Synthesis and Properties of Monolayer-Protected Co_{x}(SC₂H₄Ph)_{m} Nanoclusters

Stephan Pollitt; Ernst Pittenauer; Christoph Rameshan; Thomas Schachinger; Olga V. Safonova; Vera Truttmann; Abhijit Bera; Günter Allmaier; Noelia Barrabés; Günther Rupprechter

doi:10.1021/acs.jpcc.6b12076

journal article·2017-05-25Open access

Synthesis and Properties of Monolayer-Protected Co_x(SC₂H₄Ph)_m Nanoclusters

Stephan Pollitt, Ernst Pittenauer, Christoph Rameshan, Thomas Schachinger, Olga V. Safonova, Vera Truttmann, Abhijit Bera, Günter Allmaier, Noelia Barrabés, Günther Rupprechter

The Journal of Physical Chemistry C· Volume 121· Issue 20

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Source abstract

Abstract

Nanometer-sized and stable thiolate-protected cobalt clusters were synthesized by a wet chemical method, leading to a pink solution with well-defined optical activity (ultraviolet–visible) and photoluminescence. The cobalt cluster core of ∼1.3 nm size was metallic (as indicated by scanning transmission electron microscopy, scanning tunneling microscopy, X-ray photoelectron spectroscopy, electron-energy loss spectroscopy) and was surrounded by a specific configuration of thiolate staples (according to Raman spectra, Fourier transfrom infrared spectroscopy, X-ray absorption fine structure, matrix-assisted laser desorption ionization) that is similar to that of corresponding gold clusters.

Source: openalex_inverted_index · Quality: baseline

Research context

Nanomaterials

OpenAlex topics: Nanocluster Synthesis and Applications · Gold and Silver Nanoparticles Synthesis and Applications · Quantum Dots Synthesis And Properties

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Institute of Materials Chemistry, Technische Universität Wien, Getreidemarkt 9/165, 1060 Vienna, Austria

Institute of Chemical Technologies and Analytics, Technische Universität Wien, Getreidemarkt 9/164, 1060 Vienna, Austria

Universitary Service Centre for Transmission Electron Microscopy (USTEM), Technische Universität Wien, Wiedner Hauptstraße 8-10, 1040 Vienna, Austria

Paul Scherrer Institute, 5232 Villigen PSI, Switzerland

Funding

Austrian Science Fund

References (66)

Show source-provided references

1. Tsukuda T. · 2015 · 9

2. 10.1021/acs.chemrev.5b0070310.1021/acs.chemrev.5b00703 ↗

3. 10.1039/c2cs15325d10.1039/c2cs15325d ↗

4. 10.1039/C4NR05794E10.1039/C4NR05794E ↗

5. 10.1002/smll.20110259010.1002/smll.201102590 ↗

6. 10.1021/acs.jpcc.5b0393410.1021/acs.jpcc.5b03934 ↗

7. 10.1039/C3CC47512C10.1039/C3CC47512C ↗

8. 10.1039/c1jm10082c10.1039/c1jm10082c ↗

9. 10.1021/ar400209a10.1021/ar400209a ↗

10. 10.1039/C4NR01063A10.1039/C4NR01063A ↗

11. 10.1021/ic401306910.1021/ic4013069 ↗

12. 10.1039/C4NR04981K10.1039/C4NR04981K ↗

13. 10.1007/s11051-013-1522-810.1007/s11051-013-1522-8 ↗

14. 10.1039/C5RA27972K10.1039/C5RA27972K ↗

15. 10.1126/science.105755310.1126/science.1057553 ↗

16. 10.1140/epjb/e2003-00064-010.1140/epjb/e2003-00064-0 ↗

17. 10.1021/la702876h10.1021/la702876h ↗

18. 10.1021/jacs.5b0354510.1021/jacs.5b03545 ↗

19. 10.1039/C5CC08064A10.1039/C5CC08064A ↗

20. 10.1039/C5TA06202K10.1039/C5TA06202K ↗

21. 10.1007/s10853-015-9690-910.1007/s10853-015-9690-9 ↗

22. 10.1039/C5TA07561K10.1039/C5TA07561K ↗

23. 10.1021/jacs.5b1198610.1021/jacs.5b11986 ↗

24. 10.1021/acscatal.5b0145210.1021/acscatal.5b01452 ↗

25. 10.1039/C3994000080110.1039/C39940000801 ↗

26. 10.1107/S090904950501271910.1107/S0909049505012719 ↗

27. 10.1016/0022-1902(62)80255-310.1016/0022-1902(62)80255-3 ↗

28. 10.1021/ac200789v10.1021/ac200789v ↗

29. 10.1021/ja507189v10.1021/ja507189v ↗

30. 10.1021/jp101741a10.1021/jp101741a ↗

31. 10.1021/ja076621a10.1021/ja076621a ↗

32. 10.1021/la803865v10.1021/la803865v ↗

33. 10.1021/ac801259j10.1021/ac801259j ↗

34. 10.1021/ac100251d10.1021/ac100251d ↗

35. 10.1039/b922291j10.1039/b922291j ↗

36. 10.1021/nn101244710.1021/nn1012447 ↗

37. 10.1038/ncomms1077110.1038/ncomms10771 ↗

38. 10.1021/acscatal.5b0015410.1021/acscatal.5b00154 ↗

39. 10.1016/j.physe.2008.06.00310.1016/j.physe.2008.06.003 ↗

40. 10.1016/j.matlet.2007.09.03810.1016/j.matlet.2007.09.038 ↗

41. 10.1088/1464-4258/7/12/00410.1088/1464-4258/7/12/004 ↗

42. 10.1021/ja109303z10.1021/ja109303z ↗

43. 10.1021/jp014259v10.1021/jp014259v ↗

44. 10.1002/(SICI)1521-3773(20000502)39:9<1683::AID-ANIE1683>3.0.CO;2-110.1002/(SICI)1521-3773(20000502)39:9<1683::AID-ANIE1683>3.0.CO;2-1 ↗

45. 10.1021/jp993867w10.1021/jp993867w ↗

46. 10.1017/S143192761600017910.1017/S1431927616000179 ↗

47. 10.1063/1.348201310.1063/1.3482013 ↗

48. 10.1107/S0365110X5000073210.1107/S0365110X50000732 ↗

49. 10.1088/0953-8984/26/39/39600110.1088/0953-8984/26/39/396001 ↗

50. 10.1039/C5CC02564H10.1039/C5CC02564H ↗

51. 10.1063/1.43271110.1063/1.432711 ↗

52. 10.1021/jp502453q10.1021/jp502453q ↗

53. 10.1039/C5NR03497C10.1039/C5NR03497C ↗

54. 10.1038/ncomms534810.1038/ncomms5348 ↗

55. 10.1021/acs.jpcc.6b0759210.1021/acs.jpcc.6b07592 ↗

56. 10.1016/j.pnsc.2016.09.00810.1016/j.pnsc.2016.09.008 ↗

57. 10.1021/jp502453q10.1021/jp502453q ↗

58. 10.1021/jp403306310.1021/jp4033063 ↗

59. 10.1021/jp805638x10.1021/jp805638x ↗

60. 10.1016/j.jcat.2016.09.00210.1016/j.jcat.2016.09.002 ↗

61. 10.1021/jp507739u10.1021/jp507739u ↗

62. 10.1021/acs.jpcc.5b0414510.1021/acs.jpcc.5b04145 ↗

63. 10.1016/j.elecom.2006.11.02210.1016/j.elecom.2006.11.022 ↗

64. 10.1021/la202695710.1021/la2026957 ↗

65. 10.1021/acs.jpcc.5b0081610.1021/acs.jpcc.5b00816 ↗

66. 10.1088/0031-8949/1/5-6/02010.1088/0031-8949/1/5-6/020 ↗