Deformation mechanisms and their role in the lack of ductility in the refractory-based high entropy alloy AlMo0.5NbTa0.5TiZr

The deformation mechanisms in the refractory high entropy alloy AlMo _0.5NbTa _0.5TiZr have been investigated, with their potential impact on ductility. Specifically, the modes of plasticity active in the B2 matrix and in an alloyed version of the phase Al ₄Zr ₅ found at grain and subgrain boundaries were explored by use of nano-indentation. For the B2 phase, a combination of weak-beam dark-field and superlattice imaging revealed dissociation of 〈 111 〉 superdislocations into two superpartial dislocations, bounding an anti-phase boundary (APB), following the reaction: a 〈 111 〉 = a / 2 〈 111 〉 +APB+ a / 2 〈 111 〉 . The dislocations in the B2 phase exhibited long, relatively straight screw segments and short edge segments, such that the mobility of the edge dislocations appears to be higher than that of the screw segments. Evidence of a B2 to bcc slip transmission process has been observed through use of stereo-pair imaging and anaglyph construction. This process involves the transmission of slip from the B2 matrix, followed by the decorrelated motion of the two a / 2 〈 111 〉 dislocations in the bcc precipitate, demonstrated by the increased separation of the dislocations within the bcc phase. Regarding the deformation of the Al ₄Zr ₅ intermetallic phase, it was found that indentation of this phase resulted in no evidence of dislocation generation and motion, and cracking at the edges of the given indent. It has been concluded that the lack of plasticity of this phase is the cause of the room temperature brittle nature of this alloy.