journal article·2022-02-03Open access

Scratch-Healing Behavior of Ice by Local Sublimation and Condensation

Menno Demmenie, Paul Kolpakov, Yuki Nagata, Sander Woutersen, Daniel Bonn

Abstract

High Resolution Image Download MS PowerPoint Slide We show that the surface of ice is scratch healing: micrometer-deep scratches in the ice surface spontaneously disappear by thermal relaxation on the time scale of roughly an hour. Following the dynamics and comparing it to different mass transfer mechanisms, we find that sublimation from and condensation onto the ice surface is the dominant scratch-healing mechanism. The scratch-healing kinetics shows a strong temperature dependence, following an Arrhenius behavior with an activation energy of Δ E = 58.6 ± 4.6 kJ/mol, agreeing with the proposed sublimation mechanism and at odds with surface diffusion or fluid flow or evaporation–condensation from a quasi-liquid layer.
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Research context

OpenAlex topics: nanoparticles nucleation surface interactions · Advanced Thermodynamics and Statistical Mechanics · Material Dynamics and Properties

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Affiliations

Institute of Physics, University of Amsterdam, Science Park 904, 1098 XH Amsterdam, The Netherlands

Van’t Hoff Institute for Molecular Sciences, University of Amsterdam, Science Park 904, 1098 XH Amsterdam, The Netherlands

Max Planck Institute for Polymer Research, Ackermannweg 10, 55128 Mainz, Germany

Funding

Nederlandse Organisatie voor Wetenschappelijk Onderzoek

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