journal article·2022-04Open access

(Nd,La,Ce)-Fe-B hot-deformed magnets for application of variable-magnetic-force motors

Xin Tang, H. Sepehri-Amin, A. Bolyachkin, T. Ohkubo, K. Hono

Acta Materialia· Volume 228

Abstract

The recent development of variable-magnetic-force (VMF) motors has raised a new demand for permanent magnets with a moderate coercivity and magnetizing field (Hmag), flat first-order reversal curves (FORCs), and high magnetization. In this study, we explored the potential of low-cost (Nd,La,Ce)-Fe-B hot-deformed magnets for the VMF motor application. We showed that the coercivity can be tuned to a desirable value (∼0.15-0.65 T) using a combined effect of intrinsic and extrinsic factors. Unlike commercial Nd-Fe-B sintered magnets, FORCs of the (Nd,La,Ce)-Fe-B hot-deformed magnets are flat. Microstructure observation and magneto-optical Kerr effect (MOKE) microscopy showed the origin of the flat FORCs is the large volume fraction of the rare-earth-rich intergranular phase in the ultra-fine grained microstructure, which acts as pinning sites against magnetic domain wall propagation. Moreover, a relatively high remanent magnetization of 1.26 T for the (Nd,La,Ce)-Fe-B hot-deformed magnet is an additional merit compared to the previously proposed sintered magnets for the VMF motor application. This work demonstrates the (Nd,La,Ce)-Fe-B hot-deformed magnets are excellent candidates for VMF motor applications and thus widens the application spectrum for low-cost (Nd,La,Ce)-Fe-B magnets with a goal of well-balanced use of critical rare earth elements.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Magnetic Properties of Alloys · Magnetic properties of thin films · Magnetic and transport properties of perovskites and related materials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (38)

Show source-provided references
1. Principle of the variable-magnetic-force memory motor
2. Design and evaluation of a variable-flux flux-intensifying interior permanent magnet machine10.1109/TIA.2013.2273482 ↗
3. Design of a variable-flux permanent magnet synchronous motor for adjustable speed operation
4. Efficiency contours and loss minimization over a driving cycle of a variable flux-intensifying machine10.1109/TIA.2015.2404918 ↗
5. Magnet temperature effects on the useful properties of variable flux PM synchronous machines and a mitigating method for magnetization changes10.1109/TIA.2017.2674627 ↗
6. T. Sawa, K. Yamada, Permanent magnets and its fabrication method, JP2009302262A (2009).
7. T. Sawa, K. Yamada, Permanent magnets and its fabrication method, JP2010045068A (2010).
8. T. Ishiyama, M. Miwa, T. Watanabe, R-T-B-based permanent magnets, JP2017157834A (2017).
9. K. Takeda, S. Miyazaki, R-T-B based rare earth permanent magnets, JP2018019080A (2018).
10. T. Kajita, S. Miyazaki, K. Takeda, R-T-B-based magnet, motor and generator, US patent 2021 0242727 A1.
11. Temperature dependent magnetization reversal process of a Ga-doped Nd-Fe-B sintered magnet based on first-order reversal curve analysis10.1016/j.actamat.2019.08.004 ↗
12. First-order reversal curve analysis of a Nd-Fe-B sintered magnet with soft X-ray magnetic circular dichroism microscopy10.1016/j.actamat.2018.09.053 ↗
13. K. Takeda, S. Miyazaki, T. Kajita, abstract, 1-20 A spring meeting of Japan society of powder and powder metallurgy, 2019.
14. Coercivities of hot-deformed magnets processed from amorphous and nanocrystalline precursors10.1016/j.actamat.2016.10.026 ↗
15. Effect of Nd content on the microstructure and coercivity of hot-deformed Nd–Fe–B permanent magnets10.1016/j.actamat.2013.05.027 ↗
16. Relationship between the thermal stability of coercivity and the aspect ratio of grains in Nd-Fe-B magnets: experimental and numerical approaches10.1016/j.actamat.2019.11.038 ↗
17. Suppression of non-oriented grains in Nd-Fe-B hot-deformed magnets by Nb doping10.1016/j.scriptamat.2017.12.032 ↗
18. Magnetization and magnetic anisotropy of R2Fe14B measured on single crystals10.1063/1.336611 ↗
19. R2Fe14B materials: intrinsic properties and technological aspects10.1103/RevModPhys.63.819 ↗
20. Ce and La as substitutes for Nd in Nd2Fe14B-based melt-spun alloys and hot-deformed magnets: a comparison of structural and magnetic properties10.1016/j.jmmm.2019.01.095 ↗
21. Role of Co on the magnetic properties of Ce-substituted Nd-Fe-B hot-deformed magnets10.1016/j.actamat.2019.05.064 ↗
22. Thermally-stable high coercivity Ce-substituted hot-deformed magnets with 20% Nd reduction10.1016/j.actamat.2020.03.017 ↗
23. Research and development of Ce-containing Nd2Fe14B type alloys and permanent magnetic materials10.1016/j.jmst.2017.06.019 ↗
24. A reliable route for relieving the constraints of multi-main-phase Nd–La–Ce–Fe–B sintered magnets at high La–Ce substitution: (Pr, Nd)Hx grain boundary diffusion10.1016/j.scriptamat.2020.04.047 ↗
25. Manipulating Ce valence in RE2Fe14B tetragonal compounds by La-Ce Co-doping: resultant crystallographic and magnetic anomaly10.1038/srep30194 ↗
26. Influence of Ce content on the rectangularity of demagnetization curves and magnetic properties of Re-Fe-B magnets sintered by double main phase alloy method
27. Influence of LRE (Ce, Y, and La) on microstructure and magnetic properties of (Nd0.8LRE0.2)-Fe-B hot-deformed magnets10.1063/5.0072706 ↗
28. Temperature and field direction dependences of first-order reversalcurve (FORC) diagrams of hot-deformed Nd-Fe-B magnets10.1016/j.jmmm.2017.09.072 ↗
29. Dependence of magnetic, phase-transformation and microstructural characteristics on the Cu content of Nd–Fe–B sintered magnet10.1016/j.actamat.2013.11.063 ↗
30. Strategy for high-coercivity Nd-Fe-B magnets10.1016/j.scriptamat.2012.06.038 ↗
31. Mayergoyz · 1986 · 603e608
32. An investigation of multi-domain hysteresis mechanisms using FORC diagrams10.1016/S0031-9201(01)00241-2 ↗
33. Micromagnetic and preisach analysis of the first order reversal curves (FORC) diagram10.1063/1.1557656 ↗
34. gFORC: a graphics processing unit accelerated first-order reversal-curve calculator
35. Thermal stability of high-temperature compound La2Fe14B and magnetic properties of Nd-La-Fe-B alloys10.1016/j.jallcom.2020.157780 ↗
36. Phase precipitation behavior of rapidly quenched ternary La–Fe–B alloy and the effects of Nd substitution10.1088/2053-1591/aa7d85 ↗
37. Structure and chemical compositions of the grain boundary phase in Nd-Fe-B sintered magnets10.1016/j.actamat.2016.05.035 ↗
38. High performance hot-deformed Nd-Fe-B magnets10.1080/14686996.2020.1868049 ↗