journal article·2023-12Open access

On the precipitation mechanisms of β-Mg2Si during continuous heating of AA6061

Robert Kahlenberg, Tomasz Wojcik, Georg Falkinger, Anna Lena Krejci, Benjamin Milkereit, Ernst Kozeschnik

Acta Materialia· Volume 261

Abstract

In the present work, we study the evolution of metastable and Cu-containing precursor precipitates into stable β-Mg2Si using in-situ transmission electron microscopy during continuous heating of an AA6061 aluminum alloy. The experiments indicate that the transformation into stable β-Mg2Si involves the release of Al and Cu atoms into the matrix phase combined with the rearrangement of Mg and Si at the interfaces. Nucleation of the β-Mg2Si precipitates predominantly occurs at the interface between the precursors and the aluminum matrix and at dispersoids. The term precipitate-related transformation is used to emphasize the reaction mechanism, where a new product precipitate nucleates next to a precursor and consumes it at its original location predominantly via interface diffusion. The in-situ investigations are complemented by an analysis of bulk samples and a comparison with differential scanning calorimetry measurements, which show excellent agreement.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Aluminum Alloy Microstructure Properties · Aluminum Alloys Composites Properties · Magnesium Alloys: Properties and Applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (75)

Show source-provided references
1. A calorimetric study of precipitation in commercial aluminium alloy 606110.1007/BF00719697 ↗
2. The precipitation sequence in Al–Mg–Si alloys10.1016/S1359-6454(98)00059-7 ↗
3. Precipitation sequence of various kinds of metastable phases in Al-1.0mass% Mg2Si-0.4mass% Si alloy10.1023/A:1004769305736 ↗
4. Metastable phases in an Al-Mg-Si alloy containing copper10.1007/s11661-001-0219-2 ↗
5. Comparison of precipitates between excess Si-type and balanced-type Al-Mg-Si alloys during continuous heating10.1007/s11661-005-0321-y ↗
6. The effect of Cu on precipitation in Al–Mg–Si alloys10.1080/14786430701287377 ↗
7. Precipitates in aluminium alloys
8. Correlation between the microstructural evolution of a 6061 aluminium alloy and the evolution of its thermoelectric power10.1016/S1359-6454(00)00085-9 ↗
9. The structure of the metastable precipitates formed during ageing of an Al-Mg-Si alloy10.1080/14786437208221015 ↗
10. The crystal structure of the β′ phase in Al–Mg–Si alloys10.1016/j.actamat.2007.02.032 ↗
11. Atomic-resolution chemical mapping of ordered precipitates in Al alloys using energy-dispersive X-ray spectroscopy10.1016/j.micron.2017.02.007 ↗
12. Torsæter · 2008
13. The Crystal Structure of Al(x)Cu2Mg(12-x)Si7, (h-AlCuMgSi)10.3891/acta.chem.scand.34a-0001 ↗
14. Crystal structure and stability of complex precipitate phases in Al–Cu–Mg–(Si) and Al–Zn–Mg alloys10.1016/S1359-6454(01)00229-4 ↗
15. Clustering in age-hardenable aluminum alloys10.1002/adem.201800255 ↗
16. Mechanisms controlling the artificial aging of Al–Mg–Si Alloys10.1016/j.actamat.2011.02.010 ↗
17. Influence of interrupted quenching on artificial aging of Al–Mg–Si alloys10.1016/j.actamat.2012.04.026 ↗
18. Natural ageing clustering under different quenching conditions in an Al-Mg-Si alloy10.1016/j.scriptamat.2020.08.046 ↗
19. Natural and artificial ageing in aluminium alloys – the role of excess vacancies10.1016/j.actamat.2021.117014 ↗
20. Early stages of solute clustering in an Al–Mg–Si alloy10.1016/j.actamat.2015.02.019 ↗
21. Precipitation strengthening of aluminum alloys by room-temperature cyclic plasticity10.1126/science.aav7086 ↗
22. Vacancy behavior and solute cluster growth during natural aging of an Al-Mg-Si alloy10.1007/s11661-012-1257-7 ↗
23. Effect of natural ageing or pre-ageing on the evolution of precipitate structure and strength during age hardening of Al–Mg–Si alloy AA 601610.1016/j.msea.2019.05.073 ↗
24. Effects of natural aging after pre-aging on clustering and bake-hardening behavior in an Al–Mg–Si alloy10.1016/j.scriptamat.2016.01.019 ↗
25. Precipitation kinetics and transformation of metastable phases in Al–Mg–Si alloys10.1016/j.actamat.2006.06.005 ↗
26. In situ heating TEM observations of evolving nanoscale Al–Mg–Si–Cu precipitates10.1111/jmi.12845 ↗
27. The effect of low Cu additions on precipitate crystal structures in overaged Al-Mg-Si(-Cu) alloys10.1016/j.matchar.2019.110087 ↗
28. The evolution of precipitate crystal structures in an Al-Mg-Si(-Cu) alloy studied by a combined HAADF-STEM and SPED approach10.1016/j.matchar.2018.05.031 ↗
29. Study of intergrown L and Q′ precipitates in Al–Mg–Si–Cu alloys10.1016/j.scriptamat.2011.01.008 ↗
30. Applying precipitate–host lattice coherency for compositional determination of precipitates in Al–Mg–Si–Cu alloys10.1080/14786435.2012.693214 ↗
31. Structural phase transition in Al-Cu-Mg-Si alloys by transmission electron microscopy study on an Al-4 wt% Cu-1 wt% Mg-Ag alloy reinforced by SiC particles10.1080/01418619908212027 ↗
32. Transmission electron microscopy study of the β′ phase (Al–Mg–Si alloys) and QC phase (Al–Cu–Mg–Si alloys): ordering mechanism and crystallographic structure10.1016/S1359-6454(00)00057-4 ↗
33. Study of the precipitate evolution mechanism in an Al-Mg-Si-Cu alloy with Si-rich and low Cu composition10.1016/j.matchar.2022.112167 ↗
34. Interactive transformation mechanisms of multiple metastable precipitates in a Si-rich Al-Mg-Si alloy10.1080/14786435.2022.2051633 ↗
35. Study of the Q′ (Q)-phase precipitation in Al–Mg–Si–Cu alloys by quantification of atomic-resolution transmission electron microscopy images and atom probe tomography10.1007/s10853-019-03427-6 ↗
36. Influence of cooling after homogenisation and reheating to extrusion on extrudability and final Properties of AA 6063 and AA6082 alloys10.4028/www.scientific.net/MSF.396-402.399 ↗
37. Review of the quench sensitivity of aluminium alloys: analysis of the kinetics and nature of quench-induced precipitation10.3390/ma12244083 ↗
38. In-situ study of phase transformations during homogenization of 6005 and 6082 Al alloys10.1016/j.jallcom.2017.07.149 ↗
39. In-situ study of phase transformations during homogenization of 6060 and 6063 Al alloys10.1016/j.jpcs.2018.11.013 ↗
40. Continuous cooling precipitation diagrams of Al–Mg–Si alloys10.1016/j.msea.2012.04.033 ↗
41. Computational analysis of heterogeneous nucleation and precipitation in AA6005 Al-alloy during continuous cooling DSC experiments10.1016/j.mtla.2022.101538 ↗
42. Investigation of quench sensitivity and transformation kinetics during isothermal treatment in 6082 aluminum alloy10.1016/j.matdes.2011.03.016 ↗
43. Time–temperature–property curves for quench sensitivity of 6063 aluminum alloy10.1016/S1003-6326(13)62426-7 ↗
44. Study of Quench sensitivity and microstructure evolution of Al-Mg-Si alloy sheets10.4028/p-w317if ↗
45. Morphology and crystallography of β-Mg2Si precipitation in Al-Mg-Si alloys10.2320/matertrans.42.2576 ↗
46. Ageing processes in Al-Mg-Si alloys during continuous heating10.2320/matertrans.43.246 ↗
47. Cube-phase in excess Mg-type Al-Mg-Si alloy studied by EFTEM10.1007/s10853-006-7819-6 ↗
48. The aging characteristics of aluminum alloys electron transmission studies of Al-Mg-Si alloys
49. Precipitation reactions in an aluminium 1wt.% Mg,Si alloy10.1515/ijmr-1979-700810 ↗
50. C. Cayron, TEM study of interfacial reactions and precipitation mechanisms in Al2O3 short fiber or high volume fraction SiC particle reinforced Al-4Cu-1 Mg-0.5Ag squeeze-cast composites, Federal Institute of Technology Lausanne (EPFL), 2000, https://doi.org/10.5075/epfl-thesis-2246.
51. A study of high-temperature precipitation in Al–Mg–Si alloys with an excess of silicon10.1023/A:1004585216084 ↗
52. In situ high-energy X-ray diffraction of precipitation and dissolution reactions during heating of Al alloys10.1007/s10853-021-06548-z ↗
53. Direct observation of change from θ′ to θ phase in precipitation of an aluminium-copper alloy10.2320/jinstmet1952.27.12_599 ↗
54. Mechanisms of formation of θ and dissolution of θ′ precipitates in an Al-4% Cu alloy10.1016/0001-6160(66)90298-7 ↗
55. Analysis of the evolution of Mg 2 Si precipitates during continuous cooling and subsequent re-heating of a 6061 aluminum alloy with differential scanning calorimetry and a simple model10.1515/ijmr-2021-8443 ↗
56. P. Stadelmann, JEMS (Java Electron Microscopy Software) (2019). https://www.jems-swiss.ch/Home/jemsWebSite/jems.html (accessed 01.01.2022).
57. Formation of multiple orientation relationships of Q precipitates in Al–Mg–Si–Cu alloys10.1016/j.scriptamat.2014.05.013 ↗
58. Transmission electron microscopy study of a precipitate which forms in the Al-Mg-Si system10.1080/095008396180407 ↗
59. Phase relations and precipitation in Al–Mg–Si alloys with Cu additions10.1016/S0079-6425(03)00031-8 ↗
60. Structure of Some aluminium-iron-magnesium-manganese- silicon alloys10.1515/ijmr-1975-661008 ↗
61. Formation of a modified β′ phase in aluminum alloy 606110.1016/0036-9748(84)90362-4 ↗
62. Transforming solid-state precipitates via excess vacancies10.1038/s41467-020-15087-1 ↗
63. Thermo-kinetic modeling of Cu precipitation in α-Fe10.1016/j.actamat.2015.08.042 ↗
64. Conversion of MX nitrides to Z-phase in a martensitic 12% Cr steel10.1016/j.actamat.2009.09.045 ↗
65. Atomic resolution imaging of precipitate transformation from cubic TaN to tetragonal CrTaN10.1016/j.scriptamat.2011.11.005 ↗
66. Precipitate transformation from NiAl-type to Ni2AlMn-type and its influence on the mechanical properties of high-strength steels10.1016/j.actamat.2016.03.024 ↗
67. On the nucleation and dissolution process of Z-phase Cr(V,Nb)N in martensitic 12%Cr steels10.1016/j.msea.2008.11.019 ↗
68. High-resolution electron microscopy studies of the structure of Cu precipitates in α-Fe10.1080/01418619408242533 ↗
69. Carbide precipitation in 2.25 Cr-1 Mo bainitic steel: effect of heating and isothermal tempering conditions10.1007/s11661-017-4045-6 ↗
70. Sequences of precipitate nucleation10.1007/BF00754490 ↗
71. An electron microscope investigation of the interfacial structure of semi-coherent precipitates
72. Thermodynamic model for lattice point defect-mediated semi-coherent precipitation in alloys10.1038/s43246-021-00136-z ↗
73. Modeling Mg2Si dissolution in an AA6063 alloy during preheating to the extrusion temperature
74. Dissolution and precipitation behaviour during continuous heating of Al–Mg–Si alloys in a wide range of heating rates10.3390/ma8052830 ↗
75. Secondary precipitation during homogenization of Al-Mg-Si alloys: influence on high temperature flow stress10.1016/j.msea.2017.01.074 ↗