journal article·2014-01

Cold crucible induction melter studies for making glass ceramic waste forms: A feasibility assessment

Jarrod Crum, Vince Maio, John McCloy, Clark Scott, Brian Riley, Brad Benefiel, John Vienna, Kip Archibald, Carmen Rodriguez, Veronica Rutledge, Zihua Zhu, Joe Ryan, Matthew Olszta

Journal of Nuclear Materials· Volume 444· Issue 1-3
Publisher page

Abstract

Abstract Glass ceramics are being developed to immobilize fission products, separated from used nuclear fuel by aqueous reprocessing, into a stable waste form suitable for disposal in a geological repository. This work documents the glass ceramic formulation at bench scale and for a scaled melter test performed in a pilot-scale (∼1/4 scale) cold crucible induction melter (CCIM). Melt viscosity, electrical conductivity, and crystallization behavior upon cooling were measured on a small set of compositions to select a formulation for melter testing. Property measurements also identified a temperature range for melter operation and cooling profiles necessary to crystallize the targeted phases in the waste form. Bench scale and melter run results successfully demonstrate the processability of the glass ceramic using the CCIM melter technology.
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Research context

OpenAlex topics: Glass properties and applications · Nuclear materials and radiation effects · Advanced ceramic materials synthesis

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (34)

Show source-provided references
1. B.W. Bowan II, R. Meigs, E.C. Smith, Advancements in Joule Heated Melter Technology for Processing U.S. Department of Energy High Level Waste Global 2003: Atoms for Prosperity: Updating Eisenhowers Global Vision for, Nuclear Energy, 2003.
2. Chapman · AIChE Symp. Ser. · 1979 · 75 · 56
3. W. Tobie, S. Weisenburger, Proc. of the Waste Management ‘90: ‘Working Towards a Cleaner Environment’, Waste Processing, Transportation, Storage and Disposal, Technical Programs and Public Education, Proc. of the Symposium, 2. Tucson, AZ, USA, 1990, pp. 771–778.
4. F.A. Lifanov, M.I. Ojovan, S.V. Stefanovsky, R. Burcl, in: R. Finch, D. Bullen (Eds.), Proc. of the Scientific Basis for Nuclear Waste Management XXVI, vol. 757, 2003.10.1557/PROC-757-II5.13 ↗
5. Naline · Nucl. Eng. Int. · 2011 · 56 · 13
6. S. Robert, F.G. Guilbert, B. Carpentier, S. Naline, F. Gouyaud, C. Girold, in: Proc. of the 13th International Conference on Environmental Remediation and Radioactive, Waste Management, vol. 2, 2011, pp. 399–406.10.1115/ICEM2010-40188 ↗
7. I.A. Sobolev, S.A. Dmitriev, F.A. Lifanov, S.V. Stefanovsky, A.P. Kobelev, V.N. Kornev, M.I. Ojovan, Experience of Sia “Radon” in radioactive waste vitrification, in: Topseal ‘96-International Topical Meeting: Demonstrating the Practical Achievements of Nuclear Waste Management and Disposal, vol. I, 1996, pp. 21–24.
8. Caurant · J. Am. Ceram. Soc · 2007 · 90 · 77410.1111/j.1551-2916.2006.01467.x ↗
9. Crum · J. Am. Ceram. Soc. · 2012 · 95 · 129710.1111/j.1551-2916.2012.05089.x ↗
10. Caurant · J. Nucl. Mater. · 2006 · 354 · 14310.1016/j.jnucmat.2006.03.014 ↗
11. Henry · J. Non-Cryst. Solids · 2004 · 333 · 19910.1016/j.jnoncrysol.2003.09.055 ↗
12. Short · J. Nucl. Mater. · 2005 · 340 · 17910.1016/j.jnucmat.2004.11.008 ↗
13. J.V. Crum, B.J. Riley, L.R. Turo, M. Tang, A. Kossoy, Summary Report: Glass-Ceramic Waste Forms for Combined Fission Products, FCRD-WAST-2011-000358, Pacific Northwest National Laboratory, Richland, Washington, 2011.10.2172/1031436 ↗
14. J.V. Crum, L.R. Turo, B.J. Riley, M. Tang, A. Kossoy, K.E. Sickafus, Glass Ceramic Waste Forms for Combined CS+LN+TM Fission Products Waste Streams, FCRD-WAST-2010-000181, Pacific Northwest National Lab, Richland, Washington, 2010.10.2172/1048015 ↗
15. J.V. Ryan, E.C. Buck, J. Chun, J.V. Crum, B.J. Riley, D.M. Strachan, S.K. Sundaram, L.A. Turo, J.V. Vienna, Alternate Waste Forms: Aqueous Processing, AFCI-WAST-PMO-MI-DV-2009-000360, Pacific Northwest National Laboratory, Richland, Washington, 2009.
16. Brinkman · J. Alloy Compd. · 2013 · 551 · 13610.1016/j.jallcom.2012.09.049 ↗
17. J.C. Marra, K.M. Fox, D.K. Peeler, T.B. Edwards, J.D.V. Gillam Jr., A.L. Youchak, J.H. Gillam Jr., J.D. Vienna, S.V. Stefanovsky, A.S. Aloy, in: W.E. Lee, J.W. Roberts, N.C. Hyatt, R.W. Grimes (Eds.), Proc. of the Scientific Basis for Nuclear Waste Management XXXI, 1107, Materials Research Society, Warrendale, PA, USA, 2007, pp. 231–238.10.1557/PROC-1107-231 ↗
18. J.V. Crum, A.L. Billings, J. Lang, J.C. Marra, C. Rodriguez, J.V. Ryan, J.D. Vienna, Baseline Glass Development for Combined Fission Products Waste Streams, AFCI-WAST-WAST-MI-DV-2009-000075, Pacific Northwest National Laboratory, Richland, Washington, 2009.10.2172/1048019 ↗
19. B.J. Riley, J.V. Crum, W.C. Buchmiller, B.T. Rieck, M.J. Schweiger, J.D. Vienna, Initial Laboratory-Scale Melter Test Results for Combined Fission Product Waste, AFCI-WAST-PMO-MI-DV-2009-000184, Pacific Northwest National Laboratory, Richland, WA, 2009.10.2172/1019228 ↗
20. L. André, RPP Pilot Melter Prototypic LAW and HLW Canister Glass Fill Test Results Report, TRR-PLT-080, Duratek Inc., Columbia, Maryland, 2004.
21. DOE, Waste Acceptance Product Specifications for Vitrified High Level Waste Forms (WAPS), DOE/EM-0093, Rev 3, US Department of Energy, Office of Environmental Management, Washington, DC, 2012.
22. Crawford · J. Alloy Compd. · 2007 · 444–445 · 56910.1016/j.jallcom.2007.02.164 ↗
23. Standard Practice for Measuring Viscosity of Glass Above the Softening Point, ASTM C 965-94, ASTM International, West Conshohocken, PA, 1994.
24. Crum · J. Am. Ceram. Soc. · 2012 · 95 · 219610.1111/j.1551-2916.2012.05220.x ↗
25. X-ray Power Diffraction Intensity Set for Quantitative Analysis by X-Ray Diffraction, SRM-674b, National Institute of Standards and Technology, Department of Commerce, Gaithersburg, MD, 2007.
26. Cheary · J. Res. Natl. Inst. Stand. Technol. · 2004 · 109 · 110.6028/jres.109.002 ↗
27. P.R. Hrma, G.F. Piepel, M.J. Schweiger, D.E. Smith, D.S. Kim, P.E. Redgate, J.D. Vienna, C.A. Lopresti, D.B. Simpson, D.K. Peeler, M.H. Langowski, Property/Composition Relationships for Hanford High-Level Waste Glasses Melting at 1150°C Volume 2: Chapters 12–16 and Appendices A-K, PNNL-10359, Pacific Northwest National Laboratory, Richland, Washington, 1994.10.2172/10121752 ↗
28. Bingham · Stand. Bull. · 1916 · 13 · 30910.6028/bulletin.304 ↗
29. Fahey · J. Solid State Chem. · 1985 · 60 · 14510.1016/0022-4596(85)90106-9 ↗
30. Hazen · J. Phys. Chem. Solids · 1985 · 46 · 25310.1016/0022-3697(85)90039-3 ↗
31. Yashima · Phys. Rev. B: Condens. Matter · 1995 · 51 · 801810.1103/PhysRevB.51.8018 ↗
32. Chi · Jiegou Huaxue · 1998 · 17 · 297
33. Cotton · Inorg. Chem. · 1966 · 5 · 31710.1021/ic50036a037 ↗
34. J.D. Vienna, J.V. Crum, G.J. Sevigny, G.L. Smith, Preliminary Technology Maturation Plan for Immobilization of High-Level Waste in Glass-Ceramics, FCRD-SWF-2012-000152, Richland, WA, 2012.10.2172/1060140 ↗