journal article·2023-10Open access

On the strength and fracture toughness of an additive manufactured CrCoNi medium-entropy alloy

Punit Kumar, Matthew Michalek, David H. Cook, Huang Sheng, Kwang B. Lau, Pei Wang, Mingwei Zhang, Andrew M. Minor, Upadrasta Ramamurty, Robert O. Ritchie

Acta Materialia· Volume 258

Abstract

An additively manufactured (nominally equiatomic) CrCoNi alloy was processed by laser powder bed fusion (LPBF). At ambient temperatures (298 K), this medium-entropy alloy displayed a yield strength, σ y of ∼691 ± 9 MPa, and an ultimate tensile strength, σ u of ∼926 ± 15.2 MPa; at cryogenic temperatures (77 K), yield and tensile strengths increased respectively to σ y ∼ 944 ± 6 MPa and σ u ∼ 1382 ± 11 MPa. These strength levels are 57 and 44% higher than that of the wrought alloy, due to strengthening from the solidification cellular structures intertwined with dislocations in the LPBF CrCoNi. The crack-initiation fracture toughness, K JIc was measured to be ∼183.7 ± 28 MPa√m at 298 K; this value marginally decreased by ∼4% to ∼176 ± 11 MPa√m at 77 K. These K JIc values of the LPBF CrCoNi were 11% and 35% lower than the wrought CrCoNi alloy at 298 K and 77 K, respectively. The resistance to crack growth of the LPBF CrCoNi from its hierarchical micro- and meso‑structures was evaluated using nonlinear-elastic fracture mechanics by measuring R-curve behavior in the form of the J-integral as a function of crack extension. The specific features of the hierarchical microstructures at different length-scales provide a basis for the strengthening and toughening properties of this additively manufactured medium-entropy alloy. This correlation between the deformation and the hierarchical microstructures at different length-scales may provide future guidance for improving the fracture toughness properties of medium-entropy alloys.
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Research context

OpenAlex topics: High Entropy Alloys Studies · Additive Manufacturing Materials and Processes · High-Temperature Coating Behaviors

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References (59)

Show source-provided references
1. Effect of cryo-deformation on structure and properties of CoCrFeNiMn high-entropy alloy10.1016/j.intermet.2014.12.004 ↗
2. Effect of temperature on the fatigue-crack growth behavior of the high-entropy alloy CrMnFeCoNi10.1016/j.intermet.2017.05.009 ↗
3. Exceptional damage-tolerance of a medium-entropy alloy CrCoNi at cryogenic temperatures10.1038/ncomms10602 ↗
4. Exceptional fracture toughness of CrCoNi-based medium- and high-entropy alloys at 20 kelvin10.1126/science.abp8070 ↗
5. A fracture-resistant high-entropy alloy for cryogenic applications10.1126/science.1254581 ↗
6. Exceptional fracture toughness of CrCoNi-based medium- and high-entropy alloys at 20 kelvin10.1126/science.abp8070 ↗
7. Fracture properties of high-entropy alloys10.1557/s43577-022-00267-9 ↗
8. Fracture toughness of type 304 and 316 stainless steels and their welds10.1179/imr.1997.42.2.45 ↗
9. The conflicts between strength and toughness10.1038/nmat3115 ↗
10. The effect of grain size on fracture toughness10.1080/01418618908221173 ↗
11. Additively manufactured high strength and ductility CrCoNi medium entropy alloy with hierarchical microstructure10.1016/j.msea.2021.141545 ↗
12. Mesostructure engineering in additive manufacturing of alloys10.1016/j.scriptamat.2023.115429 ↗
13. Fracture and fatigue in additively manufactured metals10.1016/j.actamat.2021.117240 ↗
14. Cascading of the as-built microstructure through heat treatment and its role on the tensile properties of laser powder bed fused Inconel 71810.1016/j.mtla.2021.101272 ↗
15. Additive manufacturing of metal cellular structures: design and fabrication10.1007/s11837-015-1322-y ↗
16. New insights on cellular structures strengthening mechanisms and thermal stability of an austenitic stainless steel fabricated by laser powder-bed-fusion10.1016/j.actamat.2020.11.018 ↗
17. About metastable cellular structure in additively manufactured austenitic stainless steels
18. Directed energy deposition of metals: processing, microstructures, and mechanical properties10.1080/09506608.2022.2097411 ↗
19. Hierarchical microstructure and strengthening mechanisms of a CoCrFeNiMn high entropy alloy additively manufactured by selective laser melting10.1016/j.scriptamat.2018.05.015 ↗
20. A comparative study of additive manufactured and wrought SS316L: pre-existing dislocations and grain boundary characteristics10.1016/j.msea.2021.142546 ↗
21. Effect of initial dislocation density on the plastic deformation response of 316L stainless steel manufactured by directed energy deposition10.1016/j.msea.2022.143591 ↗
22. Fracture toughness of 304L austenitic stainless steel produced by laser powder bed fusion10.1016/j.scriptamat.2021.114002 ↗
23. Dislocation network in additive manufactured steel breaks strength–ductility trade-off10.1016/j.mattod.2017.11.004 ↗
24. Excellent strength-ductility synergy in metastable high entropy alloy by laser powder bed additive manufacturing
25. Simultaneously enhanced strength and ductility for 3D-printed stainless steel 316L by selective laser melting10.1038/s41427-018-0018-5 ↗
26. Simultaneous enhancements of strength and toughness in an Al-12Si alloy synthesized using selective laser melting10.1016/j.actamat.2016.06.009 ↗
27. Fracture resistance of AlSi10Mg fabricate d by laser powder b e d fusion10.1016/j.actamat.2021.116869 ↗
28. Micro-and meso-structures and their influence on mechanical properties of selectively laser melted Ti-6Al-4V10.1016/j.actamat.2018.05.044 ↗
29. J.Y. Xu, P.C. Zhang, R. Guo, L.X. Liu, Y.P. Kang, Z. Liu, C. Zhang, L. Liu, Toughening the additively manufactured Al alloys via manipulating microstructural heterogeneity, (2023). 10.1016/j.jallcom.2023.169322.
30. ASTM E8, ASTM E8/E8M standard test methods for tension testing of metallic materials 1, Ann. Book ASTM Stand. 4. (2010) 1–27. 10.1520/E0008.
31. 2013 · 1
32. Grain refinement and crack inhibition of hard-to-weld Inconel 738 alloy by altering the scanning strategy during selective laser melting10.1016/j.matdes.2021.109940 ↗
33. Layer-wise engineering of grain orientation (LEGO) in laser powder bed fusion of stainless steel 316L
34. Laser 3D printing of CoCrFeMnNi high-entropy alloy10.1016/j.matlet.2018.10.084 ↗
35. Grain structure control of additively manufactured metallic materials10.3390/ma10111260 ↗
36. Prediction of dendrite arm spacing for low alloy steel casting processes
37. Additive manufacturing of a metastable high entropy alloy: metastability engineered microstructural control via process variable driven elemental segregation10.1016/j.msea.2023.144938 ↗
38. Strengthening and hardening mechanisms of additively manufactured stainless steels: the role of cell sizes10.1016/j.scriptamat.2019.10.005 ↗
39. The mechanism of plastic deformation of crystals. Part I.—Theoretical
40. The type of dislocation interaction as the factor determining work hardening10.1016/0025-5416(80)90175-5 ↗
41. Friction stress and Hall-Petch relationship in CoCrNi equi-atomic medium entropy alloy processed by severe plastic deformation and subsequent annealing10.1016/j.scriptamat.2017.02.042 ↗
42. Yield strength and misfit volumes of NiCoCr and implications for short-range-order10.1038/s41467-020-16083-1 ↗
43. Theory of work hardening 1934-198410.1007/BF02670414 ↗
44. Role of the solidification cells on the yield strength of the Al-Si-Mg alloy manufactured using laser powder bed fusion: a micropillar compression study10.1016/j.scriptamat.2023.115566 ↗
45. A micropillar compression investigation into the plastic flow properties of additively manufactured alloys10.1016/j.actamat.2022.118290 ↗
46. Strain hardening by dynamic slip band refinement in a high-Mn lightweight steel10.1016/j.actamat.2016.06.037 ↗
47. Stacking fault energy analyses of additively manufactured stainless steel 316L and CrCoNi medium entropy alloy using in situ neutron diffraction10.1038/s41598-020-58273-3 ↗
48. Impact of chemical fluctuations on stacking fault energies of CrCoNi and CrMnFeCoNi high entropy alloys from first principles10.3390/e20090655 ↗
49. A Hall–Petch study of the high toughness Cr40Co30Ni30 multi-principal element alloy10.1557/s43578-022-00729-5 ↗
50. Dislocation-twin interaction in medium entropy alloy containing a high density of oxygen interstitials10.1016/j.jallcom.2023.169522 ↗
51. The behaviour of stacking fault energy upon interstitial alloying10.1038/s41598-017-11328-4 ↗
52. Interstitial doping enhances the strength-ductility synergy in a CoCrNi medium entropy alloy10.1016/j.msea.2020.139242 ↗
53. M. Klimova, D. Shaysultanov, A. Semenyuk, S. Zherebtsov, G. Salishchev, N. Stepanov, Effect of nitrogen on mechanical properties of CoCrFeMnNi high entropy alloy at room and cryogenic temperatures, (2020). 10.1016/j.jallcom.2020.156633.10.1016/j.jallcom.2020.156633 ↗
54. Yield strength increase of a CoCrNi medium entropy alloy by interstitial nitrogen doping at maintained ductility10.1016/j.scriptamat.2019.12.007 ↗
55. Outstanding fracture toughness combines gigapascal yield strength in an N-doped heterostructured medium-entropy alloy10.1016/j.actamat.2023.119079 ↗
56. Additively manufactured high strength and ductility CrCoNi medium entropy alloy with hierarchical microstructure10.1016/j.msea.2021.141545 ↗
57. On macroscopic and microscopic analyses for crack initiation and crack growth toughness in ductile alloys10.1007/BF02815305 ↗
58. Singular behaviour at the end of a tensile crack in a hardening material10.1016/0022-5096(68)90014-8 ↗
59. Plane strain deformation near a crack tip in a power-law hardening material10.1016/0022-5096(68)90013-6 ↗