Fabrication and characterization of dual phase magnesia–zirconia ceramics doped with plutonia

Abstract Dual phase magnesia–zirconia ceramics doped with plutonia are being studied as an inert matrix fuel (IMF) for light water reactors. The motivation of this work is to develop an IMF with a thermal conductivity superior to that of the fuels based on yttria stabilized zirconia. The concept uses the MgO phase as an efficient heat conductor to increase thermal conductivity of the composite. In this paper ceramic fabrication and characterization by scanning electron microscopy, energy and wavelength dispersive X-ray spectroscopy is discussed. Characterization shows that the ceramics consist of the two-phase matrix and PuO2-rich inclusions. The matrix is comprised of pure MgO phase and MgO–ZrO2–PuO2 solid solution. The PuO2-rich inclusion contained dissolved MgO and ZrO2.