journal article·2025-01

Comparative studies of the long-term corrosion behavior of Zr-Sn-Fe-Cr-Ni alloys in pure water at 360 °C/18.6 MPa with high and low dissolved oxygen content

Aijia Lei, Xun Dai, Yufeng Du, Jingjing Liao, Ruiju Deng, Jiangtao Xu, Xuefei Huang

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Abstract

This study compared the uniform corrosion behavior of Zr-Sn-Fe-Cr-Ni alloys in deionized water at 360 °C/18.6 MPa with high and low concentration of dissolved oxygen (DO). It was found that high concentration of DO accelerated the corrosion rate of the Zr-Sn-Fe-Cr-Ni alloys and led to an earlier corrosion transition. Increased DO concentration resulted in a higher content of t-ZrO 2 near the metal-oxide interface, which induced greater in-plane compressive stress in the oxide film and a high-level phase transformation from t-ZrO 2 to m-ZrO 2. This, in turn, led to an earlier occurrence of corrosion transition.
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OpenAlex topics: Nuclear Materials and Properties · Nuclear reactor physics and engineering · Fusion materials and technologies

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