journal article·2017-05

Strong and ductile age-hardening Mg-Al-Ca-Mn alloy that can be extruded as fast as aluminum alloys

T. Nakata, C. Xu, R. Ajima, K. Shimizu, S. Hanaki, T.T. Sasaki, L. Ma, K. Hono, S. Kamado

Acta Materialia· Volume 130
Publisher page

Abstract

Abstract We have developed a wrought magnesium alloy, Mg-1.3Al-0.3Ca-0.4Mn (wt.%) or AXM10304, that can be extruded at a very high die-exist speed of 24 m/min, comparable to the extrusion speed for aluminum alloys, and that exhibits an excellent combination of strength and elongation after an age-hardening, i.e., a tensile 0.2% proof stress of 287 MPa and an elongation of 20%. The high tensile proof stress is attributed to the dispersion of a high number density of monolayer Guinier Preston (G.P.) zones dispersed in grains with an average grain size of 17 μm and 1 ¯ 0> fiber texture typical of Mg alloy extrusions. The uniform dispersion of the G.P. zones facilitates cross-slip, and the G.P. zones do not work as crack initiation and propagation site, so the degradation of the elongation after the age-hardening is prevented. The combination of strength and elongation of the extruded and age-hardened AXM10304 is superior to those of Mg-6Al-1Zn (AZ61) and Mg-6.0Zn-0.5Zr (ZK60) commercial alloys and comparable to those of 6000 series of aluminum alloys without any expensive ingredients. Therefore, this alloy may open up a new application areas where weight reduction is of a priority issue.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Magnesium Alloys: Properties and Applications · Aluminum Alloys Composites Properties · Metal and Thin Film Mechanics

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (64)

Show source-provided references
1. Effect of Zr addition on the mechanical properties of as-extruded Mg–Zn–Ca–Zr alloys10.1016/j.msea.2009.12.024 ↗
2. Bimodally grained microstructure development during hot extrusion of Mg–2.4 Zn–0.1 Ag–0.1 Ca–0.16 Zr (at.%) alloys10.1016/j.actamat.2009.07.057 ↗
3. High-strength extruded Mg–Al–Ca–Mn alloy10.1016/j.scriptamat.2011.04.026 ↗
4. A high-strength Mg-Sn-Zn-Al alloy extruded at low temperature10.1016/j.scriptamat.2008.07.042 ↗
5. Effect of extrusion conditions on microstructure and mechanical properties of microalloyed Mg-Sn-Al-Zn alloys10.1016/j.msea.2013.09.050 ↗
6. Prediction of grain size and yield strength of Mg-7Sn-1Al-1Zn alloys extruded at various temperatures and speeds10.1007/s12540-014-2011-z ↗
7. Strong and ductile heat-treatable Mg-Sn-Zn-Al wrought alloys10.1016/j.actamat.2015.06.060 ↗
8. Achieving high strength and high ductility in magnesium alloys using severe plastic deformation combined with low temperature aging10.1016/j.scriptamat.2009.08.020 ↗
9. Texture and mechanical properties of ultrafine-grained Mg-3Al-1Zn alloy sheets prepared by high-ratio differential speed rolling10.1016/j.msea.2010.09.007 ↗
10. Strengthening Mg-Al-Zn alloy by repetitive oblique shear strain with caliber roll10.1016/j.scriptamat.2009.09.005 ↗
11. Improvement of mechanical properties of magnesium alloy ZK60 by integrated extrusion and equal channel angular pressing10.1016/j.actamat.2010.09.043 ↗
12. Extrusion limits of magnesium alloys10.1007/s11661-007-9323-2 ↗
13. Expanding the extrusion limits of wrought magnesium alloys10.1007/s11837-004-0121-7 ↗
14. Extrusion of magnesium alloy10.2464/jilm.54.472 ↗
15. Murai · J. Jpn. Inst. Light Met. · 2003 · 53 · 2710.2464/jilm.53.27 ↗
16. High-speed extrusion of heat-treatable Mg–Al–Ca–Mn dilute alloy10.1016/j.scriptamat.2015.01.010 ↗
17. Improving tensile properties of dilute Mg-0.27Al-0.13Ca-0.21Mn (at.%) alloy by low temperature high speed extrusion10.1016/j.jallcom.2015.07.051 ↗
18. Wrought alloys: 6xxx Al-Mg-Si alloys
19. The determination of foil thickness by scanning transmission electron microscopy10.1002/pssa.2210310251 ↗
20. The influence of calcium and cerium mischmetal on the microstructural evolution of Mg–3Al–1Zn during extrusion and resulting mechanical properties10.1016/j.actamat.2008.02.010 ↗
21. Effect of Sr addition on texture evolution of Mg–3Al–1Zn (AZ31) alloy during extrusion10.1016/j.msea.2010.12.091 ↗
22. Enhanced precipitation hardening of Mg–Ca alloy by Al addition10.1016/j.scriptamat.2010.06.028 ↗
23. Age-hardening response of Mg-0.3 at.% Ca alloys with different Zn contents10.1016/j.msea.2009.07.027 ↗
24. Effect of stress triaxiality on the flow and fracture of Mg alloy AZ3110.1007/s11661-014-2211-7 ↗
25. Effect of twinnig, slip, and inclusions on the fatigue anisotropy of extrusion textured AZ61 magnesium alloy10.1016/j.msea.2011.05.047 ↗
26. Improved mechanical properties of Mg–7.6Al–0.4Zn alloy through aging prior to extrusion10.1016/j.scriptamat.2014.08.017 ↗
27. The effect of Sn addition on aging behavior and mechanical properties of wrought AZ80 magnesium alloy10.1016/j.jallcom.2014.09.165 ↗
28. Effect of aging treatment on fatigue behaviour in extruded AZ61 and AZ80 magnesium alloys10.1016/j.msea.2009.03.066 ↗
29. Comparison of the microstructure and mechanical properties of a ZK60 alloy with and without 1.3wt.% gadolinium addition10.1016/j.msea.2006.06.063 ↗
30. Effect of microalloyed Zr on the extruded microstructure of Mg–6.2Zn-based alloys10.1016/j.scriptamat.2014.07.011 ↗
31. Effect of Y and Ce additions on microstructure and mechanical properties of Mg–Zn–Zr alloys10.1016/j.msea.2015.07.065 ↗
32. Effect of Ce addition on the microstructure and tensile properties of extruded Mg–Zn–Zr alloys10.1016/j.msea.2014.06.054 ↗
33. Microstructure and mechanical properties of Mg–Al–Sn extruded alloys10.1016/j.jallcom.2015.10.146 ↗
34. Improving the tensile strength of Mg–7Sn–1Al–1Zn alloy through artificial cooling during extrusion10.1016/j.msea.2014.12.011 ↗
35. Effect of aging prior to extrusion on the microstructure and mechanical properties of Mg–7Sn–1Al–1Zn alloy10.1016/j.jallcom.2014.11.213 ↗
36. Microstructure and mechanical properties of binary Mg–Sn alloys subjected to indirect extrusion10.1016/j.msea.2010.03.031 ↗
37. Strength and ductility of novel Mg–8Sn–1Al–1Zn alloys extruded at different speeds10.1016/j.matlet.2011.03.010 ↗
38. Effect of rare earth elements on the microstructure and texture development in magnesium–manganese alloys during extrusion10.1016/j.msea.2010.07.081 ↗
39. Mechanical properties and microstructures of extruded rods of Al-Mg-Si base alloys10.2464/jilm.33.718 ↗
40. Effect of extrusion conditions and cooling rate for quench on mechanical properties of 6061 aluminum alloy extrusions10.2464/jilm.50.222 ↗
41. Microstructural evolution and mechanical properties of Mg-11Gd-4.5Y-1Nd-1.5Zn-0.5Zr alloy prepared via pre-ageing and hot extrusion10.1016/j.msea.2014.11.061 ↗
42. Liu · J. Mater. Sci. Technol. · 2016 · 32 · 31310.1016/j.jmst.2015.12.004 ↗
43. Fabrication of extraordinary high-strength magnesium alloy by hot extrusion10.1016/j.scriptamat.2009.06.003 ↗
44. Microstructure and mechanical properties of extruded Mg-Zn-Y alloys with 14H long period ordered structure10.2320/matertrans.47.959 ↗
45. Development of very high strength and ductile dilute magnesium alloys by dispersion of quasicrystal phase10.1007/s11661-013-2056-5 ↗
46. Kamado · 2005
47. High-speed indirect extrusion of Mg–Sn–Al–Zn alloy and its influence on microstructure and mechanical properties10.1016/j.jallcom.2016.01.163 ↗
48. Rare earth texture and improved ductility in a Mg-Zn-Gd alloy after high-speed extrusion10.1016/j.msea.2016.04.093 ↗
49. Effect of aluminum content on the texture and mechanical behavior of Mg-1 wt.% Mn wrought magnesium alloys10.1016/j.msea.2015.05.022 ↗
50. Influence of aluminum content on the texture and sheet formability of AM series magnesium alloys10.1016/j.msea.2015.03.018 ↗
51. The effect of Sn addition on aging behavior and mechanical properties of wrought AZ80 magnesium alloy10.1016/j.jallcom.2014.09.165 ↗
52. Effects of artificial aging on microstructure and mechanical properties of the Mg–4.5Zn–4.5Sn–2Al alloy10.1016/j.jallcom.2013.12.250 ↗
53. A HREM and analytical STEM study of precipitates in an AZ91 magnesium alloy10.1007/s006040200036 ↗
54. Structural characteristics of β1’ precipitates in Mg–Zn-based alloys10.1016/j.scriptamat.2007.07.028 ↗
55. High pressure aging synthesis of a hexagonal Mg2Sn strengthening precipitate in Mg–Sn alloys10.1016/j.matlet.2015.05.087 ↗
56. Fracture behavior of super alloy IN738LC with various precipitate microstructures10.1016/S0921-5093(99)00012-X ↗
57. Effect of particles distributions on the deformation behavior of magnesium alloy AZ91 in tension and compression10.1016/j.actamat.2011.10.001 ↗
58. Effect of particles in promoting twin nucleation in a Mg–5wt.% Zn alloy10.1016/j.scriptamat.2010.06.026 ↗
59. Geometrical criterion for the activation of prismatic slip in AZ61 Mg alloy sheets deformed at room temperature10.1016/j.actamat.2005.01.008 ↗
60. Microscopic mechanisms of plastic deformation in polycrystalline magnesium alloys10.2464/jilm.54.460 ↗
61. Optimum designs of additional elements from first-principles simulations10.2464/jilm.54.82 ↗
62. Superplastic forging with dynamic recrystallization of Mg-Al-Zn alloys cast by thixo-molding10.1016/j.scriptamat.2006.09.037 ↗
63. Influence of aluminum content on the texture and sheet formability of AM series magnesium alloys10.1016/j.msea.2015.03.018 ↗
64. Mechanisms of Guinier-Preston zone hardening in the athermal limit10.1016/j.actamat.2010.06.055 ↗