Comparison of XRD, XANES and TGA methods to assess the O/M ratio of Th0.60Am0.40O2−x
Source abstract
Abstract
The mixed oxide Th0.60Am0.40O2−x has been synthesized and characterized after reductive and oxidative thermal treatments. Both materials are monophasic solid solutions. The determination of O/M ratio was achieved combining XRD, XANES and TGA, showing the consistence between the three methods. This study represents a further step in our investigation of the Th–Am–O system and improves it comprehension.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Nuclear Materials and Properties · Nuclear materials and radiation effects · Radioactive element chemistry and processing
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (19)
Show source-provided references
1. Schmitz · J. Nucl. Mater. · 1971 · 40 · 32510.1016/0022-3115(71)90100-0 ↗
2. Guéneau · 2012 · 21
3. Prieur · Inorg. Chem. · 2011 · 50 · 1243710.1021/ic200910f ↗
4. Prieur · J. Nucl. Mater. · 2013 · 434 · 710.1016/j.jnucmat.2012.11.037 ↗
5. Prieur · Eur. J. Inorg. Chem. · 2013 · 2013 · 151810.1002/ejic.201201294 ↗
6. Carvajal-Nunez · Inorg. Chem. · 2012 · 51 · 1176210.1021/ic301709d ↗
7. Prieur · Powder Technol. · 2011 · 208 · 55310.1016/j.powtec.2010.08.058 ↗
8. Prieur · J. Nucl. Mater. · 2011 · 411 · 1510.1016/j.jnucmat.2010.12.314 ↗
9. Prieur · J. Solid State Chem. · 2013 · 199 · 33410.1016/j.jssc.2012.12.022 ↗
10. Petricek · Crystallogr. Comput. Syst. · 2006
11. Rothe · Rev. Sci. Instrum. · 2012 · 83 · 04310510.1063/1.3700813 ↗
12. Ravel · J. Synchrotron. Radiat. · 2005 · 12 · 53710.1107/S0909049505012719 ↗
13. Nishi · J. Nucl. Mater. · 2008 · 374 · 33910.1016/j.jnucmat.2007.09.001 ↗
14. Nishi · J. Nucl. Mater. · 2010 · 401 · 13810.1016/j.jnucmat.2010.04.011 ↗
15. Horlait · Inorg. Chem. · 2011 · 50 · 715010.1021/ic200751m ↗
16. Shannon · Acta Crystallogr. Sect. · 1969 · 25 · 92510.1107/S0567740869003220 ↗
17. Nakamura · Solid State Ionics · 2012 · 181 · 154310.1016/j.ssi.2010.09.019 ↗
18. Templeton · J. Am. Chem. Soc. · 1953 · 75 · 456010.1021/ja01114a051 ↗
19. Kato · J. Nucl. Mater. · 2005 · 344 · 23510.1016/j.jnucmat.2005.04.048 ↗