Dissolution of corrosion product oxides relevant to nuclear power plants in formulations containing chromous complexes
Source abstract
Abstract
Abstract Reductive dissolution of corrosion product oxides relevant to nuclear power plants such as haematite (Fe2O3), nickel ferrite (NiFe2O4), iron chromite (FeCr2O4) and mixed oxides (NiFe2-xCrxO4; x = 0.4, 0.8, 1.2 and 1.6) were carried out in ethylene diamine tetra acetic acid (EDTA) and nitrilo tri acetic acid (NTA) based chemical formulations. Of all the reducing agents investigated, Cr(II)-complexes were found to be effective in dissolving these oxides. The results showed no preferential dissolution of a metal ion from the oxide lattice and the rate of dissolution was influenced by the concentration of Cr(II)-complex in solution, chromium content in the oxide lattice and pH of the formulation.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Radioactive element chemistry and processing · Nuclear Materials and Properties · Hydrogen embrittlement and corrosion behaviors in metals
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
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