journal article·2024-02Open access

Deformation strengthening of uranium and dilute uranium alloys

Kenneth H. Eckelmeyer, Gordon B. Dudder, Lloyd R. Chapman, Gerard M. Ludtka, Mary K. O'Brien

Abstract

The strength and ductility of uranium and dilute uranium alloys can be substantially improved by deformation strengthening. The yield strength of unalloyed uranium can be nearly doubled by rolling in the vicinity of 250 °C. The embrittling effect of hydrogen is also overcome, eliminating the need for vacuum outgassing to obtain good ductility. Significant differences in longitudinal versus transverse tensile properties result, in part, from texture introduced by unidirectional rolling. Warm rolling of U-2.3 %Nb results in both traditional strain hardening and a significant Bauschinger effect, resulting in differences between tensile and compressive yield strength. A similar combination of strain hardening and Bauschinger effect also occurs in deformation strengthened U-0.75 %Ti. Warm rolling of U-0.75 %Ti results in significantly better combinations of tensile yield strength and ductility than can be obtained by conventional age hardening. Warm rolling prior to aging also reduces the loss of ductility which typically accompanies conventional age hardening. An approach is developed in which the effects of prior deformation on tensile and compressive yield strengths are analyzed in terms of texture, long-range dislocation, and Bauschinger effects. The Bauschinger effect is shown to vary in sign with the type of deformation, thus providing opportunities to tailor tensile and compressive properties.
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Research context

OpenAlex topics: Nuclear Materials and Properties · Fusion materials and technologies · High Temperature Alloys and Creep

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References (34)

Show source-provided references
1. K.H. Eckelmeyer, Uranium and Uranium Alloys, ASM Metals Handbook, 10th ed., Vol. 2, Properties and Selection, 1991, pp. 670–682.10.31399/asm.hb.v02.a0001085 ↗
2. The influence of warm rolling upon the ductile/brittle transition temperature of α-uranium
3. The effect of grain size and cold work on the tensile properties of alpha-uranium10.1016/0022-5088(64)90048-7 ↗
4. The effects of warm work on some mechanical and fabrication properties of uranium10.1016/0022-3115(73)90152-9 ↗
5. C.J.E. Smith and J.C. Ruckman, The effect of warm working on the microstructure and ductility of uranium, AWRE O 27/70, 1970.
6. Precipitation hardening in uranium-rich uranium-titanium alloys
7. The mechanical properties of two-phase uranium alloy
8. E.L. Bird, Y-12 National Security Center, Unpublished Research, 1990.
9. Melting and casting of uranium alloys
10. Effect of hydrogen on mechanical properties of uranium
11. The embrittlement of U By H2O and hydrogen10.1016/S0010-938X(70)80083-X ↗
12. Hydrogen in uranium alloys
13. Overview of hydrogen embrittlement of uranium and uranium alloys
14. G.B. Dudder, Pacific Northwest National Laboratory, Unpublished Research, 1988.
15. The influence of temperature on slip and twinning in uranium10.1016/0001-6160(71)90128-3 ↗
16. S.K. Lawrence, Los Alamos National Laboratory, Private Communication, 2020.
17. The effects of hydrogen on the tensile properties of uranium when tested in different environments10.1016/0022-3115(69)90062-2 ↗
18. The effect of strain rate on the tensile flow and fracture of α-uranium10.1016/0022-3115(80)90063-X ↗
19. P. Tubesing and K.H. Eckelmeyer, Los Alamos National Laboratory, Unpublished Research, 2002.
20. Davis, W.D., Solubility, determination, diffusion and mechanical effects of hydrogen in uranium, Knolls Atomic Power Lab, KAPL-1548, 1956.10.2172/4340162 ↗
21. Assessing the influence of microstructure on uranium hydride size distributions via small angle neutron scattering10.1016/j.mtla.2023.101737 ↗
22. Deep trapping states for hydrogen in deformed iron10.1016/0001-6160(80)90038-3 ↗
23. Effects of prior cold work on hydrogen trapping and diffusion in API X-70 line pipe steel during electrochemical charging10.5006/0990 ↗
24. The embrittement of U-0.8% Ti by absorbed hydrogen
25. A thermal desorption spectroscopy study of hydrogen trapping in polycrystalline α-uranium10.1016/j.jnucmat.2015.03.023 ↗
26. A thermal desorption study of the kinetics of uranium hydride decomposition10.1016/j.jnucmat.2013.09.032 ↗
27. Holden · 1958 · 78
28. D.F. Teter, et al., Processing-property relationships in wrought uranium, LA-UR-06-2890, 2006.
29. Quench rate effects in U-6% Nb10.1007/BF02648560 ↗
30. Analysis of the Bauschinger effect10.1016/0001-6160(86)90220-8 ↗
31. Hertzberg · 1976 · 101
32. The effect of age hardening on the mechanical behavior of U-0.75 wt.%Ti and U-2.0 wt.% Mo10.1016/0022-3115(76)90282-8 ↗
33. The effect of Ti content on age hardening and mechanical properties of uranium-titanium alloys10.1016/j.jnucmat.2022.153578 ↗
34. W.T. Nachtrab, Nuclear Metals Inc., Unpublished Research, 1989.