Controlled Fabrication of Iron Oxide/Mesoporous Silica Core–Shell Nanostructures

A simple and reproducible method for the preparation of well-defined iron oxide/mesoporous silica core–shell nanostructure is provided. Iron oxide nanocubes with a narrow size distribution were synthesized through a novel ethanol/acetic acid system using Fe(NO 3 )·9H 2 O as an iron source and polyvinylpyrrolidone as a capping agent under mild solvothermal conditions (200 °C). These monodisperse nanoparticles were used directly as the core for the deposition of a mesoporous silica shell via a sol–gel process, resulting in uniform core–shell Fe 2 O 3 @SiO 2 composites with tailored silica shell thickness and controllable core morphology. In addition, composition as well as magnetization of the reduced core–shell composites could easily be controlled by a reduction process. Furthermore, the iron oxide core in Fe 2 O 3 @SiO 2 could be completely etched to produce hollow SiO 2 nanospheres. The mechanism of formation of the core–shell structure was also proposed by the aid of IR spectrum analysis.