journal article·2023-02

Enhanced mechanical strength in hot-rolled La-Fe-Si/Fe magnetocaloric composites by microstructure manipulation

Liya Miao, Xiang Lu, Zhiyang Wei, Yifei Zhang, Yuanxiang Zhang, Jian Liu

Acta Materialia· Volume 245
Publisher page

Abstract

La-Fe-Si-based alloys possess a giant magnetocaloric effect due to the sharp itinerant-electron metamagnetic transition. However, the relatively poor mechanical strength of these alloys impedes their practical application in the magnetic refrigeration system. In this study, we employed hot rolling to manipulate the microstructure, and thus to improve the mechanical strength of LaFe 11.6Si 1.4 /Fe composites. The microstructure and magnetic phase transition behavior have been systematically investigated by X-ray tomography, high-resolution transmission electron microscope and digital image correlation technique. We found that the bending strength of the hot-rolled LaFe 11.6Si 1.4 /Fe reached up to 176 MPa, which is about 26% higher than the non-rolled one. The refinement of the α-Fe particles plays a key role in hindering crack propagation and enhancing the mechanical strength of the hot-rolled sample. Additionally, the reduction of the La-rich phase and large-size pores is found to be beneficial to the mechanical strength enhancement. The hot-rolled composite shows a sharp metamagnetic transition with a maximum magnetic entropy change of 17 J kg −1 K −1 for 2 T magnetic field change. This study demonstrates that microstructure manipulation based on hot rolling is a feasible approach to improve the mechanical strength of La-Fe-Si materials.
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Research context

OpenAlex topics: Magnetic and transport properties of perovskites and related materials · Magnetic Properties of Alloys · Shape Memory Alloy Transformations

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (60)

Show source-provided references
1. Magnetic materials and devices for the 21st century: stronger, lighter, and more energy efficient10.1002/adma.201002180 ↗
2. Magnetocaloric effect: from materials research to refrigeration devices10.1016/j.pmatsci.2017.10.005 ↗
3. Giant magnetocaloric effect in Gd5(Si2Ge2)10.1103/PhysRevLett.78.4494 ↗
4. Transition-metal-based magnetic refrigerants for room-temperature applications10.1038/415150a ↗
5. Influence of negative lattice expansion and metamagnetic transition on magnetic entropy change in the compound LaFe11.4Si1.610.1063/1.1375836 ↗
6. Magnetocaloric effect and its relation to shape-memory properties in ferromagnetic Heusler alloys10.1088/0953-8984/21/23/233201 ↗
7. Itinerant-electron metamagnetic transition and large magnetovolume effects in La(FexSi1−x)13 compounds10.1103/PhysRevB.65.014410 ↗
8. Great magnetic entropy change in La(Fe, M)13 (M=Si, Al) with Co doping10.1088/1009-1963/9/7/016 ↗
9. Materials challenges for high performance magnetocaloric refrigeration devices10.1002/aenm.201200167 ↗
10. Novel design of La(Fe,Si)13 alloys towards high magnetic refrigeration performance10.1002/adma.201000177 ↗
11. Enhanced mechanical properties and large magnetocaloric effects in bonded La(Fe, Si)13-based magnetic refrigeration materials
12. Influence of powder bonding on mechanical properties and magnetocaloric effects of La0.9Ce0.1(Fe,Mn)11.7Si1.3H1.810.1016/j.jallcom.2015.02.131 ↗
13. LaFe11.6Si1.4/Cu magnetocaloric composites prepared by hot pressing
14. LaFe11.6Si1.4Hy/Sn magnetocaloric composites by hot pressing10.1016/j.scriptamat.2016.04.021 ↗
15. Outstanding comprehensive performance of La(Fe, Si)13Hy/In composite with durable service life for magnetic refrigeration10.1002/aelm.201700636 ↗
16. Study of the microstructure, mechanical, and magnetic properties of LaFe11.6Si1.4Hy/Bi magnetocaloric composites10.3390/ma11060943 ↗
17. LaFe11.6Si1.4/Pr40Co60 magnetocaloric composites for refrigeration near room temperature10.1016/j.jallcom.2021.159796 ↗
18. High-performance solid-state cooling materials: balancing magnetocaloric and non-magnetic properties in dual phase La-Fe-Si10.1016/j.actamat.2016.12.014 ↗
19. Excellent mechanical properties and age stability of hydrogenated La0.8Ce0.2Fe12.5Mn0.2Si1.3Hδ plates with extra Fe10.1016/j.jallcom.2018.01.381 ↗
20. Correlation between microstructure and martensitic transformation, mechanical properties and elastocaloric effect in Ni–Mn-based alloys10.1016/j.intermet.2019.106579 ↗
21. A eutectic dual-phase design towards superior mechanical properties of heusler-type ferromagnetic shape memory alloys10.1016/j.actamat.2019.09.054 ↗
22. Direct formation of La(Fe,Si)13 phase with enhanced mechanical property of off-stoichiometric La1.7Fe11.6Si1.4 alloys by directional solidification10.1016/j.jallcom.2019.152694 ↗
23. Large entropy change, adiabatic temperature change, and small hysteresis in La(Fe,Mn)11.6Si1.4 strip-cast flakes10.1016/j.jmmm.2014.10.035 ↗
24. A high-throughput study of magnetocaloric materials: gradient solidification applied to La-Fe-Si10.1016/j.intermet.2019.02.016 ↗
25. Structural and magnetic properties of magnetocaloric LaFe13–xSix compounds synthesized by high energy ball-milling10.1016/j.intermet.2010.07.022 ↗
26. X-ray tomography study on porosity and particle size distribution in in situ Al-4.5Cu-5TiB2 semisolid rolled composites10.1007/s11837-019-03385-z ↗
27. Effect of hot rolling and primary annealing on the microstructure and texture of a β-stabilised γ-TiAl based alloy10.1016/j.actamat.2016.12.056 ↗
28. On the microstructural evolution and accelerated magnetocaloric phase formation in La-Fe-Si alloys by hot forging deformation10.1016/j.actamat.2021.117334 ↗
29. Plastically deformed Gd-X (X = Y, In, Zr, Ga, B) solid solutions for magnetocaloric regenerator of parallel plate geometry10.1016/j.jallcom.2018.04.264 ↗
30. Unique layered microstructure and magnetocaloric effect in hot-rolled La-Fe-Co-Si plates10.1016/j.jmmm.2022.169711 ↗
31. The diffusion process of La, Fe and Si through the La(Fe,Si)13 phase - a Fick's 1st law based approach10.1016/j.jallcom.2022.163688 ↗
32. In-situ microstructural control of A6082 alloy to modify second phase particles by melt conditioned direct chill (MC-DC) casting process – a novel approach
33. Tishin · 1999
34. Multicaloric effect in synergic magnetostructural phase transformation Ni-Mn-Ga-In alloys
35. Fast and accurate lacunarity calculation for large 3D micro-CT datasets10.1016/j.actamat.2021.116970 ↗
36. Grain boundary migration and Zener pinning in a nanocrystalline Cu-Ag alloy10.1088/1361-651X/aba737 ↗
37. Impact of interface structure on functionality in hot-pressed La-Fe-Si/Fe magnetocaloric composites10.1016/j.actamat.2020.04.042 ↗
38. The effect of hydrogen on the multiscale mechanical behaviour of a La(Fe,Mn,Si)13-based magnetocaloric material10.1016/j.jallcom.2022.164274 ↗
39. Micromechanics of crack nucleation during indentation10.1007/BF00611482 ↗
40. Lawn · 1993
41. Mechanical properties of the magnetocaloric intermetallic LaFe11.2Si1.8 alloy at different length scales10.1016/j.actamat.2018.11.038 ↗
42. Intermetallic composites toughened with ductile reinforcements
43. Crack-interface grain bridging as a fracture resistance mechanism in ceramics: I, experimental study on alumina10.1111/j.1151-2916.1987.tb04982.x ↗
44. An improved crack-bridging model for rigid particle-polymer composites10.1016/j.engfracmech.2019.02.028 ↗
45. Determination of the entropy changes in the compounds with a first-order magnetic transition
46. Systematic study of the microstructure, entropy change and adiabatic temperature change in optimized La–Fe–Si alloys10.1016/j.actamat.2011.02.033 ↗
47. Volume dependence of the first-order transition temperature for RCo2 compounds10.1088/0305-4608/12/8/021 ↗
48. On a generalised approach to first and second order magnetic transitions10.1016/0031-9163(64)91158-8 ↗
49. Very large magnetic entropy change near room temperature in LaFe11.2Co0.7Si1.110.1063/1.1447592 ↗
50. Elastocaloric effect of all-d-metal Heusler NiMnTi(Co) magnetic shape memory alloys by digital image correlation and infrared thermography10.1063/1.5077076 ↗
51. Large elastocaloric effect in directionally solidified all-d-metal Heusler metamagnetic shape memory alloys10.1016/j.actamat.2020.02.045 ↗
52. Influence of ball milling process on microstructure, mechanical and thermal expansion properties of ZrMgMo3O12/Al-40Si composites10.1016/j.micron.2022.103245 ↗
53. Local evolution of the elastocaloric effect in TiNi-based films10.1007/s40830-015-0014-3 ↗
54. Giant and reversible room-temperature elastocaloric effect in a single-crystalline Ni-Fe-Ga magnetic shape memory alloy10.1038/srep25500 ↗
55. The interaction of a crack front with a second-phase dispersion10.1080/14786437008221068 ↗
56. Consolidation–microstructure–property relationships in bulk nanoceramics and ceramic nanocomposites: a review10.1179/174328007X160281 ↗
57. Effects of pore position in depth on stress/strain concentration and fatigue crack initiation10.1007/s11661-011-0947-x ↗
58. Effects of processing parameters on microstructure development in X70 pipeline steel10.4028/www.scientific.net/MSF.654-656.298 ↗
59. Microtexture, grain boundary character distribution and secondary working embrittlement of high strength IF steels10.1016/j.msea.2004.09.024 ↗
60. Unveiling the semicoherent interface with definite orientation relationships between reinforcements and matrix in novel Al3BC/Al composites10.1021/acsami.6b08913 ↗