Unexpected sluggish martensitic transformation in a strong and super-ductile high-entropy alloy of ultralow stacking fault energy

Displacive martensitic transformation usually prevails in face-centered cubic (FCC) steels and high-entropy alloys (HEAs) of low stacking fault energy (SFE; e.g., <15 mJ/m ²) upon deformation. Here, we present and rationalize an unexpectedly sluggish and suppressed martensitic transformation behavior in a newly developed non-equiatomic HEA (Fe ₃₀Ni ₂₀Co ₂₀Cr ₂₀Si ₁₀, at.%) with an ultralow SFE, i.e., ∼7 mJ/m ² measured by weak-beam dark-field scanning transmission electron microscopy (STEM) at room temperature. The recrystallized FCC HEA with an average grain size of ∼14.9 µm shows an ultimate tensile strength of 903 MPa and a fracture elongation of ∼83.1 %. Plastic deformation of this alloy with ultralow SFE is characterized by the intensive formation of stacking faults (SFs), whereas the volume fraction of hexagonal close-packed (HCP) martensite is very low even at cold-rolled state with an equivalent strain of 1.85, i.e., < 8.3 % according to neutron diffraction analysis. Atomic-scale TEM observation demonstrates that chemical short-range order (CSRO) domains are present in the FCC solid solution. Apart from contributing to the high strength, the CSRO domains and atomic size misfit (2.36 %) promoted by the high content of Si are regarded to enhance the local barrier for the successive accumulation of SFs, hindering the formation of HCP martensite and mechanical twin. The uniform formation of SFs in the FCC matrix upon deformation effectively alleviates strain localization, contributing to the sustained strain-hardening ability and super-ductility. These insights suggest a strategy to design low-SFE alloys with excellent mechanical properties via manipulating the rate of martensitic transformation by CSROs and atomic size misfit.