journal article·2015-10

Estimation of the activation energy for surface diffusion during metastable phase formation

Keke Chang, Moritz to Baben, Denis Music, Dennis Lange, Hamid Bolvardi, Jochen M. Schneider

Acta Materialia· Volume 98
Publisher page

Abstract

Abstract A method to estimate the activation energy for surface diffusion during magnetron sputtering based on experimental metastable phase formation data has been developed. The so obtained activation energies are consistent with diffusion activation barriers determined by ab initio calculations. The here adopted comparative experimental and theoretical research strategy enables the efficient acquisition of activation energy data and constitutes an improved description of surface diffusion processes of metastable materials during magnetron sputtering.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Metal and Thin Film Mechanics · nanoparticles nucleation surface interactions · Metallurgical and Alloy Processes

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (60)

Show source-provided references
1. Accelerated kinetics of surface hardening by diffusion near phase transition temperature: mechanism of growth of boride layers on titanium10.1016/j.actamat.2011.03.046 ↗
2. Microstructural evolution and formation of nanocrystalline intermetallic compound during surface mechanical attrition treatment of cobalt10.1016/j.actamat.2007.06.030 ↗
3. Microstructural evolution during film growth10.1116/1.1601610 ↗
4. Ohring · 2002
5. Phase formation in co-deposited metallic alloy thin films10.1007/BF01160780 ↗
6. Atomistic processes in the early stages of thin-film growth10.1126/science.276.5311.377 ↗
7. Venables · 2000
8. In situ epitaxial MgB2 thin films for superconducting electronics10.1038/nmat703 ↗
9. Multiferroics progress and prospects in thin films10.1038/nmat1805 ↗
10. Scaling hetero-epitaxy from layers to three-dimensional crystals10.1126/science.1217666 ↗
11. Correlation between defect structure and electrochemical properties of mixed conducting La0.1Sr0.9Co0.8Fe0.2O3−δ10.1016/j.actamat.2013.11.006 ↗
12. Formation and properties of Au-based nanograined metallic glasses10.1016/j.actamat.2011.07.007 ↗
13. Oxide ultra-thin films on metals: new materials for the design of supported metal catalysts10.1039/b718768h ↗
14. Mechanics of sintering for coupled grain boundary and surface diffusion10.1016/j.actamat.2011.05.006 ↗
15. Effective diffusion coefficients in solid-state sintering10.1016/j.actamat.2004.02.042 ↗
16. Nanoantenna-enhanced gas sensing in a single tailored nanofocus10.1038/nmat3029 ↗
17. Ultralow-voltage field-ionization discharge on whiskered silicon nanowires for gas-sensing applications10.1038/nmat2944 ↗
18. Self-assembly of large and small molecules into hierarchically ordered sacs and membranes10.1126/science.1154586 ↗
19. Mann · Nat. Mater. · 2009 · 8 · 78110.1038/nmat2496 ↗
20. Self-assembly and transformation of hybrid nano-objects and nanostructures under equilibrium and non-equilibrium conditions10.1126/science.1092356 ↗
21. The role of surface oxygen in the growth of large single-crystal graphene on copper10.1126/science.1243879 ↗
22. Epitaxial growth writ large10.1126/science.1184947 ↗
23. Field ionization of gases at a metal surface and the resolution of the field ion microscope10.1103/PhysRev.102.624 ↗
24. Antczak · 2010
25. Scanning tunneling microscopy10.1016/0039-6028(83)90716-1 ↗
26. Controlling the dynamics of a single atom in lateral atom manipulation10.1126/science.1102370 ↗
27. How sensitive is epitaxial growth to adsorbates10.1103/PhysRevLett.81.1255 ↗
28. Theory of self-diffusion at and growth of Al(111)10.1103/PhysRevLett.72.254 ↗
29. Self-diffusion of small clusters on fcc metal (111) surfaces10.1103/PhysRevLett.85.1044 ↗
30. Dynamics of Ti, N, and TiNx (x=1–3) admolecule transport on TiN(001) surfaces10.1103/PhysRevB.86.155443 ↗
31. Surface morphology during multilayer epitaxial growth of Ge(001)10.1103/PhysRevLett.74.1127 ↗
32. Reaction of O2 with subsurface oxygen vacancies on TiO2 anatase (101)10.1126/science.1239879 ↗
33. Combinatorial thin film materials science. From alloy discovery and optimization to alloy design10.1016/j.tsf.2012.04.062 ↗
34. Diffraction stress analysis of macroscopically elastically anisotropic specimens: on the concepts of diffraction elastic constants and stress factors10.1063/1.1569662 ↗
35. Diffraction stress analysis of elastic grain interaction in polycrystalline materials10.1524/zkri.2007.222.3-4.160 ↗
36. Total-energy method based on the exact muffin-tin orbitals theory10.1103/PhysRevB.64.014107 ↗
37. Andersen · 1995 · 63
38. Application of the exact muffin-tin orbitals theory: the spherical cell approximation10.1016/S0927-0256(99)00098-1 ↗
39. Full charge-density scheme with a kinetic-energy correction: application to ground-state properties of the 4d metals10.1103/PhysRevB.55.13521 ↗
40. Generalized gradient approximation made simple10.1103/PhysRevLett.77.3865 ↗
41. The alloy theoretic automated toolkit: a user guide10.1016/S0364-5916(02)80006-2 ↗
42. First-principles study of binary bcc alloys using special quasirandom structures10.1103/PhysRevB.69.214202 ↗
43. Electronic properties of random alloys: special quasirandom structures10.1103/PhysRevB.42.9622 ↗
44. From ultrasoft pseudopotentials to the projector augmented-wave method10.1103/PhysRevB.59.1758 ↗
45. Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set10.1103/PhysRevB.54.11169 ↗
46. Projector augmented-wave method10.1103/PhysRevB.50.17953 ↗
47. Special points for brillouin-zone integrations10.1103/PhysRevB.13.5188 ↗
48. First-principles study of binary special quasirandom structures for the Al–Cu, Al–Si, Cu–Si, and Mg–Si systems10.1016/j.calphad.2009.10.007 ↗
49. Energetics of point defects in TiC10.1016/j.jeurceramsoc.2008.06.027 ↗
50. The surface energy of metals10.1016/S0039-6028(98)00363-X ↗
51. Structure and properties of nanograined Fe–C alloys after severe plastic deformation10.1002/adem.201000312 ↗
52. Interfacial dominated ferromagnetism in nanograined ZnO: a mSR and DFT study10.1038/srep08871 ↗
53. A review of wetting versus adsorption, complexions, and related phenomena: the rosetta stone of wetting10.1007/s10853-013-7462-y ↗
54. Thermodynamic aspects of the grain boundary segregation in Cu(Bi) alloys10.1016/S1359-6454(99)00264-5 ↗
55. Grain boundary phase transitions and their influence on properties of polycrystals10.1023/B:INTS.0000028645.30358.f5 ↗
56. Straumal · 2003
57. Lattice parameters, densities, expansion coefficients and perfection of structure of Cu and of Cu-In α phase10.1107/S0567739469001549 ↗
58. The lattice parameter and density of pure tungsten10.1103/PhysRev.26.736 ↗
59. Elementare Theorie der Brownschen Bewegung
60. Metastable alloy phases by co-sputtering10.1016/0001-6160(76)90051-1 ↗