A novel approach to coating for improving the comprehensive high-temperature service performance of TiAl alloys
Source abstract
Abstract
TiAl alloys, with half the density of nickel-based superalloys, are highly suitable for aerospace applications requiring lightweight materials. However, they tend to form a nonprotective mixed oxide film on their surface at high temperatures. This oxide film is prone to cracking, which can lead to long-term high-temperature oxidation surface degradation, thereby reducing their high-temperature creep and fatigue resistance. Surface cracks on the oxide film further aggravated the brittleness of the TiAl intermetallic compounds after high-temperature exposure. While coatings are typically applied to promote the formation of dense oxides for surface protection, they primarily enhance oxidation resistance. However, this improvement comes at the cost of reducing the high-temperature creep and fatigue resistance and the room-temperature plasticity of TiAl alloys. This study introduced an electroless coating method to deposit a Pt coating, approximately 200 nm thick, on the surface of TiAl alloys. During high-temperature applications, the Pt dispersed as nanoparticles within the oxide layer, enhancing the oxide`s plasticity. This oxide structure considerably improved the high-temperature creep and fatigue properties of TiAl alloys, while enhancing their room-temperature tensile properties after oxidation. This approach offers a novel strategy for designing surface coatings for high-temperature components.
Source: expertdata · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Intermetallics and Advanced Alloy Properties · MXene and MAX Phase Materials · Energetic Materials and Combustion
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (41)
Show source-provided references
1. Improvement of steam oxidation resistance of the γ-TiAl alloy with microarc oxidation coatings at 900–1200°C10.1016/j.corsci.2022.110711 ↗
2. Advances in Gammalloy Materials–Processes–Application Technology: Successes, Dilemmas, and Future10.1007/s11837-018-2747-x ↗
3. High temperature materials for aerospace applications: Ni-based superalloys and γ-TiAl alloys10.1016/j.crhy.2018.10.002 ↗
4. Gamma Titanium Aluminide Alloys
5. Polysynthetic twinned TiAl single crystals for high-temperature applications10.1038/nmat4677 ↗
6. Microstructure evolution and cyclic oxidation performance of Cr2AlC as active diffusion barrier for NiCrAlY coating on TiAl alloy10.1016/j.corsci.2023.111696 ↗
7. Microstructure and mechanical properties of high niobium β-γ TiAl and IN718 alloy joints diffusion bonded by spark plasma sintering
8. Interdiffusion mechanism at the interface between TiAl alloy and NiCoCrAlY bond coating10.1016/j.surfcoat.2022.128687 ↗
9. High temperature oxidation resistance of γ-TiAl alloy with pack aluminizing and electrodeposited SiO2 composite coating10.1016/j.corsci.2018.10.031 ↗
10. Improvement of oxidation resistance of γ-TiAl at 900 and 1000°C through hot-dip aluminizing10.1007/s11085-009-9187-5 ↗
11. Effect of intermetallic coatings on the tensile properties of a γ-TiAl based TNM alloy10.1016/j.msea.2017.05.077 ↗
12. Influence of an oxidation protective coating upon hot corrosion and mechanical behaviour of Ti-48Al-2Cr-2Nb alloy10.1016/j.intermet.2011.03.014 ↗
13. Pack cementation coatings on Ti3Al-Nb alloys to modify the high-temperature oxidation properties10.1016/S0257-8972(00)00546-6 ↗
14. On the influence of coating and oxidation on the mechanical properties of a γ-TiAl based alloy10.1016/j.intermet.2008.07.003 ↗
15. Effects of preexposure duration and temperature on interfacial Diffusion-Induced fatigue life degradation of MCrAlY-Coated single crystal superalloys10.1016/j.ijfatigue.2023.107977 ↗
16. Influence of MCrAlY coating on low-cycle fatigue behavior of a directionally solidified nickel-based superalloy in hot corrosive environment10.1016/j.msea.2016.09.064 ↗
17. Thermal fatigue behavior of thermal barrier coatings with the MCrAlY bond coats by cold spraying and low-pressure plasma spraying10.1016/j.surfcoat.2010.08.144 ↗
18. Effect of MCrAlY coating on the low-cycle fatigue behavior of a directionally solidified nickel-base superalloy at different temperatures10.1016/j.ijfatigue.2015.02.018 ↗
19. Effect of Ru in the underlying superalloy on isothermal oxidation performance of Pt-Al coating10.1016/j.corsci.2023.111415 ↗
20. The effects of tensile stress on the microstructure evolution and elemental interdiffusion behavior of (Ni,Pt)Al coating and nickel-based superalloy at 1100°C for 200 h10.1016/j.jallcom.2023.169422 ↗
21. The interaction between Dy, Pt and Mo during the short-time oxidation of (γ’ + β) two-phase NiAl coating on single crystal superalloy with high Mo content10.1016/j.surfcoat.2021.127999 ↗
22. Oxidation study of Pt–Al based coatings on γ-TiAl at 950°C10.1016/j.surfcoat.2015.12.043 ↗
23. Effect of a magnetron sputtered (Al2O3–Y2O3)/(Pt–Au) laminated coating on hot corrosion resistance of 8Nb–TiAl alloy10.1016/j.surfcoat.2011.11.028 ↗
24. Al2O3–ZrO2–Pt composite coatings prepared by cathode plasma electrolytic deposition on the TiAl alloy10.1016/j.surfcoat.2015.10.050 ↗
25. High temperature oxidation behavior of TiAl alloy with electrodeposited SiOC coating10.1016/j.corsci.2023.111491 ↗
26. Microstructure and ablation behavior of TiAl alloy with in situ HfSi2-HfO2-SiO2 nanocomposite ceramic coating by LPDS technique10.1016/j.surfcoat.2023.130268 ↗
27. LAMMPS-a flexible simulation tool for particle-based materials modelling at the atomic, meso, and continuum scales10.1016/j.cpc.2021.108171 ↗
28. Misfit-energy-increasing dislocations in vapour-deposited CoFe/NiFe multilayers10.1103/PhysRevB.69.144113 ↗
29. Visualization and analysis of atomistic simulation data with OVITO–the Open Visualization Tool10.1088/0965-0393/18/1/015012 ↗
30. Solubility relations in ternary solid solutions of ionic compounds10.1063/1.1747458 ↗
31. Oxidation protection of TNM alloys with Al-rich γ-TiAl-based coatings10.1016/j.jallcom.2023.172343 ↗
32. Improving high temperature oxidation resistance of TiAl alloy via hierarchical Ti5Si3-Ti2AlC precipitation strategy10.1016/j.corsci.2024.111834 ↗
33. Isothermal oxidation behavior of high-Nb-containing TiAl alloys doped with W, B, Y, and C/Si10.1016/j.corsci.2023.110980 ↗
34. Cyclic oxidation behavior of Nb/Mn/Si alloying beta-gamma TiAl alloys10.1016/S1003-6326(22)66095-3 ↗
35. Diffusion and high temperature oxidation of metals
36. Influence of Pt on oxidation behavior of CoNiCrAlY alloy10.1016/S1875-5372(12)60026-5 ↗
37. Examination of the platinum effect on the oxidation behavior of nickel-aluminide coatings10.1016/j.surfcoat.2007.06.013 ↗
38. Trifunctional nanoprecipitates ductilize and toughen a strong laminated metastable titanium alloy10.1038/s41467-023-37155-y ↗
39. A strong fracture-resistant high-entropy alloy with nanobridged honeycomb microstructure intrinsically toughened by 3D-printing10.1038/s41467-024-45178-2 ↗
40. Making ultrastrong steel tough by grain-boundary delamination
41. Hierarchical crack buffering triples ductility in eutectic herringbone high-entropy alloys