The mechanism of coercivity enhancement by the grain boundary diffusion process of Nd–Fe–B sintered magnets

Abstract We discuss the mechanism of the coercivity enhancement by the grain boundary diffusion process (GBDP) using Dy vapor based on detailed microstructural characterizations. Scanning electron microscopy and electron probe microanalysis showed that a (Nd,Dy) 2 Fe 14 B shell formed in the outer region of Nd 2 Fe 14 B grains while its thickness decreased from the surface to the center of a cube-shaped sample. Atom probe tomography showed that the Dy content at grain boundaries (GBs) was close to that in the (Nd,Dy) 2 Fe 14 B shell. High-temperature annealing (at 900 °C) of a GB diffusion processed magnet led to the disappearance of the GB layers, which resulted in a substantial reduction in coercivity. This suggests that both the (Nd,Dy) 2 Fe 14 B shell and the Nd-rich GB phase layer are required microstructural features for the coercivity enhancement by the GBDP.