journal article·2019-09

Stable lattice thermal expansion of ZIRLO™: High-temperature X-ray diffraction results

Young-Sang Youn, Jeongmi Park, Sang Ho Lim

Publisher page

Abstract

Abstract Crystallographic properties of Zr and ZIRLO™ in the temperature range of 30–1430 °C were investigated using in situ high-temperature X-ray diffraction (HT-XRD). Hexagonal Zr diffraction peaks observed at 30 °C started to vanish above 1110 °C for Zr and 1230 °C for ZIRLO™ owing to oxidation, resulting in a composition with monoclinic ZrO2, tetragonal ZrO2, and rhombohedral Zr3O. Furthermore, based on Pawley refinement of in situ HT-XRD spectra, we demonstrated that the lattice thermal expansion in ZIRLO™ occurred in a stable manner compared to that in Zr, which contribute to the enhancement of its mechanical properties via thermal treatment.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Nuclear Materials and Properties · Advanced ceramic materials synthesis · Advancements in Solid Oxide Fuel Cells

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (30)

Show source-provided references
1. Ultra-high vacuum investigation of the surface chemistry of zirconium10.1016/S0022-3115(00)00131-8 ↗
2. Surface chemistry of zirconium10.1016/j.progsurf.2005.07.001 ↗
3. Bakradze · 2011
4. Investigation of NH4OH on Zircaloy-4 surfaces using electron emission spectroscopy10.5012/bkcs.2007.28.10.1751 ↗
5. The effects of Ar-ion bombardment and annealing of D2O/Zircaloy-4 surfaces using XPS and UPS10.5012/bkcs.2007.28.8.1341 ↗
6. Surface phenomena of deuterized ethanol exposed Zircaloy-4 surfaces10.5012/bkcs.2009.30.6.1349 ↗
7. Oxidation kinetics of zirconium examined by in situ X-ray diffraction10.1149/2.006304jes ↗
8. Landolt-Börnstein, Group III Condensed Matter
9. Oskarsson · 2000
10. XPS studies of the thermal behaviour of passivated Zircaloy-4 surfaces10.1002/sia.740111003 ↗
11. Zirconia powders and Zircaloy oxide films: tetragonal phase evolution during 400°C autoclave tests10.1016/0022-3115(95)00108-5 ↗
12. Initial oxidation of zirconium and Zircaloy-2 with oxygen and water vapor at room temperature10.1016/0022-3115(95)00194-8 ↗
13. Air oxidation of Zircaloy-4, M5® and ZIRLO™ cladding alloys at high temperatures10.1016/j.jnucmat.2011.04.012 ↗
14. Raman investigation of pre- and post-breakaway oxide scales formed on Zircaloy-4 and M5® in air at high temperature10.1016/j.jnucmat.2011.11.071 ↗
15. Surface analysis study on ZIRLO cladding hulls oxidized at low temperatures10.7733/jnfcwt.2014.12.3.235 ↗
16. Temperature-dependent variations of the interface between UO2 and Zr10.1002/bkcs.10403 ↗
17. Compositional changes at the interface between thorium-doped uranium dioxide and zirconium due to high-temperature annealing10.1016/j.jnucmat.2018.03.028 ↗
18. In situ study of the solid-State formation of U1–xAmxO2±δ solid solution10.1021/ic301124d ↗
19. Studying radiotoxic materials by high temperature X-ray diffraction10.1016/j.apmt.2016.03.005 ↗
20. Lattice thermal expansion of Pu1−yAmyO2−x plutonium–americium mixed oxides10.1107/S1600576717014832 ↗
21. Kofstad · 1966
22. Insight into the Am–O phase equilibria: a thermodynamic study coupling high-temperature XRD and CALPHAD modeling10.1021/acs.inorgchem.7b00572 ↗
23. The use of Hi-Res TGA, TG-FTIR, HT-DRIFT and HT-XRD in the study of the decomposition of La2(C2O4)3·10H2O10.1016/S0040-6031(00)00469-X ↗
24. A study into the impact of interface roughness development on mechanical degradation of oxides formed on zirconium alloys10.1016/j.jnucmat.2015.01.028 ↗
25. In-situ digital image correlation for fracture analysis of oxides formed on zirconium alloys10.1016/j.corsci.2016.05.026 ↗
26. Ceramic coating for corrosion (c3) resistance of nuclear fuel cladding10.1016/j.surfcoat.2015.08.062 ↗
27. Zirconium under pressure: phase transitions and thermodynamics10.1088/0953-8984/18/5/001 ↗
28. The O−Zr (Oxygen-Zirconium) system10.1007/BF02881546 ↗
29. Martensitic transformation in zirconia containing ceramics and its applications10.1016/j.cossms.2006.02.012 ↗
30. Microstructure and growth mechanism of oxide layers formed on Zr alloys studied with micro-beam synchrotron radiation