Performance of Sc-Y-ODS variant of Eurofer steel in stagnant PbLi at 600°C
Source abstract
Abstract
This paper represents a part of the research of structural materials for fusion systems. The performance of a conventionally formed Eurofer-97 steel and its Sc-Y-ODS variant developed by our group was assessed in a stagnant liquid PbLi environment. The experiments were performed at 600°C for 500 and 1000 hours, and the subsequent microscopical investigation identified a solution-based attack as the dominant corrosion damage of both materials. The metal loss of the conventional Eurofer-97 steel was 66.2 µm after 1000 h exposure, corresponding to a rate of 580 µm/year. In contrast, the ODS Eurofer variant strengthened with various fine Sc-Y complex oxides showed a 70% lower corrosion damage, mainly owing to formation of a Sc-Y-rich Pb surface layer. To understand the degradation process in more detail, both materials were characterized before and after the PbLi exposure in terms of their microstructures and mechanical behavior including hardness, tensile, impact and static fracture toughness tests.
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Research context
OpenAlex topics: Fusion materials and technologies · Nuclear Materials and Properties · Ion-surface interactions and analysis
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (47)
Show source-provided references
1. Compatibility of reduced activation ferritic martensitic steel JLF-1 with liquid metals Li and Pb-17Li10.1016/j.fusengdes.2011.12.013 ↗
2. Microstructural characterization of Eurofer-97 and Eurofer-ODS steels before and after multi-beam ion irradiations at JANNUS Saclay facility10.1016/j.jnucmat.2015.05.045 ↗
3. Long-term corrosion behavior of EUROFER RAFM steel in static liquid Pb-16Li at 550°C10.1016/j.fusengdes.2020.111829 ↗
4. Perspective of ODS alloys application in nuclear environments10.1016/S0022-3115(02)01043-7 ↗
5. Current status and future prospective of advanced radiation resistant oxide dispersion strengthened steel (ARROS) development for nuclear reactor system applications10.1016/j.net.2015.12.005 ↗
6. Comparison of corrosion behavior of bare and hot-dip coated EUROFER steel in flowing Pb–17Li10.1016/j.jnucmat.2007.03.205 ↗
7. Compatibility behavior of EUROFER steel in flowing Pb–17Li10.1016/j.jnucmat.2008.12.271 ↗
8. Corrosion behavior of 9Cr-ODS steel in stagnant liquid lithium and lead–lithium at 873 K10.1016/j.jnucmat.2013.07.026 ↗
9. H. Feuerstein, H. Gräbner, J. Oschinski, J. Beyer, S. Horn, L. Hörner, K. Santo, Compatibility of 31 Metals, Alloys and Coatings with Static Pb-17li Eutectic Mixture, report FZK 5596, 1995.
10. Flow rate dependent corrosion behavior of Eurofer steel in Pb-15.7Li10.1016/j.jnucmat.2010.12.277 ↗
11. Long-term corrosion behavior of ODS-Eurofer in flowing Pb-15.7Li at 550°C10.1016/j.nme.2016.04.011 ↗
12. Corrosion behavior of Fe-14Cr-2W and Fe-9Cr-2W ODS steels in stagnant liquid Pb with different oxygen concentration at 550 and 650°C10.1016/j.jnucmat.2013.07.040 ↗
13. Behaviour of pre-stressed T91 and ODS steels exposed to liquid lead-bismuth eutectic10.1016/j.corsci.2017.12.005 ↗
14. Evaluation of Pb-17Li compatibility of ODS Fe-12Cr-5Al alloys10.1016/j.jnucmat.2016.07.017 ↗
15. Survey of oxide candidate for advanced 9%, 14% and 17%Cr ODS steels for fusion applications10.1016/j.fusengdes.2017.04.048 ↗
16. ODS EUROFER steel strengthened by Y-(Ce, Hf, La, Sc, and Zr) complex oxides10.3390/met9111148 ↗
17. Effect of oxide layer and the duration of exposure on the liquid metal corrosion mechanism of RAFM steel in molten Pb-Li10.1016/j.corsci.2021.109321 ↗
18. The effect of coatings on the compatibility of Fe-Cr steels with Pb-Li10.1016/j.jnucmat.2010.12.286 ↗
19. Compatibility of SiC with ODS FeCrAl in flowing Pb-Li at 600–700°C10.1016/j.fusengdes.2021.112389 ↗
20. Development of anti-permeation and corrosion barrier coatings for the WCLL breeding blanket of the European DEMO10.1016/j.fusengdes.2021.112453 ↗
21. Comparison of microstructural properties and Charpy impact behaviour between different plates of the Eurofer97 steel and effect of isothermal ageing10.1016/j.jnucmat.2011.06.018 ↗
22. Metallurgical properties of reduced activation martensitic steel Eurofer97 in the as-received condition and after thermal ageing10.1016/S0022-3115(02)01013-9 ↗
23. TEM characterization of precipitates in EUROFER 9710.1016/j.pnucene.2011.10.006 ↗
24. Grain boundary microchemistry and metallurgical characterization of Eurofer’97 after simulated service conditions10.1016/j.jnucmat.2004.04.055 ↗
25. Grain structural characterization of 9Cr–ODS steel aged at 973 K up to 10,000 h by electron backscatter diffraction10.1016/j.jnucmat.2014.08.047 ↗
26. On the thermal stability of a 9Cr-ODS steel aged at 700°C up to 10000 h - mechanical properties and microstructure10.1016/j.msea.2020.139292 ↗
27. Comparison of austenitic and martensitic steels behaviour in semi-stagnant Pb17Li10.1016/0022-3115(92)90619-V ↗
28. The compatibility of martensitic steels with liquid Pb-17Li10.1016/S0022-3115(98)00003-8 ↗
29. Corrosion of Fe9Cr1Mo steel in stagnant liquid lead-lithium eutectic10.1016/j.fusengdes.2012.01.014 ↗
30. Corrosion characteristics of RAFM steels and unalloyed metals in static Pb-17Li10.1585/pfr.8.3405053 ↗
31. Pint · Mater. High Temp. · 2014 · 29 · 12910.3184/096034012X13334529777329 ↗
32. Al2O3 coating as barrier against corrosion in Pb-17Li10.1016/j.fusengdes.2017.03.070 ↗
33. Short-term corrosion behavior of Indian RAFM steel in liquid Pb-Li: Corrosion mechanism and effect of alloying elements10.1016/j.jnucmat.2019.04.018 ↗
34. Comparison of corrosion behavior of EUROFER and CLAM steels in flowing Pb-5.7Li10.1016/j.jnucmat.2014.07.045 ↗
35. Thermodynamic properties of oxygen in Yttrium-Oxygen solid solutions10.1007/BF02915613 ↗
36. Effect of yttrium addition on the microstructure and mechanical properties of ODS RAF steels10.1016/j.jnucmat.2014.08.040 ↗
37. B. Hary, R. Logé, J. Ribis, M.H. Mathon, M. van der Meer, T. Baudin, Y. de Carlan, Strain-induced dissolution of Y–Ti–O nano-oxides in a consolidated ferritic oxide dispersion strengthened (ODS) steel, Materialia 4 (2018) 444–448. 10.1016/j.mtla.2018.11.00210.1016/j.mtla.2018.11.002 ↗
38. Investigation on different oxides as candidates for nano-sized ODS particles in reduced-activation ferritic (RAF) steels10.1016/j.jnucmat.2013.09.008 ↗
39. Influence of scandium addition on the high-temperature grain size stabilization of oxide-dispersion-strengthened (ODS) ferritic alloy10.1016/j.msea.2015.03.117 ↗
40. Thermodynamic stability of oxide, nitride, and carbide coating materials in liquid Sn–25Li10.1016/j.jnucmat.2004.04.210 ↗
41. Effects of alloying elements and thermomechanical treatment on 9Cr reduced activation ferritic-martensitic (RAFM) steels10.1016/j.jnucmat.2012.10.015 ↗
42. D. Kumar, U. Prakash, V. V. Dabhade, K. Laha, T. Sakthivel, Influence of Yttria on Oxide Dispersion Strengthened (ODS) Ferritic Steel, ICMPC 2017, Materials Today: Proceedings 5, (2018), 3909-3913.10.1016/j.matpr.2017.11.646 ↗
43. Investigation of coarsening of oxide nanoparticles at 1400 K and its effect on the microstructure formation of and ODS Eurofer steel10.1016/j.matchar.2022.111723 ↗
44. Chemical compatibility of F82H and 316L in liquid metal heat transfer mediums Li, Na and NaK10.1016/j.jnucmat.2022.153546 ↗
45. Compatibility of materials in fusion first wall and blanket structures cooled by liquid metals10.1016/S0022-3115(09)80020-2 ↗
46. Corrosion of ferritic-martensitic steel in the eutectic Pb-17Li10.1016/S0022-3115(00)00322-6 ↗
47. Effect of machining on oxide development in type 316L stainless steel in high-temperature hydrogenated water10.1016/j.corsci.2021.109444 ↗