journal article·2024-12

Liquid lead resistance and cracking of novel 1Al-Sc-Y ODS Eurofer steel

Martina Pazderová, Anna Hojná, Hynek Hadraba, Luděk Stratil, Filip Šiška, Michal Chocholoušek, David Bricín, Jan Čížek

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Abstract

Novel 1Al-S c-Y ODS Eurofer steel for use in high temperature heavy metal cooling technologies has been developed by a mechanical alloying of feedstock powders using spark plasma sintering technique and a two-step heat treatment. The 1 wt.% Al has been added to increase the resistance in the environments at high temperatures. This paper reports the microstructure and mechanical properties of the material in the as-manufactured state, and after exposure in liquid lead. Emphasis is placed on the determination of environmental resistance and namely susceptibility to cracking in contact with liquid lead. The material specimens were exposed to static liquid lead with an average concentration of oxygen 1 × 10 −6 wt.% at 600 °C for 1000 h and then, tensile, impact, fracture toughness and slow three-point bend testing was performed. After the exposure, some Pb penetrated into a subsurface layer which in fact caused wetting but testing with the remains of liquid lead at the surface of corroded specimens at 350 °C showed that the steel stayed very low susceptible to the cracking.
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Research context

OpenAlex topics: High Temperature Alloys and Creep · Nuclear Materials and Properties · Hydrogen embrittlement and corrosion behaviors in metals

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (61)

Show source-provided references
1. Compatibility tests on steels in molten lead and lead–bismuth10.1016/S0022-3115(01)00538-4 ↗
2. Lead-cooled system design and challenges in the frame of generation IV international forum10.1016/j.jnucmat.2011.04.042 ↗
3. Overview of lead-cooled fast reactor activities10.1016/j.pnucene.2013.11.011 ↗
4. Comparison of the corrosion behavior of austenitic and ferritic/martensitic steels exposed to static liquid Pb-Bi at 450 and 550°C10.1016/j.jnucmat.2004.07.064 ↗
5. Performance of 9 % Cr steels in flowing lead-bismuth eutectic at 450 and 550°C, and 10−6 mass% dissolved oxygen10.1016/j.nucengdes.2014.01.023 ↗
6. Compatibility of structural steels with heavy liquid metals: from a cross-cutting view
7. Characterization of corrosion phenomena and kinetics on T91 ferritic/martensitic steel exposed at 450 and 550°C to flowing Pb-Bi eutectic with 10 − 7 mass% dissolved oxygen10.1016/j.jnucmat.2017.07.031 ↗
8. Performance of 9Cr ferritic-martensitic steels in flowing lead for 8000 h10.1016/j.jnucmat.2021.153092 ↗
9. Microstructural characterization of Eurofer-97 and Eurofer-ODS steels before and after multi-beam ion irradiations at JANNUS Saclay facility10.1016/j.jnucmat.2015.05.045 ↗
10. Corrosion behavior and mechanism of CLAM and 316L steels in flowing Pb-17Li alloy under magnetic field10.1016/j.net.2021.12.020 ↗
11. Corrosion investigations of steels in flowing lead at 400°C and 550°C10.1016/S0022-3115(01)00522-0 ↗
12. A review of steel corrosion by liquid lead and lead-bismuth10.1016/j.corsci.2009.03.013 ↗
13. Corrosion behavior of Fe–14Cr–2W and Fe–9Cr–2W ODS steels in stagnant liquid Pb with different oxygen concentration at 550 and 650°C10.1016/j.jnucmat.2013.07.040 ↗
14. Embrittlement of the martensitic steel 91 tested in liquid lead10.1016/S0022-3115(01)00525-6 ↗
15. Behavior of the steel T91 under multi axial loading in contact with liquid and solid Pb10.3390/met7090342 ↗
16. Effect of applied stress on T91 steel performance in liquid lead at 400°C10.3390/ma11122512 ↗
17. Environmentally-assisted cracking of the T91 in heavy liquid metals10.1515/corrrev-2019-0035 ↗
18. Liquid metal embrittlement susceptibility of ferritic–martensitic steel in liquid lead alloys10.1016/j.jnucmat.2008.02.008 ↗
19. Environmental degradation of structural materials in liquid lead- and lead-bismuth eutectic-cooled reactors10.1016/j.pmatsci.2022.100920 ↗
20. Behaviour of the steel T91 under uniaxial and multiaxial slow loading in contact with liquid lead10.1016/j.jnucmat.2015.05.041 ↗
21. Influence of liquid lead and lead–bismuth eutectic on tensile, fatigue and creep properties of ferritic/martensitic and austenitic steels for transmutation systems10.1016/j.jnucmat.2011.04.047 ↗
22. Microstructure and mechanical properties of two ODS ferritic/martensitic steels10.1016/S0022-3115(02)01193-5 ↗
23. ODS EUROFER Steel Strengthened by Y-(Ce, Hf, La, Sc, and Zr) Complex Oxides10.3390/met9111148 ↗
24. Oxide dispersion strengthened steels
25. Ukai · 2017 · 357
26. Current status and future prospective of Advanced Radiation Resistant Oxide Dispersion Strengthened Steel (ARROS) development for nuclear reactor system applications10.1016/j.net.2015.12.005 ↗
27. The effects of Cr and Al concentrations on the oxidation behavior of oxide dispersion strengthened ferritic alloys10.1016/j.corsci.2013.07.004 ↗
28. Corrosion resistance of Al-alloying high Cr–ODS steels in stagnant lead–bismuth10.1016/j.jnucmat.2009.10.023 ↗
29. Oxidative passivation of FeCrAl steels in lead-bismuth eutectic under oxygen-controlled static conditions at 700 and 800°C10.1016/j.jnucmat.2019.06.004 ↗
30. Investigation on oxygen controlled liquid lead corrosion of surface treated steels10.1016/S0022-3115(99)00211-1 ↗
31. Oxide scales formed on Fe–Cr–Al-based model alloys exposed to oxygen containing molten lead10.1016/j.jnucmat.2013.02.044 ↗
32. Mapping of 475 °C embrittlement in ferritic Fe–Cr–Al alloys10.1016/j.scriptamat.2010.08.015 ↗
33. Microstructural stability of Fe–Cr–Al alloys at 450–550°C10.1016/j.jnucmat.2014.11.101 ↗
34. Liquid metal embrittlement of an Fe10Cr4Al ferritic alloy exposed to oxygen-depleted and-saturated lead-bismuth eutectic at 350°C10.1016/j.corsci.2019.108364 ↗
35. A comparative study on liquid metal embrittlement susceptibility of three FeCrAl ferritic alloys in contact with liquid lead-bismuth eutectic at 350°C10.1016/j.corsci.2021.109346 ↗
36. Effect of temperature on liquid metal embrittlement susceptibility of an Fe10Cr4Al ferritic alloy in contact with stagnant lead-bismuth eutectic10.1016/j.jnucmat.2020.152196 ↗
37. The microstructure and mechanical properties of Al-containing 9Cr ODS ferritic alloy10.1016/j.jallcom.2015.06.214 ↗
38. Oxidation resistance in LBE and air and tensile properties of ODS ferritic steels containing Al/Zr elements10.1016/j.jnucmat.2014.07.028 ↗
39. Influence of Al addition on the microstructure and mechanical properties of Zr-containing 9Cr-ODS steel10.1016/j.jmrt.2021.05.112 ↗
40. Performance of Sc-Y-ODS variant of Eurofer steel in stagnant PbLi at 600°C10.1016/j.jnucmat.2022.154227 ↗
41. Influence of scandium addition on the high-temperature grain size stabilization of oxide-dispersion-strengthened (ODS) ferritic alloy10.1016/j.msea.2015.03.117 ↗
42. ESIS TC7D-1-96D guidelines for terminology and nomenclature in the field of structural integrity
43. Comparison of corrosion behavior of the austenitic steel 316L in static and flowing liquid lead10.1115/1.4049719 ↗
44. Fracture mechanics behavior of the T91 martensitic steel in contact with liquid lead-bismuth eutectic for application in an accelerator driven system10.1016/j.jnucmat.2011.04.021 ↗
45. Microstructure evolution in nono-reinforced ferritic steel processed by mechanical alloying and spark plasma sintering10.1007/s11661-013-2107-y ↗
46. On the understanding of microstructural evolution during hot deformation of n-ODS-18Cr ferritic steel containing heterogeneous microstructure10.1016/j.msea.2020.140343 ↗
47. Effects of aluminum on microstructure and mechanical behavior of 14Cr–ODS steels10.1016/j.jnucmat.2014.12.079 ↗
48. Reducibility of oxides and sulphides in metallurgical processes
49. Present development status of EUROFER and ODS-EUROFER for application in blanket concepts10.1016/j.fusengdes.2005.06.186 ↗
50. Controlling the ductile to brittle transition in Fe–9 %Cr ODS steels10.1016/j.jnucmat.2013.03.097 ↗
51. Effects of manufacturing process on impact properties and microstructures of ODS steels10.1016/j.jnucmat.2014.07.075 ↗
52. Fracture behavior of 9Cr nanostructured ferritic alloy with improved fracture toughness10.1016/j.jnucmat.2014.03.007 ↗
53. Fracture behavior of the ODS steels prepared by internal oxidation10.1016/j.fusengdes.2017.03.008 ↗
54. Comparison of microstructural properties and Charpy impact behaviour between different plates of the Eurofer97 steel and effect of isothermal ageing10.1016/j.jnucmat.2011.06.018 ↗
55. Schroer · 2007 · 7364
56. J. Töpfer, S. Aggarwal, R. Dieckmann, Point defects and cation tracer diffusion in (CrxFe1−x) 3 − δO4 spinels. Solid State Ion 81 (1995) 251–266. doi.org/10.1016/0167-2738(95)00190-H.10.1016/0167-2738(95)00190-H ↗
57. Improvement of steels corrosion resistance in liquid lead and lead-bismuth by coatings – review - SI10.1115/1.4048631 ↗
58. The Nanostructure of the Oxide Formed on Fe–10Cr–4Al Exposed in Liquid Pb10.1017/S1431927621000337 ↗
59. Behaviour of pre-stressed T91 and ODS steels exposed to liquid lead-bismuth eutectic10.1016/j.corsci.2017.12.005 ↗
60. Mechanical properties of the steel T91 in contact with lead10.1016/j.nucengdes.2014.10.004 ↗
61. Liquid metal embrittlement susceptibility of an oxide-dispersion strengthened FeCrAl alloy in contact with liquid lead-bismuth eutectic at 350°C10.1016/j.corsci.2022.110603 ↗