Age-hardening behaviors of the weld metals of 22% Cr and 25% Cr duplex stainless steels at 400 °C

Duplex stainless steel (DSS) alloys are attractive materials for pressure components in nuclear power plants as they offer a good combination of high strength, corrosion resistance, and weldability. However, DSS suffers from embrittlement and hardening upon exposure to temperatures of 250–500 °C. Most previous studies addressed only solution-treated materials, and limited research has been conducted on weld metals. In this study, the relationship between the nanostructural evolution and hardening of 22% Cr and 25% Cr DSS weld metals (fabricated with grade-2209 and 2594 welding materials, respectively) during aging at 400 °C was investigated. The results revealed that the degree of hardening of ferrite after aging at 400 °C for 1000 h was greater in the 22% Cr DSS weld metal than in the 25% Cr DSS weld metal. The ferrite phases of both samples underwent two different phase decomposition processes during aging, (1) phase separation (α → Fe-rich α + Cr-rich α’) and (2) solute clustering to form G-phase precursors, both of which were identified within the body-centered cubic structure of ferrite in the weld metals. Phase separation was less pronounced, whereas formation of G-phase precursors was more pronounced in the 22% Cr DSS weld metal than in the 25% Cr DSS. These results indicate that the extent of formation of G-phase precursors has a significant influence on predicting the degree of hardening of ferrite. The enhanced formation of G-phase precursors in the 22% Cr DSS weld metal was elucidated using thermodynamic simulations; the formation of the G-phase precursor was predominantly facilitated by the higher Mn fraction in the 22% Cr DSS weld metal. The findings of the present study are expected to aid the selection and/or further improvement of the compositional design of DSS welding materials, thereby increasing the long-term safety of DSS welded components in nuclear applications.