journal article·2017-08Open access

Elastically confined martensitic transformation at the nano-scale in a multifunctional titanium alloy

H.L. Wang, Y.L. Hao, S.Y. He, T. Li, J.M. Cairney, Y.D. Wang, Y. Wang, E.G. Obbard, F. Prima, K. Du, S.J. Li, R. Yang

Acta Materialia· Volume 135

Abstract

Abstract A martensitic transformation (MT) is a typical first-order diffusionless crystal structural change with strong autocatalysis like avalanche at a speed of sound propagation. This unique characteristic, however, is undetectable in some multifunctional titanium alloys. Recently, a nano-scale elastically confined MT mechanism was proposed because a nano-scale Nb modulation in a Ti-Nb based alloy was observed. Here we analyze the elastic confinement in details and its induced novel properties in a wide temperature range. The statistical analyses of atom probe tomography (APT) data confirm the existence of the nano-scale Nb concentration modulation. The synchrotron X-ray diffraction (SXRD) profiles demonstrate that the nano-scale Nb modulation causes weak diffuse scattering, as evidenced by the extreme broad diffraction bands. The tensile tests find a critical temperature of ∼150 K, where the critical stress to induce the MT and Young's modulus reach the minimum and the superelastic strain reaches the maximum (∼4.5%) and keeps constant as the temperature decreases further to
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Research context

OpenAlex topics: Titanium Alloys Microstructure and Properties · Microstructure and mechanical properties · Advanced Materials Characterization Techniques

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References (45)

Show source-provided references
1. Physical metallurgy of Ti–Ni-based shape memory alloys10.1016/j.pmatsci.2004.10.001 ↗
2. Shape memory effect and superelasticity in a strain glass alloy10.1103/PhysRevLett.97.225703 ↗
3. Nonhysteretic superelasticity of shape memory alloys at the nanoscale10.1103/PhysRevLett.111.145701 ↗
4. Multifunctional alloys obtained via a dislocation-free plastic deformation mechanism10.1126/science.1081957 ↗
5. Super-elastic titanium alloy with unstable plastic deformation10.1063/1.2037192 ↗
6. Ductile titanium alloy with low Poisson's ratio10.1103/PhysRevLett.98.216405 ↗
7. Elastic deformation behaviour of Ti-24Nb-4Zr-7.9Sn for biomedical applications10.1016/j.actbio.2006.11.002 ↗
8. Reversible movement of homogenously nucleated dislocations in a β-titanium alloy10.1103/PhysRevLett.102.045503 ↗
9. On the mechanism of superelasticity in Gum metal10.1016/j.actamat.2008.11.013 ↗
10. Anomalous transformation-induced deformation in <1 1 0> textured Gum Metal10.1016/j.actamat.2010.02.001 ↗
11. The effect of oxygen on a" martensite and superelasticity in Ti-24Nb-4Zr-8Sn10.1016/j.actamat.2010.09.015 ↗
12. Nanodisturbances in deformed Gum metal10.1016/j.actamat.2006.01.027 ↗
13. Superelasticity and tunable thermal expansion across a wide temperature range10.1016/j.jmst.2016.06.017 ↗
14. Controlling reversible martensitic transformation in titanium alloys with high strength and low elastic modulus10.1016/j.scriptamat.2012.06.011 ↗
15. Collings · 1984
16. Lattice modulation and superelasticity in oxygen-added β-Ti alloys10.1016/j.actamat.2011.06.015 ↗
17. Effects of oxygen concentration and phase stability on nano-domain structure and thermal expansion behavior of Ti-Nb-Zr-Ta-O alloys10.1016/j.actamat.2015.08.054 ↗
18. Anomalous thermal expansion of cold-rolled Ti-Nb-Ta-Zr Alloy10.2320/matertrans.MRP2008380 ↗
19. Nanodomain structure and its effect on abnormal thermal expansion behavior of a Ti-23Nb-2Zr-0.7Ta-1.2O alloy10.1016/j.actamat.2013.04.060 ↗
20. Point-by-point compositional analysis for atom probe tomography10.1016/j.mex.2014.02.001 ↗
21. New insights into the phase transformations to isothermal ω and ω-assisted α in near β-Ti alloys10.1016/j.actamat.2015.12.046 ↗
22. Low-cycle fatigue properties of a titanium alloy exhibiting nonlinear elastic deformation behavior10.1016/j.actamat.2011.04.015 ↗
23. Contingency table techniques for three dimensional atom probe tomography10.1002/jemt.20412 ↗
24. A three-dimensional Markov field approach for the analysis of atomic clustering in atom probe data10.1080/14786430903441475 ↗
25. Superelastic effect in polycrystalline ferrous alloys10.1126/science.1202232 ↗
26. Shape memory and superelastic ceramics at small scales10.1126/science.1239745 ↗
27. Transition from many domain to single domain martensite morphology in small-scale shape memory alloys10.1016/j.actamat.2013.06.003 ↗
28. The structure and decomposition of Zr and Ti b.c.c. solid solutions10.1016/0022-5088(72)90177-4 ↗
29. Morphology and crystallography of alpha precipitates in beta Ti-Mo binary alloys10.2320/matertrans1989.39.31 ↗
30. Beta phase decomposition in Ti-5Al-5Mo-5V-3Cr10.1016/j.actamat.2009.04.031 ↗
31. Phase transformation kinetics during continuous heating of a β-quenched Ti–10V–2Fe–3Al alloy10.1007/s10853-014-8701-6 ↗
32. HAADF-STEM study of phase separation and the subsequent α phase precipitation in a β-Ti alloy10.1016/j.scriptamat.2015.09.007 ↗
33. The effect of alloy composition on instabilities in the β phase of titanium alloys10.1016/j.scriptamat.2016.01.024 ↗
34. A nano-scale instability in the β phase of dilute Ti–Mo alloys10.1016/j.scriptamat.2016.01.044 ↗
35. Khachaturyan · 2013
36. Free energy of a nonuniform system. I. Interfacial free energy10.1063/1.1744102 ↗
37. On spinodal decomposition10.1016/0001-6160(61)90182-1 ↗
38. Stabilizing the body centered cubic crystal in titanium alloys by a nano-scale concentration modulation10.1016/j.jallcom.2016.12.406 ↗
39. Crystal instabilities at finite strain10.1103/PhysRevLett.71.4182 ↗
40. Mechanical properties and shape memory behavior of Ti-Nb alloys10.2320/matertrans.45.2443 ↗
41. X-ray line broadening from filed aluminium and wolfram10.1016/0001-6160(53)90006-6 ↗
42. Williamson–Hall anisotropy in nanocrystalline metals: X-ray diffraction experiments and atomistic simulations10.1016/j.actamat.2007.09.007 ↗
43. Martensitic transformation, shape memory effect and superelasticity of Ti-Nb binary alloys10.1016/j.actamat.2006.01.019 ↗
44. Precipitation hardening, progress in materials science
45. Tracing the coupled atomic shear and shuffle for a cubic to a hexagonal crystal transition10.1016/j.scriptamat.2017.02.024 ↗