journal article·2022-09

Surface modification and deuterium retention in hot-rolled potassium doped tungsten alloy exposed to deuterium plasma

Xiaolei Ma, Ting Wang, Xiaoxin Zhang, Yue Yuan, Long Cheng, Jipeng Zhu, Wei Lv, Shaoting Lang, Zihao Wang, Changchun Ge, Qingzhi Yan

Publisher page

Abstract

A 25 kg potassium doped tungsten (KW) plate dispersed with ∼71 nm K bubbles was prepared by hot rolling firstly. In order to evaluate the radiation resistance of KW, the surface blistering and deuterium (D) retention were investigated on KW and pure tungsten (PW), which were exposed to low-energy (50 eV) and high-flux (∼10 22 D m −2 s −1 ) D plasmas at 523 K and 573 K to a fluence of 1.08 × 10 26 m −2 . After irradiation, D desorption information of all the irradiated samples were measured by thermal desorption spectroscopy (TDS). The results indicate that severe blistering occurs on both PW and KW under different irradiation conditions. Compared to PW, KW tends to form more but smaller blisters on the surface. Nevertheless, the blistering area ratio of KW is comparable with that of PW. In addition, the blisters prefer to form on those grains with surface orientation close to (111). In terms of D retention, compared with PW, the total D retention of KW increases by a factor of ∼ 2.5 under both irradiation conditions. The present results indicate that the presence of K bubbles will increase the D retention. The reasons for the difference in surface morphology evolution and total D retention of PW and KW are discussed in detail.
Source: expertdata · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Fusion materials and technologies · Nuclear Materials and Properties · High-Temperature Coating Behaviors

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (68)

Show source-provided references
1. Hydrogen isotope retention and recycling in fusion reactor plasma-facing components10.1016/S0022-3115(01)00732-2 ↗
2. Recent progress in research on tungsten materials for nuclear fusion applications in Europe10.1016/j.jnucmat.2012.08.018 ↗
3. Plasma facing and high heat flux materials - Needs for ITER and beyond10.1016/S0022-3115(02)01175-3 ↗
4. Materials for the plasma-facing components of fusion reactors10.1016/j.jnucmat.2004.04.005 ↗
5. Effect of low-temperature rolling on the tensile behavior of commercially pure tungsten10.1016/j.msea.2008.01.013 ↗
6. Microstructure and helium irradiation performance of high purity tungsten processed by cold rolling10.1016/j.jnucmat.2016.07.038 ↗
7. Tungsten foil laminate for structural divertor applications - Analyses and characterisation of tungsten foil10.1016/j.jnucmat.2012.02.030 ↗
8. A comparative study on the in situ helium irradiation behavior of tungsten: Coarse grain vs. nanocrystalline grain10.1016/j.actamat.2018.01.015 ↗
9. Microstructure and mechanical properties of super-strong nanocrystalline tungsten processed by high-pressure torsion10.1016/j.actamat.2006.05.005 ↗
10. Plastic flow localization in bulk tungsten with ultrafine microstructure10.1063/1.1875754 ↗
11. High temperature fracture experiments on tungsten-rhenium alloys10.1016/j.ijrmhm.2010.03.002 ↗
12. Segregation and aggregation of rhenium in tungsten grain boundary: Energetics, configurations and strengthening effects10.1016/j.jnucmat.2019.151867 ↗
13. Microstructure and mechanical properties of a W-2wt.%Y2O 3 composite produced by sintering and hot forging10.1016/j.jnucmat.2013.01.301 ↗
14. W-Y2O3 composite nanopowders prepared by freeze-drying method and its sintering characteristics10.1016/j.jallcom.2019.07.214 ↗
15. Extraordinary high ductility/strength of the interface designed bulk W-ZrC alloy plate at relatively low temperature10.1038/srep16014 ↗
16. Deformability enhancement in ultra-fine grained, Ar-contained W compacts by TiC additions up to 1.1%10.1016/j.msea.2008.05.012 ↗
17. MD simulations of onset of tungsten fuzz formation under helium irradiation10.1016/j.nimb.2012.11.029 ↗
18. Growth annealing equilibrium of tungsten nanostructures by helium plasma irradiation in non-eroding regimes10.1016/j.jnucmat.2013.04.040 ↗
19. A review of modelling and simulation of hydrogen behaviour in tungsten at different scales10.1088/0029-5515/54/8/086001 ↗
20. Deuterium occupation of vacancy-type defects in argon-damaged tungsten exposed to high flux and low energy deuterium plasma10.1088/0029-5515/56/3/036010 ↗
21. Surface modification of molten W exposed to high heat flux helium neutral beams10.1016/j.jnucmat.2013.02.043 ↗
22. Deuterium retention in rhenium-doped tungsten10.1016/j.jnucmat.2007.01.110 ↗
23. Deuterium implantation into Y2O3-doped and pure tungsten: Deuterium retention and blistering behavior10.1016/j.jnucmat.2017.02.005 ↗
24. The high-flux effect on deuterium retention in TiC and TaC doped tungsten at high temperatures10.1016/j.jnucmat.2017.07.028 ↗
25. Design of highly thermal-shock resistant tungsten alloys with nanoscaled intra- and inter-type K bubbles10.1016/j.jallcom.2018.12.168 ↗
26. Tungsten–potassium: a promising plasma-facing material10.1007/s42864-019-00018-5 ↗
27. Refractory metals revolutionizing the lighting technology: A historical review10.1016/j.ijrmhm.2014.11.002 ↗
28. Thermo-mechanical and thermal shock characterization of potassium doped tungsten10.1016/j.ijrmhm.2010.03.001 ↗
29. The effect of heat treatments on pure and potassium doped drawn tungsten wires: Part II – Fracture properties10.1016/j.msea.2018.09.029 ↗
30. The effect of heat treatments on pure and potassium doped drawn tungsten wires: Part I - Microstructural characterization10.1016/j.msea.2018.09.027 ↗
31. Plastic deformation of recrystallized tungsten-potassium wires: Constitutive deformation law in the temperature range 22–600°C[J]10.1016/j.ijrmhm.2018.01.012 ↗
32. Correlation between the microstructure, mechanical/thermal properties, and thermal shock resistance of K-doped tungsten alloys10.1016/j.jnucmat.2019.03.056 ↗
33. Improvement of impact properties of tungsten by potassium doping10.1016/j.fusengdes.2019.01.130 ↗
34. Mechanical properties and microstructural characterizations of potassium doped tungsten10.1016/j.nucengdes.2011.10.008 ↗
35. Basic thermal-mechanical properties and thermal shock, fatigue resistance of swaged + rolled potassium doped tungsten10.1016/j.jnucmat.2014.05.032 ↗
36. Preparation of hot-rolled potassium doped tungsten (KW) thick plate and performance of KW-Cu monoblock mock-ups under high heat flux testing
37. Large-scale potassium-doped tungsten alloy with superior recrystallization resistance, ductility and strength induced by potassium bubbles10.1016/j.jnucmat.2021.153450 ↗
38. Irradiation hardening behaviors of large-scale hot rolling potassium-doped tungsten alloy under synergistic irradiations of Fe11+ ion combined with deuterium and helium plasmas
39. Development and optimization of STEP-A linear plasma device for plasma-material interaction studies10.13182/FST16-115 ↗
40. Aggravated blistering and increased deuterium retention in iron-damaged tungsten after exposure to deuterium plasma with various surface temperatures10.1088/1741-4326/aad1a0 ↗
41. Surface morphology and deuterium retention in tungsten exposed to high flux D plasma at high temperatures10.1016/j.jnucmat.2014.11.079 ↗
42. Mechanism for orientation dependence of blisters on W surface exposed to D plasma at low temperature10.1016/j.jnucmat.2016.05.011 ↗
43. Deuterium behavior in tungsten exposed to deuterium plasma with rising or declining temperature
44. Vacancy trapping mechanism for hydrogen bubble formation in metal10.1103/PhysRevB.79.172103 ↗
45. Blister bursting and deuterium bursting release from tungsten exposed to high fluences of high flux and low energy deuterium plasma10.1088/0029-5515/47/3/006 ↗
46. Subsurface morphology changes due to deuterium bombardment of tungsten10.1088/0031-8949/2009/T138/014040 ↗
47. Temperature dependence of surface topography and deuterium retention in tungsten exposed to low-energy, high-flux D plasma10.1016/j.jnucmat.2011.01.088 ↗
48. Surface morphology and deuterium retention in tungsten exposed to low-energy, high flux pure and helium-seeded deuterium plasmas10.1088/0031-8949/2009/T138/014048 ↗
49. CHRISTIAN graduated in physics from Oxford University in 1945 and obtained a D. Phil. in Metallurgy in 1949
50. Observations of suppressed retention and blistering for tungsten exposed to deuterium-helium mixture plasmas
51. Microstructure dependence of deuterium retention and blistering in the near-surface region of tungsten exposed to high flux deuterium plasmas of 38 eV at 315 K10.1088/0031-8949/2007/T128/019 ↗
52. Blister formation and deuterium retention on tungsten exposed to low energy and high flux deuterium plasma10.1016/j.jnucmat.2004.10.137 ↗
53. Influence of neon seeding on the deuterium retention and surface modification of ITER-like forged tungsten
54. Surface modification of tungsten and tungsten-tantalum alloys exposed to high-flux deuterium plasma and its impact on deuterium retention
55. Hydrogenic retention in irradiated tungsten exposed to high-flux plasma
56. Effect of plastic deformation on deuterium retention and release in tungsten
57. Ion-driven deuterium retention in high-Z metals10.1016/j.jnucmat.2009.01.181 ↗
58. Multiscale modelling of the interaction of hydrogen with interstitial defects and dislocations in BCC tungsten
59. Dislocations mediate hydrogen retention in tungsten10.1088/0029-5515/54/4/042004 ↗
60. Trapping of hydrogen and helium at dislocations in tungsten: An ab initio study
61. Surface modification and deuterium retention of high energy rate forging W-Y2O3exposed to deuterium plasma10.1016/j.jnucmat.2018.06.022 ↗
62. The influence of helium on the bulk properties of fusion reactor structural materials10.1088/0029-5515/24/8/009 ↗
63. E. Diagram, C. Structures, The H-K (Hydrogen-Potassium) System The H-K (Hydrogen-Potassium) System, 18 (1997) 387–389.10.1007/s11669-997-0066-y ↗
64. Solubility of H in Molten K
65. Dissociation Pressure of KH
66. Dopant Observations in Thin Foils of Annealed Tungsten Wire10.1007/BF02647071 ↗
67. L. Rosta, A. Len, G. Pépy, P. Harmat, Nano-scale Morphology of Inclusions in Tungsten Wires - a Complex SANS Study, Neutron News. 23 (2012) 13–16. doi:10.1080/10448632.2012.645697.10.1080/10448632.2012.645697 ↗
68. A. Manhard, Deuterium Inventory in Tungsten After Plasma Exposure: A Microstructural Survey, 2013. https://opus.bibliothek.uni-augsburg.de/opus4/frontdoor/deliver/index/docId/19.81/file/Dissertation_Manhard.pdf