DataVXThe Journal of Physical Chemistry LettersPaper
journal article·2017-06-15Open access

Far-Zone Resonant Energy Transfer in X-ray Photoemission as a Structure Determination Tool

Denis Céolin, Jean-Pascal Rueff, Andrey Zimin, Paul Morin, Victor Kimberg, Sergey Polyutov, Hans Ågren, Faris Gel’mukhanov

The Journal of Physical Chemistry Letters· Volume 8· Issue 12
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Source abstract

Abstract

Near-zone Förster resonant energy transfer is the main effect responsible for excitation energy flow in the optical region and is frequently used to obtain structural information. In the hard X-ray region, the Förster law is inadequate because the wavelength is generally shorter than the distance between donors and acceptors; hence, far-zone resonant energy transfer (FZRET) becomes dominant. We demonstrate the characteristics of X-ray FZRET and its fundamental differences with the ordinary near-zone resonant energy-transfer process in the optical region by recording and analyzing two qualitatively different systems: high-density CuO polycrystalline powder and SF 6 diluted gas. We suggest a method to estimate geometrical structure using X-ray FZRET employing as a ruler the distance-dependent shift of the acceptor core ionization potential induced by the Coulomb field of the core-ionized donor.
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Research context

OpenAlex topics: X-ray Spectroscopy and Fluorescence Analysis · Advanced Chemical Physics Studies · Electron and X-Ray Spectroscopy Techniques

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Synchrotron SOLEIL, l’Orme des Merisiers, Saint-Aubin, BP 48, 91192 Gif-sur-Yvette Cedex, France

LCP-MR (UMR 7614), Sorbonne Universités, UPMC Univ Paris 06, CNRS, 75005, Paris, France

Theoretical Chemistry and Biology, School of Biotechnology, Royal Institute of Technology, S-106 91 Stockholm, Sweden

Institute of Nanotechnology, Spectroscopy and Quantum Chemistry, Siberian Federal University, 660041 Krasnoyarsk, Russia

Funding

Vetenskapsr?det · FP7 People: Marie-Curie Actions · Russian Science Foundation · Knut och Alice Wallenbergs Stiftelse · European Cooperation in Science and Technology · Japan Society for the Promotion of Science · Triangle de la Physique

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