journal article·2014-02-20

Laser Power Dependent Surface-Enhanced Raman Spectroscopic Study of 4-Mercaptopyridine on Uniform Gold Nanoparticle-Assembled Substrates

Xiao-Shan Zheng, Pei Hu, Jin-Hui Zhong, Cheng Zong, Xiang Wang, Bi-Ju Liu, Bin Ren

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Abstract

A facile procedure was introduced to prepare uniform and highly active substrates assembled with gold nanoparticles for surface-enhanced Raman spectroscopy (SERS). The laser power and time dependent SERS study of 4-mercaptopyridine (4-MPy) adsorbed on this substrate was investigated. The relative intensity of the characteristic Raman peak pair (1575 and 1610 cm –1 ) was found to change with the laser power and the exposure time. The spectral changes may originate from change in the fraction of the double-end-bonded and the single-end-bonded states of 4-Mpy adsorbed on the gold nanoparticle-assembled substrate. In addition, this study offers a way to avoid the effect of laser power to achieve reliable spectral response to other factors.
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Research context

OpenAlex topics: Gold and Silver Nanoparticles Synthesis and Applications · Electrochemical Analysis and Applications · Nanocluster Synthesis and Applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

State Key Laboratory of Physical Chemistry of Solid Surfaces, the MOE Key Laboratory of Spectrochemical Analysis & Instrumentation, and Department of Chemistry, College of Chemistry and Chemical Engineering and Collaborative Innovation Center of Chemistry of Energy Materials, Xiamen University, Xiamen 361005, China

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