journal article·2024-06Open access

Preferential intergranular oxidation as a potential degradation mechanism for Alloy X-750 CANDU spacers

A.E. Yaedu, L. Volpe, J.D. Henderson, S. Ramamurthy, K. Daub, F. Scenini, S.Y. Persaud

Abstract

Oxidation experiments on Alloy X-750 were performed in reducing CO-CO2 mixtures to assess the possibility of preferential intergranular oxidation (PIO) in relation to CANDU garter-spring spacers. The testing environments simulate hypothetical off-chemistry scenarios, promoting the oxidation of the alloying elements, but not Ni. Surface and cross-section microscopy corroborated by Auger electron spectroscopy confirmed the occurrence of internal and intergranular oxidation in Alloy X-750, accompanied by Ni nodule expulsion to the surface. Results are qualitatively similar to observations in Alloy 600 exposed to 480°C hydrogenated steam, used as an accelerated environment for primary water stress corrosion cracking (PWSCC) testing.
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OpenAlex topics: High-Temperature Coating Behaviors · Nuclear Materials and Properties · Fusion materials and technologies

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