A Multinuclear NMR Study of Six Forms of AlPO-34: Structure and Motional Broadening

We report a study of the CHA-type aluminophosphate AlPO-34, prepared with six different structure-directing agents (SDAs): piperidine (pip), morpholine (mor), pyridine (pyr), 1,4,8,11-tetraazacyclotetradecane (cyclam), 1,3-dimethylimidazolium (dmim) chloride, and 1-ethyl-3-methylimidazolium (emim) bromide. Using a combination of solid-state NMR spectroscopy, periodic density functional theory (DFT) calculations, and synchrotron X-ray diffraction, we show that, even in crystallographically well-ordered materials such as AlPO-34 with dmim as the SDA, local disorder may be present. For such disordered structures, where it is challenging to use DFT to assign NMR spectra, we show that the 31 P isotropic chemical shift can be predicted accurately using the mean P–O bond length and P–O–Al bond angle, in an extension of previous work. Variable-temperature 27 Al NMR reveals the presence of microsecond-time scale dynamics in all forms of AlPO-34, with two different motional regimes observed, depending on whether structural H 2 O is present. H 2 O is detected in AlPO-34 prepared with mor as the SDA, although this material was previously reported as anhydrous, suggesting that this form of AlPO-34 may be hygroscopic despite the presence of the SDAs within the pores.