Interfaces between Different Iron Phthalocyanines and Au(111): Influence of the Fluorination on Structure and Interfacial Interactions
Source abstract
Abstract
The interface properties of iron phthalocyanine (FePc) as well as partially fluorinated and perfluorinated iron phthalocyanine (FePcF 4 and FePcF 16 ) have been studied and compared. Well-ordered monolayers have been prepared and investigated with scanning tunneling microscopy (STM). X-ray photoelectron spectroscopy (XPS) and ultraviolet photoelectron spectroscopy (UPS) have been used to study the electronic structure of FePcF x in the monolayer in comparison with FePcF x in thin films. While the fluorination changes the structural ordering as well the total interface dipole, local interactions of the central iron atom and the Au(111) surface remain unchanged. The interplay of substrate–molecule and intermolecular interactions is discussed.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Molecular Junctions and Nanostructures · Surface Chemistry and Catalysis · Surface and Thin Film Phenomena
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Institute of Physical and Theoretical Chemistry, University of Tübingen, Auf der Morgenstelle 18, 72076 Tübingen, Germany
Nikolaev Institute of Inorganic Chemistry SB RAS, 3 Lavrentiev Ave., Novosibirsk, Russia 630090
Center for Light−Matter Interaction, Sensors & Analytics (LISA+) at the University of Tübingen, Auf der Morgenstelle 18, 72076 Tübingen, Germany
Funding
Deutsche Forschungsgemeinschaft · State of Baden-W??rttemberg
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