journal article·2024-08-08

Calculation of π Using a Molecular Electron Spin Qubit Implemented by Pulsed Electron Paramagnetic Resonance

A. V. Borodulina, A. R. Melnikov, G. A. Bochkin, M. V. Fedin, E. B. Fel’dman, S. L. Veber

Publisher page

Abstract

The present letter demonstrates a simple method to characterize the molecular electron spin qubits, for which a large number of chemical compounds with non-zero spin have been proposed. The method is based on calculating the value of π using a one-qubit protocol based on obtaining and processing Rabi oscillations. It was implemented using a model system of a Finland trityl radical with an electron spin S = 1/2 and a pulsed electron paramagnetic resonance spectrometer. As a result, the value of π was obtained with an accuracy of two decimal places, and an analysis of statistical and systematic errors was carried out.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Spectroscopy and Quantum Chemical Studies · Molecular spectroscopy and chirality · Quantum Information and Cryptography

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

International Tomography Center, Siberian Branch of the Russian Academy of Sciences (SB RAS), 3a Institutskaya Street, Novosibirsk 630090, Russian Federation

Novosibirsk State University, 1 Pirogova Street, Novosibirsk 630090, Russian Federation

Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences (RAS), 1 Academician Semenov Avenue, Chernogolovka 142432, Russian Federation

Funding

Russian Science Foundation · Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry of RAS

References (51)

Show source-provided references
1. 10.1038/s42254-021-00410-610.1038/s42254-021-00410-6 ↗
2. 10.54097/hset.v38i.587510.54097/hset.v38i.5875 ↗
3. 10.1002/wcms.148110.1002/wcms.1481 ↗
4. 10.48550/ARXIV.QUANT-PH/960504310.48550/ARXIV.QUANT-PH/9605043 ↗
5. 10.1137/S009753979529317210.1137/S0097539795293172 ↗
6. 10.48550/arXiv.quant-ph/951102610.48550/arXiv.quant-ph/9511026 ↗
7. 10.1103/RevModPhys.90.01500210.1103/RevModPhys.90.015002 ↗
8. 10.1021/acs.chemrev.8b0080310.1021/acs.chemrev.8b00803 ↗
9. 10.1016/j.revip.2019.10002810.1016/j.revip.2019.100028 ↗
10. 10.1017/CBO978051197666710.1017/CBO9780511976667 ↗
11. 10.3103/S875669902004002010.3103/S8756699020040020 ↗
12. 10.1038/s41586-023-06096-310.1038/s41586-023-06096-3 ↗
13. 10.1063/1.508816410.1063/1.5088164 ↗
14. 10.3938/PhiT.20.01110.3938/PhiT.20.011 ↗
15. 10.1038/s41928-023-01037-410.1038/s41928-023-01037-4 ↗
16. 10.1063/5.000744410.1063/5.0007444 ↗
17. 10.1063/1.511581410.1063/1.5115814 ↗
18. 10.1109/MNANO.2022.317539210.1109/MNANO.2022.3175392 ↗
19. 10.1038/nature.2017.2158510.1038/nature.2017.21585 ↗
20. 10.1088/2058-7058/32/2/610.1088/2058-7058/32/2/6 ↗
21. 10.48550/ARXIV.2306.1172710.48550/ARXIV.2306.11727 ↗
22. 10.1021/jacs.2c1178410.1021/jacs.2c11784 ↗
23. 10.1021/jz101650z10.1021/jz101650z ↗
24. 10.1002/chem.20230177110.1002/chem.202301771 ↗
25. 10.1002/9780470034590.emrstm152110.1002/9780470034590.emrstm1521 ↗
26. 10.1038/ncomms974810.1038/ncomms9748 ↗
27. 10.1021/acs.jpcc.3c0440110.1021/acs.jpcc.3c04401 ↗
28. 10.26434/chemrxiv-2023-0p9jh10.26434/chemrxiv-2023-0p9jh ↗
29. 10.1063/5.017720010.1063/5.0177200 ↗
30. 10.1002/anie.20231293610.1002/anie.202312936 ↗
31. 10.1002/chem.20230100510.1002/chem.202301005 ↗
32. 10.1063/1.512813210.1063/1.5128132 ↗
33. 10.1021/jacs.8b0673310.1021/jacs.8b06733 ↗
34. 10.1103/PhysRevB.79.17240810.1103/PhysRevB.79.172408 ↗
35. 10.1038/nnano.2006.17410.1038/nnano.2006.174 ↗
36. 10.1103/PhysRevLett.95.20050110.1103/PhysRevLett.95.200501 ↗
37. 10.1103/PhysRevA.71.01233210.1103/PhysRevA.71.012332 ↗
38. 10.1073/pnas.94.5.163410.1073/pnas.94.5.1634 ↗
39. 10.1007/978-1-4939-3658-810.1007/978-1-4939-3658-8 ↗
40. 10.1103/PhysRevLett.108.10720410.1103/PhysRevLett.108.107204 ↗
41. 10.1021/acscentsci.5b0038410.1021/acscentsci.5b00384 ↗
42. 10.1039/b819556k10.1039/b819556k ↗
43. 10.1021/acs.jpclett.0c0221310.1021/acs.jpclett.0c02213 ↗
44. 10.1038/s41557-019-0232-y10.1038/s41557-019-0232-y ↗
45. 10.1038/s41586-022-05434-110.1038/s41586-022-05434-1 ↗
46. 10.1038/s41586-023-06438-110.1038/s41586-023-06438-1 ↗
47. 10.1038/s41586-023-06481-y10.1038/s41586-023-06481-y ↗
48. 10.1007/s11128-020-02759-610.1007/s11128-020-02759-6 ↗
49. 10.1021/acs.jpcb.5b0302710.1021/acs.jpcb.5b03027 ↗
50. 10.1016/j.jmr.2016.08.00910.1016/j.jmr.2016.08.009 ↗
51. 10.1103/PhysRevLett.93.20660310.1103/PhysRevLett.93.206603 ↗