journal article·2025-12

Preparation and Thermal Effect Study of Fluorographene/Boron Powder Composite Materials

Xu Wen, Jianhua Wang, Fawei Wang, Yucun Liu, Jiapeng Wang, Nan Zhang, Yanwu Yu

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Abstract

To overcome the problem of sticky oxide films hindering the complete energy release of boron powder during ignition, graphene fluoride (FG) was used. FG, selected for its high fluorine content, low hydrogen content, low surface free energy, and high thermal conductivity, reacts with boron to produce high combustion heat and large amounts of gaseous products, effectively removing the viscous oxide film and preventing boron agglomeration. FG was synthesized via shear emulsification cutting, and FG/B composites were fabricated via solvent evaporation. Thermal analysis and combustion heat testing revealed that the prepared FG flake had an average thickness of 1.56 nm. For 20% FG addition, the FG/B composite exhibited a 1.86-fold increase in combustion heat. Moreover, 20% FG addition effectively improved the combustion heat release of boron powder, making it comparable with the combustion heat release of high-energy metal powder/boron powder composites.
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OpenAlex topics: Energetic Materials and Combustion · Flame retardant materials and properties · Boron and Carbon Nanomaterials Research

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (33)

Show source-provided references
1. Yang, H., Huang, Ch., and Chen, H., Tuning reactivity of nanoaluminum with fluoropolymer via electrospray deposition, J. Therm. Anal. Calorim., 2017, vol. 127, no. 3, pp. 2293–2299. https://doi.org/10.1007/s10973-016-5801-310.1007/s10973-016-5801-3 ↗
2. Wang, J., Wang, J., Mao, Ya., Peng, R., and Nie, F., The surface activation of boron to improve ignition and combustion characteristic, Def. Technol., 2022, vol. 18, no. 9, pp. 1679–1687. https://doi.org/10.1016/j.dt.2021.09.01210.1016/j.dt.2021.09.012 ↗
3. Duan, L., Xia, Zh., Chen, B., Feng, Yu., and Ma, L., Ignition and combustion characteristics of boron agglomerates under different oxygen concentrations, Acta Astronaut., 2022, vol. 197, pp. 81–90. https://doi.org/10.1016/j.actaastro.2022.05.02010.1016/j.actaastro.2022.05.020 ↗
4. Yu, D., Zhuo, J.K., and Yao, Q., Review on ignition and combustion characteristics of boron particles, J. Combust. Sci. Technol., 2014, vol. 20, no. 1, pp. 44–50.
5. Korotkikh, A.G., Sorokin, I.V., Teplov, D.V., and Arkhipov, V.A., Combustion characteristics of high-energy material containing dispersed aluminum, boron, and aluminum borides, Combust., Explos., Shock Waves, 2023, vol. 59, no. 4, pp. 440–446. https://doi.org/10.1134/s001050822304006810.1134/s0010508223040068 ↗
6. Shin, W.G., Han, D., Park, Yo., Hyun, H.S., Sung, H.-G., and Sohn, Yo., Combustion of boron particles coated with an energetic polymer material, Korean J. Chem. Eng., 2016, vol. 33, no. 10, pp. 3016–3020. https://doi.org/10.1007/s11814-016-0173-810.1007/s11814-016-0173-8 ↗
7. Song, Q.G., Cao, W., Gao, D.Y., et al., Research on energetic characteristics of explosive containing B/AI, Science and Technology of Energetic Materials, 2019, vol. 80, no. 5/6, pp. 199–206.
8. Li, Ya., Cheng, Yi., Hui, Y.-L., and Yan, Sh., The effect of ambient temperature and boron content on the burning rate of the B/Pb3O4 delay compositions, J. Energ. Mater., 2010, vol. 28, no. 2, pp. 77–84. https://doi.org/10.1080/0737065090319329910.1080/07370650903193299 ↗
9. Xu, S., Chen, Y.U., Chen, X., Wu, D., and Liu, D., Combustion heat of the Al/B powder and its application in metallized explosives in underwater explosions, Combust., Explos., Shock Waves, 2016, vol. 52, no. 3, pp. 342–349. https://doi.org/10.1134/s001050821603014x10.1134/s001050821603014x ↗
10. Huang, S., Deng, S., Jiang, Yu., and Zheng, X., Experimental effective metal oxides to enhance boron combustion, Combust. Flame, 2019, vol. 205, pp. 278–285. https://doi.org/10.1016/j.combustflame.2019.04.01810.1016/j.combustflame.2019.04.018 ↗
11. Liu, T., Luh, S., and Perng, H., Effect of boron particle surface coating on combustion of solid propellants for ducted rockets, Propellants, Explos., Pyrotech., 2010, vol. 16, no. 4, pp. 156–166. https://doi.org/10.1002/prep.1991016040310.1002/prep.19910160403 ↗
12. Keerthi, V., Nie, H., Pisharath, S., and Hng, H.H., Combustion characteristics of fluoropolymer coated boron powders, Combust. Sci. Technol., 2022, vol. 194, no. 6, pp. 1183–1198. https://doi.org/10.1080/00102202.2020.180488510.1080/00102202.2020.1804885 ↗
13. Zhu, Ch., Qin, Ya., Liu, K., Liu, Q., Gao, X., and Liu, J., Ignition and combustion performance of B@HMX composite microunit prepared by recrystallization of solvent evaporation, ACS Omega, 2024, vol. 9, no. 48, pp. 47719–47728. https://doi.org/10.1021/acsomega.4c0782410.1021/acsomega.4c07824 ↗
14. Yang, D., Liu, R., Li, W., and Yan, Q.-L., Recent advances on the preparation and combustion performances of boron-based alloy fuels, Fuel, 2023, vol. 342, no. 15, p. 127855. https://doi.org/10.1016/j.fuel.2023.12785510.1016/j.fuel.2023.127855 ↗
15. Young, G., Stoltz, Ch.A., Mayo, D.H., Roberts, C.W., and Milby, Ch.L., Combustion behavior of solid fuels based on PTFE/boron mixtures, Combust. Sci. Technol., 2013, vol. 185, no. 8, pp. 1261–1280. https://doi.org/10.1080/00102202.2013.78741710.1080/00102202.2013.787417 ↗
16. Chen, B., Xia, Zh., Huang, L., and Hu, J., Ignition and combustion model of a single boron particle, Fuel Process. Technol., 2017, vol. 165, pp. 34–43. https://doi.org/10.1016/j.fuproc.2017.05.00810.1016/j.fuproc.2017.05.008 ↗
17. Ulas, A., Kuo, K.K., and Gotzmer, C., Ignition and combustion of boron particles in fluorine-containing environments, Combust. Flame, 2001, vol. 127, nos. 1–2, pp. 1935–1957. https://doi.org/10.1016/s0010-2180(01)00299-110.1016/s0010-2180(01)00299-1 ↗
18. Yao, J., Huang, Ya., Chang, K., Nie, J., Guo, X., Shen, Ch., and Yan, Sh., Preparation and energy release properties of nB@F2603@CL-20 microspheres by electrospray, Metals, 2022, vol. 12, no. 10, p. 1727. https://doi.org/10.3390/met1210172710.3390/met12101727 ↗
19. Wang, J., Mao, Ya., Chen, J., Li, Z., Wang, J., and Nie, F., Surface engineering boron/graphite fluoride composite with enhanced ignition and combustion performances, Fuel, 2022, vol. 323, p. 124374. https://doi.org/10.1016/j.fuel.2022.12437410.1016/j.fuel.2022.124374 ↗
20. Yan, T., Liu, P., Song, N., and Ou, Ya., Insight into combustion characteristics of micro- and nano-sized boron carbide, Combust. Flame, 2023, vol. 251, p. 112721. https://doi.org/10.1016/j.combustflame.2023.11272110.1016/j.combustflame.2023.112721 ↗
21. Yetter, R.A., Dryer, F.L., Rabitz, H., Brown, R.C., and Kolb, C.E., Effect of fluorine on the gasification rate of liquid boron oxide droplets, Combust. Flame, 1998, vol. 112, no. 3, pp. 387–403. https://doi.org/10.1016/s0010-2180(97)00123-510.1016/s0010-2180(97)00123-5 ↗
22. Zhou, W., Yetter, R.A., Dryer, F.L., Rabitz, H., Brown, R.C., and Kolb, C.E., Effect of fluorine on the combustion of “clean” surface boron particles, Combust. Flame, 1998, vol. 112, no. 4, pp. 507–521. https://doi.org/10.1016/s0010-2180(97)00129-610.1016/s0010-2180(97)00129-6 ↗
23. Zhang, W.P., Guo, Y.L., Zhao, Y., and Pang, W.Q., Research progress of fluor-ine-containing materials combustion supporting boron powder, Ordnance Equip. Eng., 2024, vol. 45, no. 5, pp. 1–7.
24. Hedman, T.D., Demko, A.R., and Kalman, J., Enhanced ignition of milled boron-polytetrafluoroethylene mixtures, Combust. Flame, 2018, vol. 198, pp. 112–119. https://doi.org/10.1016/j.combustflame.2018.08.02010.1016/j.combustflame.2018.08.020 ↗
25. Yan, L., Zhu, B., Chen, J., and Sun, Yu., Study on nano-boron particles modified by PVDF to enhance the combustion characteristics, Combust. Flame, 2023, vol. 248, p. 112556. https://doi.org/10.1016/j.combustflame.2022.11255610.1016/j.combustflame.2022.112556 ↗
26. Zhu, L., Zhu, B., Zhao, X., Wang, Ya., Li, M., Chen, J., and Sun, Yu., Using polyvinylidene fluoride to improve ignition and combustion of micron-sized boron powder by fluorination reaction, Chin. J. Aeronaut., 2023, vol. 36, no. 10, pp. 64–76. https://doi.org/10.1016/j.cja.2023.05.00110.1016/j.cja.2023.05.001 ↗
27. Ma, Sh., Shu, Q., Zhang, M., Huang, H., Shi, Ya., Lv, X., and Zhao, Sh., Anti-aging performance improvement and enhanced combustion efficiency of boron via the coating of PDA, Def. Technol., 2024, vol. 33, pp. 399–410. https://doi.org/10.1016/j.dt.2023.10.00710.1016/j.dt.2023.10.007 ↗
28. Zhu, B., Zhang, S., Sun, Yu., Ji, Ya., and Wang, J., Fluorinated graphene improving thermal reaction and combustion characteristics of nano-aluminum powder, Thermochim. Acta, 2021, vol. 705, p. 179038. https://doi.org/10.1016/j.tca.2021.17903810.1016/j.tca.2021.179038 ↗
29. Wang, Zh., Wang, J., Li, Zh., Gong, P., Ren, J., Wang, H., Han, X., and Yang, Sh., Cooperatively exfoliated fluorinated graphene with full-color emission, RSC Adv., 2012, vol. 2, no. 31, p. 11681. https://doi.org/10.1039/c2ra21871b10.1039/c2ra21871b ↗
30. Singh, S.K., Srinivasan, S.G., Neek-Amal, M., Costamagna, S., Van Duin, A.C.T., and Peeters, F.M., Thermal properties of fluorinated graphene, Phys. Rev. B, 2013, vol. 87, no. 10, p. 104114. https://doi.org/10.1103/physrevb.87.10411410.1103/physrevb.87.104114 ↗
31. Tao, Ch., Xianrui, Zh., Yuanyuan, W., Ling, H., and Jinwu, X., Effect of LiF coating on thermal oxidation characteristics of boron powder, Chin. J. Energ. Mater., 2013, vol. 21, no. 1, pp. 57–60. https://CNKI:SUN:HNCL.0.2013-01-013.
32. Wang, D., Liu, J., Tan, T., Liu, Sh., Xu, G., Zhang, Zh., Qin, Ya., and Li, F., Dual-core–shell structure B@LiF@AP with multi-effect synergies to improve processibility and energy release characteristics of B, J. Mater. Chem. A, 2013, vol. 11, no. 3, pp. 1351–1360. https://doi.org/10.1039/d2ta08298e10.1039/d2ta08298e ↗
33. Liu, J.-Z., Xi, J.-F., Yang, W.-J., Hu, Y.-R., Zhang, Y.-W., Wang, Ya., and Zhou, J.-H., Effect of magnesium on the burning characteristics of boron particles, Acta Astronaut., 2014, vol. 96, pp. 89–96. https://doi.org/10.1016/j.actaastro.2013.11.03910.1016/j.actaastro.2013.11.039 ↗