journal article·2022-08Open access

Tungsten–tantalum alloys for fusion reactor applications

Shuhei Nogami, Itsuki Ozawa, Daisuke Asami, Naoya Matsuta, Seiji Nakabayashi, Siegfried Baumgärtner, Philipp Lied, Kiyohiro Yabuuchi, Takeshi Miyazawa, Yuta Kikuchi, Marius Wirtz, Michael Rieth, Akira Hasegawa

Abstract

Tungsten–tantalum (W-Ta) alloys containing 1–5%Ta were developed for fusion reactor applications. For the mechanical properties and resistance against recrystallization in the non-irradiated state, Ta-alloying improved the performance of W. Grain refining and solute Ta improved the recrystallization temperature and strength. In addition, W-1%Ta exhibited a superior ductility, including ductile-to-brittle transition temperature (DBTT), which might be attributed to the strength of sub-grain boundary. Proton irradiation study at 1500 °C to 0.5 dpa revealed a decrease in irradiation hardening (increase in hardness) in recrystallized specimens and a decrease in hardness reduction in as-received specimens with increasing Ta concentration. With respect to the high temperature irradiation of the as-received specimens, microstructural recovery followed by recrystallization could be one of the dominant factors affecting the hardness change. As a material performance required for the actual components of fusion reactors, resistance against high heat flux exposure have been studied through thermal shock tests. Thorough this experiment, it was clarified that the degradation by high heat flux exposure could be suppressed due to Ta-alloying.
Source: expertdata · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Fusion materials and technologies · Advanced materials and composites · Nuclear Materials and Properties

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (100+)

Show source-provided references
1. Brittle fracture and the brittle-to-ductile transition of tungsten10.1016/j.jnucmat.2003.08.009 ↗
2. Fracture toughness investigations of tungsten alloys and SPD tungsten alloys10.1016/j.jnucmat.2007.03.079 ↗
3. An empirical correlation between temperature and activation energy for brittle-to-ductile transitions in single-phase materials10.1088/0031-8949/2007/T128/017 ↗
4. Strain-rate dependence of the brittle-to-ductile transition temperature in tungsten10.1080/14786430701253197 ↗
5. Experimental investigation of the fracture toughness of polycrystalline tungsten in the brittle and semi-brittle regime10.1016/j.jnucmat.2008.12.184 ↗
6. Fracture toughness and microstructural characterization of polycrystalline rolled tungsten10.1016/j.ijrmhm.2010.05.006 ↗
7. Anisotropic fracture behaviour and brittle to ductile transition of polycrystalline tungsten10.1080/14786435.2010.504198 ↗
8. Loading rate dependence of the fracture toughness of polycrystalline tungsten10.1016/j.jnucmat.2010.12.118 ↗
9. Fracture behaviour of polycrystalline tungsten10.1016/j.jnucmat.2013.11.001 ↗
10. Evaluating the crack resistance of tungsten at high temperatures10.1007/BF00770141 ↗
11. Recrystallization and embrittlement of sintered tungsten10.1007/BF00802116 ↗
12. Effect of recrystallization on the fracture toughness of tungsten10.1007/BF00795612 ↗
13. High-temperature embrittlement of tungsten10.1007/BF01523215 ↗
14. Comparison of microstructure with mechanical properties of irradiated tungsten10.1016/0022-3115(67)90005-0 ↗
15. Effects of neutron irradiation on properties of refractory metals10.1016/0022-3115(92)90799-Q ↗
16. Tensile properties of neutron irradiated TZM and tungsten10.1016/0022-3115(76)90112-4 ↗
17. Influence of fast neutron fluence on the DBTT of W, W10Re, and W3.4Ni1.6Fe
18. Recrystallization, grain growth and the ductile-brittle transition in tungsten sheet10.1016/0022-5088(67)90177-4 ↗
19. Effect of low-temperature rolling on the tensile behavior of commercially pure tungsten10.1016/j.msea.2008.01.013 ↗
20. Solution softening mechanism of iridium and rhenium in tungsten at room temperature10.1016/0263-4368(91)90028-M ↗
21. Development of tungsten-based vacuum melted and powder structural alloys10.1016/S0263-4368(02)00030-6 ↗
22. 100 years of doped tungsten wire10.1016/j.ijrmhm.2010.05.003 ↗
23. The alloys of rhenium with molybdenum or with tungsten and having good high temperature properties
24. Dislocation-core symmetry and slip planes in tungsten alloys: ab initio calculations and microcantilever bending experiments10.1016/j.actamat.2011.10.031 ↗
25. Effect of rhenium on the dislocation core structure in tungsten10.1103/PhysRevLett.104.195503 ↗
26. High-temperature properties of particle-strengthened W-Re10.1007/BF03221045 ↗
27. Properties of tungsten-rhenium and tungsten-rhenium with hafnium carbide10.1007/s11837-009-0107-6 ↗
28. Achieving high strength/ductility in bulk W-Zr-Y2O3 alloy plate with hybrid microstructure10.1016/j.matdes.2016.06.012 ↗
29. Tensile properties at elevated temperature of W-1%La2O310.1016/0921-5093(96)10377-4 ↗
30. Deformation behavior and strengthening mechanisms at intermediate temperatures in W-1%La2O310.1016/S0921-5093(97)00420-6 ↗
31. Development of re-crystallized W–1.1%TiC with enhanced room-temperature ductility and radiation performance10.1016/j.jnucmat.2009.10.015 ↗
32. Development of advanced materials for spallation neutron sources and radiation damage simulation based on multi-scale models10.1016/j.jnucmat.2011.11.023 ↗
33. Effect of hot rolling and annealing on the mechanical properties and thermal conductivity of W-0.5wt.% TaC alloys10.1016/j.ijrmhm.2015.12.004 ↗
34. Extraordinary high ductility/strength of the interface designed bulk W-ZrC alloy plate at relatively low temperature10.1038/srep16014 ↗
35. On the short time creep rupture properties of lamp wire10.1007/BF02648706 ↗
36. The high temperature creep behavior of doped tungsten wire10.1007/BF02649840 ↗
37. The recrystallization of commercially pure and doped tungsten wire drawn to high strain10.1007/BF02658299 ↗
38. Anisotropy in the mechanical properties of potassium and rhenium doped tungsten alloy plates for fusion reactor applications10.13182/FST14-998 ↗
39. Effects of temperature and strain rate on the tensile properties of potassium-doped tungsten10.1016/j.jnucmat.2015.03.015 ↗
40. Effect of microstructural anisotropy on the mechanical properties of K-doped tungsten rods for plasma facing components10.1016/j.fusengdes.2015.11.024 ↗
41. Tensile and fatigue properties of potassium doped and rhenium containing tungsten rods for fusion reactor applications10.1016/j.fusengdes.2015.11.030 ↗
42. Analysis of the temperature and thermal stress in pure tungsten monoblock during heat loading and the influences of alloying and dispersion strengthening on these responses10.1016/j.fusengdes.2016.04.013 ↗
43. Strain rate dependence of tensile properties of tungsten alloys for plasma-facing components in fusion reactors10.1016/j.fusengdes.2015.10.032 ↗
44. Feasibility of utilizing tungsten rod for fusion reactor divertor10.1080/15361055.2017.1347463 ↗
45. Improved structural strength and lifetime of monoblock divertor targets by using doped tungsten alloys under cyclic high heat flux loading10.1088/1402-4896/aa864d ↗
46. A review of impact properties of tungsten materials10.1016/j.fusengdes.2018.08.001 ↗
47. Thermal properties of pure tungsten and its alloys for fusion applications10.1016/j.fusengdes.2018.04.117 ↗
48. Solid state diffusion bonding of doped tungsten alloys with different thermo-mechanical properties10.1016/j.fusengdes.2017.12.036 ↗
49. Improvement of impact properties of tungsten by potassium doping10.1016/j.fusengdes.2019.01.130 ↗
50. Tensile and impact properties of tungsten-rhenium alloy for plasma-facing components in fusion reactor10.1016/j.fusengdes.2019.111323 ↗
51. Tungsten modified by potassium doping and rhenium addition for fusion reactor applications10.1016/j.fusengdes.2019.111445 ↗
52. Thermal shock behavior of potassium doped and rhenium added tungsten alloys10.1088/1402-4896/ab3dcc ↗
53. Mechanical properties of tungsten: recent research on modified tungsten materials in Japan10.1016/j.jnucmat.2020.152506 ↗
54. Ductile to brittle transition temperature of advanced tungsten alloys for nuclear fusion applications deduced by miniaturized three-point bending tests10.1016/j.ijrmhm.2020.105464 ↗
55. Neutron irradiation effects on the mechanical properties of powder metallurgical processed tungsten alloys10.1016/j.jnucmat.2019.151910 ↗
56. Tensile properties of powder-metallurgical-processed tungsten alloys after neutron irradiation near recrystallization temperatures10.1016/j.jnucmat.2020.152505 ↗
57. Neutron irradiation tolerance of potassium-doped and rhenium-alloyed tungsten10.1016/j.jnucmat.2021.153009 ↗
58. Effects of Re content and fabrication process on microstructural changes and hardening in neutron irradiated tungsten10.2320/matertrans.MBW201110 ↗
59. Microstructural development of tungsten and tungsten–rhenium alloys due to neutron irradiation in HFIR10.1016/j.jnucmat.2014.08.002 ↗
60. Neutron energy spectrum influence on irradiation hardening and microstructural development of tungsten10.1016/j.jnucmat.2016.06.051 ↗
61. Effects of transmutation elements on neutron irradiation hardening of tungsten10.2320/matertrans.MAW200722 ↗
62. Precipitation of solid transmutation elements in irradiated tungsten alloys10.2320/matertrans.MAW200821 ↗
63. Effects of transmutation elements on the microstructural evolution and electrical resistivity of neutron-irradiated tungsten10.1016/j.jnucmat.2008.12.091 ↗
64. Property change mechanism in tungsten under neutron irradiation in various reactors10.1016/j.jnucmat.2010.12.114 ↗
65. Neutron irradiation effects on tungsten materials10.1016/j.fusengdes.2014.04.035 ↗
66. Neutron irradiation effects on the microstructural development of tungsten and tungsten alloys10.1016/j.jnucmat.2015.10.047 ↗
67. Effect of neutron irradiation on rhenium cluster formation in tungsten and tungsten-rhenium alloys10.1016/j.jnucmat.2018.04.031 ↗
68. Response of un- alloyed tungsten to mixed spectrum neutrons10.1016/j.jnucmat.2019.03.045 ↗
69. Defect evolution in single crystalline tungsten following low temperature and low dose neutron irradiation10.1016/j.jnucmat.2015.12.040 ↗
70. Irradiation hardening of pure tungsten exposed to neutron irradiation10.1016/j.jnucmat.2016.08.024 ↗
71. Transmutation-induced precipitation in tungsten irradiated with a mixed energy neutron spectrum10.1016/j.actamat.2018.11.032 ↗
72. Microstructural evolution of pure tungsten neutron irradiated with a mixed energy spectrum10.1016/j.jnucmat.2017.04.010 ↗
73. Effect of neutron irradiation on the microstructure of tungsten10.1016/j.nme.2016.09.010 ↗
74. Okamoto · 2016
75. Materials selection for reduced activation of fusion reactors10.1016/0022-3115(88)90375-3 ↗
76. Precipitation sensitivity to alloy composition in Fe-Cr-Mn austenitic steels developed for reduced activation for fusion application
77. The impact of refractory material properties on the helium cooled divertor design10.13182/FST12-1T3 ↗
78. Fracture behaviour of tungsten–vanadium and tungsten–tantalum alloys and composites10.1016/j.jnucmat.2011.04.025 ↗
79. Comparison of hydrogen retention in W and W/Ta alloys10.1016/j.jnucmat.2012.04.003 ↗
80. Development of advanced high heat flux and plasma-facing materials10.1088/1741-4326/aa6f71 ↗
81. Thermal shock behavior under deuterium plasma exposure of tungsten–tantalum alloys10.1088/1402-4896/ac1702 ↗
82. Ion-irradiation induced clustering in W-Re-Ta, W-Re and W-Ta alloys: an atom probe tomography and nanoindentation study10.1016/j.actamat.2016.10.050 ↗
83. Characterisation of radiation damage in W and W-based alloys from 2 MeV self-ion near-bulk implantations10.1016/j.actamat.2015.04.015 ↗
84. Mechanical properties of ion-implanted tungsten–5 wt% tantalum10.1088/0031-8949/2011/T145/014076 ↗
85. Hardening of self ion implanted tungsten and tungsten 5-wt% rhenium10.1016/j.jnucmat.2012.07.044 ↗
86. Thermal evolution of the proton irradiated structure in tungsten-5 wt% tantalum10.1007/s10894-017-0145-y ↗
87. Structural defect accumulation in tungsten and tungsten-5wt.% tantalum under incremental proton damage10.1016/j.jnucmat.2017.11.030 ↗
88. Void evolution in tungsten and tungsten-5wt.% tantalum under in-situ proton irradiation at 800 and 1000°C10.1016/j.jnucmat.2019.07.030 ↗
89. In-situ TEM investigation of nano-scale helium bubble evolution in tantalum-doped tungsten at 800°C10.1016/j.jnucmat.2021.152910 ↗
90. ASTM E112–13, Standard methods for determining the average grain size, Annual Book of ASTM, 2013. https://www.astm.org/e0112-13r21.html.
91. DIN EN ISO 14556:2017-05, Metallische Werkstoffe - Kerbschlagbiegeversuch nach Charpy (V-Kerb) - Instrumentiertes Prüfverfahren (ISO 14556:2015); Deutsche Fassung EN ISO 14556:2015 [in German]. https://www.beuth.de/de/norm/din-en-iso-14556/272602371.
92. The stopping and range of ions in matter
93. ASTM E521-96, Standard practice for neutron radiation damage simulation by charged-particle irradiation, Annual Book of ASTM, 1996. https://www.astm.org/e0521-96.html.
94. Pulse method of measuring thermal diffusivity at high temperatures10.1063/1.1729564 ↗
95. Die konstitution der mischkristalle und die raumfüllung der atome10.1007/BF01349680 ↗
96. Effect of rhenium addition on fracture toughness of tungsten at elevated temperatures10.1007/BF00356341 ↗
97. Fracture toughness of poly-crystalline tungsten alloys10.1016/j.ijrmhm.2010.04.007 ↗
98. Tensile properties of K-doped W–3%Re10.1016/j.fusengdes.2014.02.062 ↗
99. A first report on deformation-mechanism maps10.1016/0001-6160(72)90082-X ↗
100. Tungsten as a structural divertor material10.4028/www.scientific.net/AST.73.11 ↗