journal article·2020-03Open access

Correlation between Grain Boundary Migration and Stress Corrosion Cracking of Alloy 600 in Hydrogenated Steam

L. Volpe, M.G. Burke, F. Scenini

Acta Materialia· Volume 186

Abstract

Solution-annealed Alloy 600 samples were tested under active load conditions in a superheated low pressure H2-steam environment over a range of oxidising potentials relevant to Primary Water Stress Corrosion Cracking (PWSCC). Increased SCC susceptibility was observed for potentials the more reducing than the Ni/NiO transition where a deeper Preferential Intergranular Oxidation (PIO) occurred. Advanced microstructural analysis clearly showed that SCC initiated along the grain boundaries that exhibited Diffusion-Induced Grain Boundary Migration (DIGM), as well as enrichments in Al and Ti. Rather than the result of a single dominant mechanism, the initiation of SCC in Ni-base alloys involves the synergistic interactions between DIGM and the formation of Al- and Ti-enriched oxides, promoting PIO that can fracture with applied stress.
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Research context

OpenAlex topics: Hydrogen embrittlement and corrosion behaviors in metals · High-Temperature Coating Behaviors · High Temperature Alloys and Creep

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