journal article·2015-10Open access

Heat capacity of Bi2UO6

Karin Popa, Ondrej Beneš, Philippe E. Raison, Jean-Christophe Griveau, Philipp Pöml, Eric Colineau, Rudy J.M. Konings, Joseph Somers

Abstract

In the frame of the safety of lead–bismuth eutectic cooled fast reactors, the thermal behaviour of bismuth(III) uranate(VI) was studied as a possible interaction product of the coolant and mixed oxide fuel. The heat capacity of Bi2UO6 were measured and presented here for the first time. The thermodynamic functions derived at T = 298.15 K are Cp(298.15 K) = 185.1 J K−1 mol−1, S°(298.15 K) = 238.8 J K−1 mol−1, and {H°(298.15 K)−H°(0 K)} = 34863 J mol−1.
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Research context

OpenAlex topics: Nuclear Materials and Properties · Nuclear materials and radiation effects · Radioactive element chemistry and processing

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