journal article·2026-07-23

Atomically Dispersed Ru-Supported Cu-Ceria Catalysts for Selective 1-Octanol Ammoxidation

Chaoqi Chen, Fanny Hanon, Hayato Tsuchiya, Nirupama Sheet, Akiyo Omi, Satoshi Muratsugu, Kimitaka Higuchi, Mizuki Tada

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Abstract

Atomically dispersed Ru catalysts (Ru(AD)-Cu-CeO z ) were prepared by dispersing Ru species atomically on the surface of Cu-containing ceria. The Ru(AD)-Cu-CeO z catalysts (Ru/Ce molar ratio = 0.0078) exhibited markedly high catalytic performances in the ammoxidation of aliphatic alcohols, which was not selective on a Ru(NC)-Cu-CeO z catalyst with Ru nanoclusters. The incorporation of atomically dispersed Ru species was key for achieving the selective ammoxidation of 1-octanol, and the atomically dispersed Ru species was found to be stable under the identical ammoxidation conditions.
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Research context

OpenAlex topics: Catalytic Processes in Materials Science · Catalysis for Biomass Conversion · Oxidative Organic Chemistry Reactions

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Chemistry, Graduate School of Science/Research Center for Materials Science (RCMS)/Integrated Research Consortium on Chemical Sciences (IRCCS)

Nagoya University

Research Center for Materials Science (RCMS)

Department of Chemistry, Graduate School of Science

Institute of Materials and Systems for Sustainability

Funding

Ministry of Education, Culture, Sports, Science and Technology · Core Research for Evolutional Science and Technology · Asahi Glass Foundation · Japan Society for the Promotion of Science

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