journal article·2022-08-04

Electronic Topological Transition of 2D Boron by the Ion Exchange Reaction

Xiaoni Zhang, Yuki Tsujikawa, Ikuma Tateishi, Masahito Niibe, Tetsuya Wada, Masafumi Horio, Miwa Hikichi, Yasunobu Ando, Kunio Yubuta, Takahiro Kondo, Iwao Matsuda

The Journal of Physical Chemistry C· Volume 126· Issue 30
Publisher page

Abstract

We systematically investigated electronic evolutions of nonsymmorphic borophene with chemical environments that were realized by the ion exchange method. Electronic structures can be characterized by the topological invariant. Spectroscopic experiments and DFT calculations unveiled that a sheet of hydrogenated borophene (borophane) is the Dirac nodal loop semimetal ( ), while a layered crystal of YCrB 4 is an insulator ( ). The results demonstrate the electronic topological transition by replacement of the counter atoms on the nonsymmorphic borophene layer.
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Research context

OpenAlex topics: Graphene research and applications · Boron and Carbon Nanomaterials Research · Diamond and Carbon-based Materials Research

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Institute for Solid State Physics (ISSP), The University of Tokyo, Kashiwa, Chiba 277-8581, Japan

RIKEN Center for Emergent Matter Science, Wako, Saitama 351-0198, Japan

Faculty of Pure and Applied Sciences, University of Tsukuba, Tsukuba, Ibaraki 305-8573, Japan

CD-FMat, National Institute of Advanced Industrial Science and Technology (AIST), Tsukuba, Ibaraki 305-8560, Japan

Faculty of Engineering, Kyushu University, Fukuoka, Fukuoka 819-0395, Japan

Funding

Core Research for Evolutional Science and Technology · Japan Society for the Promotion of Science

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