Iodine sorption by microwave irradiated hydrotalcites

Abstract Mg–Al hydrotalcite-like compounds (HT) were prepared by the microwave method on the one hand with ethoxide–acetylacetonate and on the other with acetylacetonate as precursors. They presented a maximum sorption capacity of 2.179 and 1.517 meq of 131I−/g of hydrotalcite respectively. When the hydrotalcites were calcined and rehydrated in a 131I− solution, iodine sorption decreased in both samples to 1.515 and 1.446, respectively. The corresponding value for nitrated hydrotalcite which was prepared by the conventional method for comparison purposes, was 0.570. The radionuclide content in hydrotalcites was determined by γ-spectrometry. 131I− sorption is dependent on two main parameters: one is the type of the interlayer organic material and the second the surface area. It was found that hydrotalcites prepared with ethoxide–acetylacetonate were better sorbents for 131I− than those with acetylacetonate. Still, if the specific surface area increased, 131I−sorption increased as well; nitrated HT resulted in low specific surface area and a low sorption capacity. It is, therefore, concluded that organic residues present in the samples prepared by the microwave method favor the sorption of radioactive anions, in particular 131I− if compared with nitrated and/or carbonate interlayered hydrotalcites.