Highly Nonlinear Optical Configurationally Locked Triene Crystals Based on 3,5-Dimethyl-2-cyclohexen-1-one
Source abstract
Abstract
New organic nonlinear optical configurationally locked polyene (CLP) crystals based on 3,5-dimethyl-2-cyclohexen-1-one have been designed and their supramolecular organization investigated. Acentric single crystals 2-(5-methyl-3-(4-(pyrrolidin-1-yl)styryl)cyclohex-2-enylidene)malononitrile (MH2) of large sizes with a maximal side length of up to 1 cm have been grown from acetonitrile solution. The acentric MH2 crystals present the monoclinic space-group symmetry Cc and exhibit a large macroscopic nonlinearity with a similar powder second-harmonic generation efficiency at 1.9 µm as the well-studied DAST ( N,N -dimethylamino- N ′-methylstilbazolium p -toluenesulfonate), which is about seven times larger than that of analogous CLP crystals studied previously. The microscopic and macroscopic nonlinearities are also investigated theoretically using quantum chemical calculations.
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Research context
OpenAlex topics: Nonlinear Optical Materials Research · Crystallography and molecular interactions · Crystal structures of chemical compounds
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Nonlinear Optics Laboratory, ETH Zurich, CH-8093 Zurich, Switzerland, Department of Molecular Science and Technology, Ajou University, Suwon 443-749, Korea, Department of Chemistry and School of Molecular Science (BK 21), Korea Advanced Institute of Science and Technology (KAIST), Daejeon 305-701, Korea, Laboratory of Crystallography, ETH Zurich, CH-8093 Zurich, Switzerland, and Division of Energy Systems Research and Department of Chemistry, Ajou University, Suwon 443-749, Korea
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