. Pöschl, Raman microspectroscopy of soot and related carbonaceous materials: spectral analysis and structural information. Carbon 43, 1731–1742 (2005). https://doi.org/10.1016/10.1016/j.carbon.2005.02.01810.1016/10.1016/j.carbon.2005.02.018 ↗
33. X. Zhang, Q. Yan, W. Leng, J. Li, J. Zhang, Z. Cai, E.B. Hassan, Carbon nanostructure of kraft lignin thermally treated at 500 to 1000 °C. Materials (2017). https://doi.org/10.1016/10.3390/ma1008097510.1016/10.3390/ma10080975 ↗
34. A.C. Ferrari, J. Robertson, Interpretation of Raman spectra of disordered and amorphous carbon. Phys. Rev. B 61, 14095–14107 (2000). https://doi.org/10.1016/10.1103/PhysRevB.61.1409510.1016/10.1103/PhysRevB.61.14095 ↗
35. K. Le Van, T. Luong Thi Thu, Preparation of pore-size controllable activated carbon from rice husk using dual activating agent and its application in supercapacitor. J. Chem. 2019, 1–11 (2019). https://doi.org/10.1016/10.1155/2019/432960910.1016/10.1155/2019/4329609 ↗
36. F. Tuinstra, J.L. Koenig, Raman spectrum of graphite. J. Chem. Phys. 53, 1126–1130 (1970). https://doi.org/10.1016/10.1063/1.167410810.1016/10.1063/1.1674108 ↗
37. A.L. Patterson, The Scherrer formula for X-ray particle size determination. Phys. Rev. 56, 978–982 (1939). https://doi.org/10.1016/10.1103/PhysRev.56.97810.1016/10.1103/PhysRev.56.978 ↗
38. A. Pandey, T. Bhaskar, M. Stöcker, R.K. Sukumaran, Recent Advances in Thermochemical Conversion of Biomass (Elsevier, Amsterdam, 2015).10.1016/B978-0-444-63289-0.00001-6 ↗
39. A. Colin Cameron, F.A.G. Windmeijer, An R-squared measure of goodness of fit for some common nonlinear regression models. J. Econ. 77, 329–342 (1997). https://doi.org/10.1016/10.1016/S0304-4076(96)01818-010.1016/10.1016/S0304-4076(96)01818-0 ↗
40. F.L.H. da Silva, M.I. Rodrigues, F. Maugeri, Dynamic modelling, simulation and optimization of an extractive continuous alcoholic fermentation process. J. Chem. Technol. Biotechnol. 74, 176–182 (1999). https://doi.org/10.1016/10.1002/(SICI)1097-4660(199902)74:2<176:AID-JCTB995>3.0.CO;2-C10.1016/10.1002/(SICI)1097-4660(199902)74:2<176:AID-JCTB995>3.0.CO;2-C ↗
41. O. Onay, Influence of pyrolysis temperature and heating rate on the production of bio-oil and char from safflower seed by pyrolysis, using a well-swept fixed-bed reactor. Fuel Process. Technol. 88, 523–531 (2007). https://doi.org/10.1016/10.1016/j.fuproc.2007.01.00110.1016/10.1016/j.fuproc.2007.01.001 ↗
42. F. Rodríguez-Reinoso, M. Molina-Sabio, Activated carbons from lignocellulosic materials by chemical and/or physical activation: an overview. Carbon 30, 1111–1118 (1992). https://doi.org/10.1016/10.1016/0008-6223(92)90143-K10.1016/10.1016/0008-6223(92)90143-K ↗
43. P.H. Brunner, P.V. Roberts, The significance of heating rate on char yield and char properties in the pyrolysis of cellulose. Carbon 18, 217–224 (1980). https://doi.org/10.1016/10.1016/0008-6223(80)90064-010.1016/10.1016/0008-6223(80)90064-0 ↗
44. M.M. Tang, R. Bacon, Carbonization of cellulose fibers—I. Low temperature pyrolysis. Carbon 2, 211–220 (1964). https://doi.org/10.1016/10.1016/0008-6223(64)90035-110.1016/10.1016/0008-6223(64)90035-1 ↗
45. R. Bacon, M.M. Tang, Carbonization of cellulose fibers—II. Physical property study. Carbon 2, 221–225 (1964). https://doi.org/10.1016/10.1016/0008-6223(64)90036-310.1016/10.1016/0008-6223(64)90036-3 ↗
46. J.L. Figueiredo, J.A. Moulijn, Carbon and Coal Gasification: Science and Technology (Springer, Dordrecht, 1986).10.1007/978-94-009-4382-7 ↗
47. C. Bouchelta, M.S. Medjram, M. Zoubida, F.A. Chekkat, N. Ramdane, J.-P. Bellat, Effects of pyrolysis conditions on the porous structure development of date pits activated carbon. J. Anal. Appl. Pyrolysis 94, 215–222 (2012). https://doi.org/10.1016/10.1016/j.jaap.2011.12.01410.1016/10.1016/j.jaap.2011.12.014 ↗
48. A.C. Lua, T. Yang, J. Guo, Effects of pyrolysis conditions on the properties of activated carbons prepared from pistachio-nut shells. J. Anal. Appl. Pyrolysis 72, 279–287 (2004). https://doi.org/10.1016/10.1016/j.jaap.2004.08.00110.1016/10.1016/j.jaap.2004.08.001 ↗
49. D.R. Helsel, R.M. Hirsch, Statistical Methods in Water Resources (USGS, 2002)
50. S.C. Abrahams, E.T. Keve, Normal probability plot analysis of error in measured and derived quantities and standard deviations. Acta Crystallogr. A 27, 157–165 (1971). https://doi.org/10.1016/10.1107/S056773947100030510.1016/10.1107/S0567739471000305 ↗
51. Z. Zheng, H. Xia, C. Srinivasakannan, J. Peng, L. Zhang, Utilization of Crofton weed for preparation of activated carbon by microwave induced CO2 activation. Chem. Eng. Process. 82, 1–8 (2014). https://doi.org/10.1016/10.1016/j.cep.2014.05.00110.1016/10.1016/j.cep.2014.05.001 ↗
52. I. Karacan, A. Gül, Carbonization behavior of oxidized viscose rayon fibers in the presence of boric acid–phosphoric acid impregnation. J. Mater. Sci. 49, 7462–7475 (2014). https://doi.org/10.1016/10.1007/s10853-014-8451-510.1016/10.1007/s10853-014-8451-5 ↗
53. C. Moreno-Castilla, F. Carrasco-Marín., F.J. Maldonado-Hódar, J. Rivera-Utrilla, Effects of non-oxidant and oxidant acid treatments on the surface properties of an activated carbon with very low ash content. Carbon 36, 145–151 (1998). https://doi.org/10.1016/10.1016/S0008-6223(97)00171-110.1016/10.1016/S0008-6223(97)00171-1 ↗
54. I. Karacan, T. Soy, Structure and properties of oxidatively stabilized viscose rayon fibers impregnated with boric acid and phosphoric acid prior to carbonization and activation steps. J. Mater. Sci. 48, 2009–2021 (2013). https://doi.org/10.1016/10.1007/s10853-012-6970-510.1016/10.1007/s10853-012-6970-5 ↗
55. W. Tongpoothorn, M. Sriuttha, P. Homchan, S. Chanthai, C. Ruangviriyachai, Preparation of activated carbon derived from Jatropha curcas fruit shell by simple thermo-chemical activation and characterization of their physico-chemical properties. Chem. Eng. Res. Des. 89, 335–340 (2011). https://doi.org/10.1016/10.1016/j.cherd.2010.06.01210.1016/10.1016/j.cherd.2010.06.012 ↗
56. L. Deng, R.J. Young, I.A. Kinloch, Y. Zhu, S.J. Eichhorn, Carbon nanofibres produced from electrospun cellulose nanofibres. Carbon 58, 66–75 (2013). https://doi.org/10.1016/10.1016/j.carbon.2013.02.03210.1016/10.1016/j.carbon.2013.02.032 ↗
57. Z.Q. Li, C.J. Lu, Z.P. Xia, Y. Zhou, Z. Luo, X-ray diffraction patterns of graphite and turbostratic carbon. Carbon 45, 1686–1695 (2007). https://doi.org/10.1016/10.1016/j.carbon.2007.03.03810.1016/10.1016/j.carbon.2007.03.038 ↗
58. H. Takagi, K. Maruyama, N. Yoshizawa, Y. Yamada, Y. Sato, XRD analysis of carbon stacking structure in coal during heat treatment. Fuel 83, 2427–2433 (2004). https://doi.org/10.1016/10.1016/j.fuel.2004.06.01910.1016/10.1016/j.fuel.2004.06.019 ↗
59. A.C. Ferrari, S.E. Rodil, J. Robertson, Interpretation of infrared and Raman spectra of amorphous carbon nitrides. Phys. Rev. B 67, 841 (2003). https://doi.org/10.1016/10.1103/PhysRevB.67.15530610.1016/10.1103/PhysRevB.67.155306 ↗
60. A.C. Ferrari, D.M. Basko, Raman spectroscopy as a versatile tool for studying the properties of graphene. Nat. Nanotechnol. 8, 235–246 (2013). https://doi.org/10.1016/10.1038/nnano.2013.4610.1016/10.1038/nnano.2013.46 ↗
61. O.A. Maslova, M.R. Ammar, G. Guimbretière, J.-N. Rouzaud, P. Simon, Determination of crystallite size in polished graphitized carbon by Raman spectroscopy. Phys. Rev. B 86, 1036 (2012). https://doi.org/10.1016/10.1103/PhysRevB.86.13420510.1016/10.1103/PhysRevB.86.134205 ↗
62. M.A. Amaral Junior, J.T. Matsushima, M.C. Rezende, E.S. Gonçalves, J.S. Marcuzzo, M.R. Baldan, Production and characterization of activated carbon fiber from textile PAN fiber. J. Aerosp. Technol. Manag. 9, 423–430 (2017). https://doi.org/10.1016/10.5028/jatm.v9i4.83110.1016/10.5028/jatm.v9i4.831 ↗
63. S. Yamauchi, Y. Kurimoto, Raman spectroscopic study on pyrolyzed wood and bark of Japanese cedar: temperature dependence of Raman parameters. J. Wood Sci. 49, 235–240 (2003). https://doi.org/10.1016/10.1007/s10086-002-0462-110.1016/10.1007/s10086-002-0462-1 ↗
64. S. Bernard, O. Beyssac, K. Benzerara, N. Findling, G. Tzvetkov, G.E. Brown, XANES, Raman and XRD study of anthracene-based cokes and saccharose-based chars submitted to high-temperature pyrolysis. Carbon 48, 2506–2516 (2010). https://doi.org/10.1016/10.1016/j.carbon.2010.03.02410.1016/10.1016/j.carbon.2010.03.024 ↗