The mechanical properties of a nanocrystalline Al2O3/a-Al2O3 composite coating measured by nanoindentation and Brillouin spectroscopy

Abstract In this work, ellipsometry, Brillouin spectroscopy and nanoindentation are combined to assess the mechanical properties of a nanocrystalline Al 2 O 3 /a-Al 2 O 3 composite coating with high accuracy and precision. The nanocomposite is grown by pulsed laser deposition at either room temperature or 600 °C. The adhesive strength is evaluated by nanoscratch tests. In the room temperature process the coating attains an unusual combination of compactness, strong interfacial bonding, moderate stiffness ( E = 195 ± 9 GPa and ν = 0.29 ± 0.02) and significant hardness ( H = 10 ± 1 GPa), resulting in superior plastic behavior and a relatively high ratio of hardness to elastic modulus ( H / E = 0.049). These features are correlated to the nanostructure of the coating, which comprises a regular dispersion of ultrafine crystalline Al 2 O 3 nanodomains (2–5 nm) in a dense and amorphous alumina matrix, as revealed by transmission electron microscopy. For the coating grown at 600 °C, strong adhesion is also observed, with an increase of stiffness and a significant enhancement of hardness ( E = 277 ± 9 GPa, ν = 0.27 ± 0.02 and H = 25 ± 1 GPa), suggesting an outstanding resistance to wear ( H / E = 0.091).