journal article·2021-02

Microstructure and Phase Evolution Mechanism in Hot-pressed and Hot-deformed Nd-Fe-B Magnets with Nd85Cu15 Addition

Tieqiao Zhang, Wandong Xing, Fugang Chen, Shengsheng Liu, Lanting Zhang, Rong Yu

Acta Materialia· Volume 204
Publisher page

Abstract

Abstract Chemical composition and structure characteristics of the intergranular phases in Nd-Fe-B magnets play a key role in regulating the magnetic properties. However, it has still been a challenge to understand the evolution mechanism of grain boundary phases in hot-pressed and hot-deformed Nd-Fe-B magnets due to the complex phase composition and structure. In this work, grain boundary modification using Nd85Cu15 alloy has been applied to hot-pressed and hot-deformed Nd-Fe-B magnets. The structure evolution mechanism of the grain boundary phase during hot-pressing was studied by TEM analysis, which shows that an overall reaction, Nd + Nd26Ga7Co10 + Nd2Fe14B → Nd3Co + Nd5Fe2B6 + Nd6(Fe,Co)13Ga, occurs at 600°C in hot-pressed magnet with Nd85Cu15 addition. When the hot-deformation was conducted at 675°C abnormal grain growth was observed in hot-deformed magnets with or without Nd85Cu15 addition. In contrast, as the hot deformation temperature decreased to 630 °C, the uniform and ultra-fine Nd2Fe14B grains formed in the Nd85Cu15 doped magnet, which shows a significantly improved coercivity of 2.03 T and a squareness factor of 0.93.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Magnetic Properties of Alloys · Hydrogen Storage and Materials · Magnetic properties of thin films

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

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