journal article·2021-01Open access

Plastic deformation of single crystals of the equiatomic Cr−Mn−Fe−Co−Ni high-entropy alloy in tension and compression from 10 K to 1273 K

Marino Kawamura, Makoto Asakura, Norihiko L. Okamoto, Kyosuke Kishida, Haruyuki Inui, Easo P. George

Acta Materialia· Volume 203

Abstract

Abstract The plastic deformation behavior of single crystals of the quinary, equiatomic Cr−Mn−Fe−Co−Ni high-entropy alloy (HEA) with the face-centered cubic structure has been investigated in tension and compression as a function of crystal orientation and temperature from 10 K to 1373 K. The critical resolved shear stress (CRSS) for {111} slip at room temperature is 42−45 MPa. It does not depend much on crystal orientation (i.e., the Schmid law holds true) and the sense (tension vs. compression) of the applied load. The CRSS for {111} slip increases with the decrease in temperature, without showing any significant inertia effects at cryogenic temperatures below 77 K. Extrapolation from the measured yield stresses down to 10 K yields a CRSS value at 0 K of 168 MPa. At cryogenic temperatures, the measured strain-rate sensitivity of flow stress is consistent with a very small activation volume. The concept of stress equivalence holds true both for the temperature dependence of CRSS and the stress dependence of activation volume, indicating that solid-solution hardening is the major strengthening mechanism. Deformation twinning occurs at 77 K but not at room temperature, resulting in higher tensile elongation to failure at 77 K than at room temperature. Deformation twinning at 77 K occurs at a shear stress of 378 MPa on conjugate ( 1 ¯ 1 ¯ 1) planes in the form of Luders deformation after large plastic strain (about 85%) achieved by the stage I (easy glide) and stage II (linear work-hardening) deformation.
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Research context

OpenAlex topics: High Entropy Alloys Studies · High-Temperature Coating Behaviors · Advanced materials and composites

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References (54)

Show source-provided references
1. Nanostructured high-entropy alloys with multiple principal elements: novel alloy design concepts and outcomes10.1002/adem.200300567 ↗
2. High-entropy alloys; A critical review10.1080/21663831.2014.912690 ↗
3. A critical review of high entropy alloys and related concept10.1016/j.actamat.2016.08.081 ↗
4. A review on fundamental of high entropy alloys with promising high–temperature properties10.1016/j.jallcom.2018.05.067 ↗
5. High-entropy alloys10.1038/s41578-019-0121-4 ↗
6. High entropy alloys: a focused review of mechanical properties and deformation mechanisms10.1016/j.actamat.2019.12.015 ↗
7. Microstructural development in equiatomic multicomponent alloys10.1016/j.msea.2003.10.257 ↗
8. Tensile properties of high-and medium-entropy alloys10.1016/j.intermet.2013.03.018 ↗
9. The influences of temperature and microstructure on the tensile properties of a CoCrFeMnNi high-entropy alloy10.1016/j.actamat.2013.06.018 ↗
10. A fracture resistant high-entropy alloy for cryogenic applications10.1126/science.1254581 ↗
11. Modelling solid solution hardening in high entropy alloys10.1016/j.actamat.2014.11.014 ↗
12. A general formulation for solid solution hardening effect in multicomponent alloys10.1016/j.scriptamat.2016.09.009 ↗
13. Theory of strengthening in fcc high entropy alloys10.1016/j.actamat.2016.07.040 ↗
14. Solute strengthening in random alloys10.1016/j.actamat.2016.09.046 ↗
15. Atomic displacement in the CrMnFeCoNi high-entropy alloy –A scaling factor to predict solid solution hardening10.1063/1.4971371 ↗
16. Microstructure evolution and critical stress for twinning in the CrMnFeCoNi high-entropy alloy10.1016/j.actamat.2016.07.038 ↗
17. The onset of twinning in metals: a constitutive description10.1016/S1359-6454(01)00300-7 ↗
18. Predicting twinning stress in fcc metals: linking twin-energy pathways to twin nucleation10.1016/j.actamat.2007.08.042 ↗
19. Slip nucleation in single crystal CoCrFeMnNi high-entropy alloy10.1016/j.scriptamat.2015.09.009 ↗
20. Critical resolved shear stress for slip and twin nucleation in single crystalline FeNiCoCrMn high entropy alloy10.1016/j.matchar.2017.05.014 ↗
21. Orientation dependence of twinning in single crystalline CoCrFeMnNi high-entropy alloy10.1016/j.msea.2017.08.065 ↗
22. Experimental determination of latent hardening coefficients in FeMnNiCoCr10.1016/j.ijplas.2018.02.016 ↗
23. Twinning in [001]-oriented single crystals of CoCrFeMnNi high-entropy alloy at tensile deformation10.1016/j.msea.2017.12.059 ↗
24. Hardening by slip-twin and twin-slip interactions in FeMnNiCoCr10.1016/j.actamat.2018.04.054 ↗
25. Temperature dependence of the mechanical properties of equiatomic solid solution alloys with face-centered cubic crystal structures10.1016/j.actamat.2014.08.026 ↗
26. Size effect, critical resolved shear stress, stacking fault energy, and solid solution strengthening in the CrMnFeCoNi high-entropy alloy10.1038/srep35863 ↗
27. Entropy determination of single-phase high entropy alloys with different crystal structures over a wide temperature range10.3390/e20090654 ↗
28. Effects of ordering on the properties of Ni-Cr alloys10.1007/BF01115776 ↗
29. Hydrogen enhanced localization of plasticity in an austenitic stainless steel10.1007/BF02669644 ↗
30. Effect of short-range ordering in stress corrosion cracking susceptibility of alloy 600 studied by electron and neutron diffraction10.1016/j.actamat.2014.10.009 ↗
31. Monocrystalline elastic constants of fcc-CrMnFeCoNi high entropy alloy10.1557/adv.2017.76 ↗
32. Mechanical properties and stacking fault energies of NiFeCrCoMn high-entropy alloy10.1007/s11837-013-0771-4 ↗
33. Calculating elastic constants in high-entropy alloys using the coherent potential approximation: current issues and errors10.1016/j.commatsci.2015.09.058 ↗
34. Effect of alloying on the thermal-elastic properties of 3d high entropy alloys10.1016/j.matchemphys.2017.10.046 ↗
35. Simmons · 1971
36. Temperature dependencies of the elastic moduli and thermal expansion coefficient of an equiatomic, single-phase CoCrFeMnNi high-entropy alloy10.1016/j.jallcom.2014.11.061 ↗
37. Polycrystalline elastic moduli of a high-entropy alloy at cryogenic temperatures10.1016/j.intermet.2014.11.005 ↗
38. Decomposition of the single-phase high-entropy alloy CrMnFeCoNi after prolonged anneals at intermediate temperatures10.1016/j.actamat.2016.04.005 ↗
39. Thermally activated glide in face-centered cubic alloys
40. Investigations of the yield region of concentrated Cu−Ge and Cu−Zn single crystals-I. Critical resolved shear stress, slip line formation and the true strain rate10.1016/0001-6160(77)90234-6 ↗
41. Thermally activated deformation and the rate controlling mechanism in CoCrFeMnNi high-entropy alloy10.1016/j.msea.2016.11.078 ↗
42. Thermal activation parameters of plastic flow reveal deformation mechanisms in the CrMnFeCoNi high entropy alloy10.1016/j.actamat.2017.10.014 ↗
43. On the strain rate-dependent deformation mechanism of CoCrFeMnNi high-entropy alloy at liquid nitrogen temperature10.1080/21663831.2017.1323807 ↗
44. The evolution of the deformation substructure in a Ni-Co-Cr equiatomic solid solution alloy10.1016/j.actamat.2017.04.033 ↗
45. Magnetically-driven phase transformation strengthening in high entropy alloys10.1038/s41467-018-03846-0 ↗
46. Stress equivalence of solution hardening10.1016/0036-9748(72)90052-X ↗
47. Atomic-scale characterization and modeling of 60° dislocations in a high-entropy alloy10.1016/j.actamat.2016.03.045 ↗
48. The weak beam technique as applied to the determination of the stacking-fault energy of copper10.1080/14786437108217418 ↗
49. The measurement of stacking-fault energies of pure face-centered cubic metals10.1080/14786437108217419 ↗
50. Observations of constrictions on dissociated dislocation lines in copper alloys10.1080/14786437408226609 ↗
51. the formation and glide of jogs in low stacking-fault energy face-centered cubic materials10.1080/14786437708232974 ↗
52. The extension of jogs on dissociated dislocations in F.C.C. metals10.1002/pssa.2210540150 ↗
53. Anderson · 2017 · 455
54. Sluggish diffusion in Co–Cr–Fe–Mn–Ni high-entropy alloys10.1016/j.actamat.2013.04.058 ↗