journal article·2023-03

Deuterium to protium isotope exchange in W-D co-deposited films below 200°C

Stepan Krat, Alexander Prishvitsyn, Elena Fefelova, Maria Popova, Ivan Sorokin, Yuri Gasparyan, Alexander Pisarev

Publisher page

Abstract

Hydrogen isotope exchange as a method for removal of heavy hydrogen isotopes from tungsten co-deposits in fusion devices was investigated by exposing fresh W-D co-deposited films in protium atmosphere. The temperature was in the range from room temperature to 473 K (200°C), the protium pressure was 1 atm, the time of exposure was 18 hours. It was shown that the efficiency of exchange increases with temperature, and at least 99% of deuterium was removed at 473 K from 250 nm thick films. Vacuum annealing was much less efficient at all experimental conditions. Similar to polycrystalline materials, multiple occupation of traps by hydrogen isotopes is suggested to be a key mechanism of D to H exchange in the co-deposits.
Source: expertdata · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Fusion materials and technologies · Nuclear Materials and Properties · Metal and Thin Film Mechanics

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (47)

Show source-provided references
1. Recent analysis of key plasma wall interactions issues for ITER10.1016/j.jnucmat.2009.01.037 ↗
2. Overview of fuel inventory in JET with the ITER-like wall10.1088/1741-4326/aa7475 ↗
3. Deposition of impurity metals during campaigns with the JET ITER-like Wall10.1016/j.nme.2018.12.024 ↗
4. Implications of PMI and wall material choice on fusion reactor tritium self-sufficiency10.1016/j.nme.2018.12.006 ↗
5. Tritium inventory in ITER plasma-facing materials and tritium removal procedures10.1088/0741-3335/50/10/103001 ↗
6. Deuterium retention and release in tungsten co-deposited layers10.1016/j.jnucmat.2009.03.028 ↗
7. Deuterium trapping in tungsten deposition layers formed by deuterium plasma sputtering10.1016/j.jnucmat.2010.01.024 ↗
8. Tungsten-deuterium co-deposition: Experiment and analytical description10.1016/j.vacuum.2017.12.004 ↗
9. An empirical scaling for deuterium retention in co-deposited beryllium layers10.1088/0029-5515/48/7/075008 ↗
10. Facility and the method for MEIS analysis of layers redeposited in plasma devices10.1088/1742-6596/748/1/012016 ↗
11. Issues and strategies for DEMO in-vessel component integration10.1016/j.fusengdes.2016.05.040 ↗
12. Deuterium retention in mixed Be-W-D codeposited layers10.1088/1741-4326/abae83 ↗
13. WallDYN simulations of material migration and fuel retention in ITER low power H plasmas and high power neon-seeded DT plasmas
14. Temperature dependence of D atom adsorption on polycrystalline tungsten10.1016/j.apsusc.2013.05.157 ↗
15. Deuterium removal from radiation damage in tungsten by isotopic exchange with hydrogen atomic beam
16. Recent progress in the understanding of H transport and trapping in W10.1088/1402-4896/aa8de0 ↗
17. Hydrogen isotope exchange in tungsten: discussion as removal method for tritium10.1016/j.jnucmat.2012.08.004 ↗
18. Hydrogen isotope exchange in tungsten during annealing in hydrogen atmosphere10.1088/1741-4326/aaf6c9 ↗
19. Substitution of heavy hydrogen isotopes in tungsten layers during gas exposure
20. A setup for study of co-deposited films10.1088/1748-0221/15/01/P01011 ↗
21. X-ray microanalysis of precious metal thin films: thickness and composition determination10.3390/coatings8020084 ↗
22. Coating thickness determination using x-ray fluorescence spectroscopy: monte carlo simulations as an alternative to the use of standards10.3390/coatings9020079 ↗
23. Reference-free evaluation of thin films mass thickness and composition through energy dispersive X-ray spectroscopy10.1016/j.matchar.2019.04.030 ↗
24. On the possibility of indirect measurement of the thin carbon films thickness using energy-dispersive analysis10.1016/j.tsf.2021.138937 ↗
25. Thickness determination of large-area films of yttria-stabilized zirconia produced by pulsed laser deposition10.1016/j.apsusc.2005.07.145 ↗
26. Three-dimensional electron microscopy simulation with the CASINO Monte Carlo software10.1002/sca.20262 ↗
27. Coating thickness measurement by electron probe microanalysis10.1088/0508-3443/14/11/320 ↗
28. Longhurst · 2006
29. Solute diffusion of hydrogen isotopes in tungsten—a gas loading experiment10.1088/1402-4896/ab4b42 ↗
30. Hydrogen isotopes transport in sputter-deposited tungsten coatings10.1016/j.fusengdes.2017.07.021 ↗
31. Hydrogen permeation behavior through tungsten deposition layer10.1016/j.fusengdes.2020.112083 ↗
32. Hydrogen transport behavior of metal coatings for plasma-facing components10.1016/0022-3115(90)90127-9 ↗
33. Experimental measurements and modeling of the deuterium release from tungsten co-deposited layers
34. Experimental determination of the deuterium binding energy with vacancies in tungsten10.1016/j.jnucmat.2016.04.052 ↗
35. Hydrogen-vacancy interaction in tungsten10.1088/0953-8984/3/49/004 ↗
36. Dissolving, trapping and detrapping mechanisms of hydrogen in bcc and fcc transition metals10.1063/1.4789547 ↗
37. Recombination coefficient of hydrogen on tungsten surface10.1016/j.jnucmat.2019.05.017 ↗
38. Fundamental aspects of deuterium retention in tungsten at high flux plasma exposure10.1063/1.4928407 ↗
39. Deuterium thermal desorption from vacancy clusters in tungsten10.1016/j.nimb.2016.04.038 ↗
40. Thermal desorption from self-damaged tungsten exposed to deuterium atoms10.1016/j.jnucmat.2014.11.022 ↗
41. Modelling deuterium release during thermal desorption of D+-irradiated tungsten10.1016/j.jnucmat.2007.09.028 ↗
42. Trapping of hydrogen isotopes in radiation defects formed in tungsten by neutron and ion irradiations10.1016/j.jnucmat.2013.01.018 ↗
43. D retention and depth profile behavior for single crystal tungsten with high temperature neutron irradiation10.1016/j.jnucmat.2020.152323 ↗
44. Air exposure and sample storage time influence on hydrogen release from tungsten10.1016/j.jnucmat.2010.07.011 ↗
45. Transport of hydrogen in metals with occupancy dependent trap energies10.1063/1.4896580 ↗
46. Solution and diffusion of hydrogen in tungsten10.1116/1.1492699 ↗
47. Influence of apparatus geometry and deposition conditions on the structure and topography of thick sputtered coatings10.1116/1.1312732 ↗