journal article·2019-07Open access

Response of unalloyed tungsten to mixed spectrum neutrons

Y. Katoh, L.L. Snead, L.M. Garrison, X. Hu, T. Koyanagi, C.M. Parish, P.D. Edmondson, M. Fukuda, T. Hwang, T. Tanaka, A. Hasegawa

Abstract

Abstract Neutron irradiation in mixed spectrum reactors is an effective approach to investigate the synergistic effects of solid transmutations and atomic displacement damage in tungsten. In this article the findings and interpretations from a large-scale tungsten irradiation campaign conducted using the High Flux Isotope Reactor of Oak Ridge National Laboratory are summarized. The response of originally-unalloyed tungsten to mixed spectrum neutron irradiation is characterized by enormous hardening, degradation of modulus of toughness eventually leading to embrittlement, and decreased thermal conductivity. These property changes may be attributed primarily to production, segregation, and precipitation of rhenium and osmium and assisted by displacement damage. The stages describing the evolution of the microstructural development and property changes with the neutron dose and the accompanying accumulation of transmutation products are proposed. This manuscript has been co-authored by UT-Battelle, LLC under Contract No. DE-AC05-00OR22725 with the U.S. Department of Energy. The United States Government retains and the publisher, by accepting the article for publication, acknowledges that the United States Government retains a non-exclusive, paid-up, irrevocable, worldwide license to publish or reproduce the published form of this manuscript, or allow others to do so, for United States Government purposes. The Department of Energy will provide public access to these results of federally sponsored research in accordance with the DOE Public Access Plan ( http://energy.gov/downloads/doe-public-access-plan ).
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Research context

OpenAlex topics: Fusion materials and technologies · Nuclear Materials and Properties · Nuclear materials and radiation effects

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References (87)

Show source-provided references
1. Recent progress in research on tungsten materials for nuclear fusion applications in Europe10.1016/j.jnucmat.2012.08.018 ↗
2. Recent progress in R&D on tungsten alloys for divertor structural and plasma facing materials10.1016/j.jnucmat.2013.02.074 ↗
3. Materials challenges for the fusion nuclear science facility10.1016/j.fusengdes.2017.07.012 ↗
4. Plasma facing and high heat flux materials - needs for ITER and beyond10.1016/S0022-3115(02)01175-3 ↗
5. Baseline high heat flux and plasma facing materials for fusion10.1088/1741-4326/aa6b60 ↗
6. Use of tungsten material for the ITER divertor10.1016/j.nme.2016.07.003 ↗
7. Radiation effects in refractory alloys
8. Swelling in neutron irradiated tungsten and tungsten-25 percent rhenium10.1016/0036-9748(74)90304-4 ↗
9. Neutron irradiation effects on tungsten materials10.1016/j.fusengdes.2014.04.035 ↗
10. Voids in irradiated tungsten and molybdenum10.1016/0022-3115(69)90029-4 ↗
11. Effects of Re content and fabrication process on microstructural changes and hardening in neutron irradiated tungsten10.2320/matertrans.MBW201110 ↗
12. Annealing of defect clusters in irradiated tungsten10.1080/00337577108231014 ↗
13. Leonard · 2012
14. Effects of irradiation on properties of refractory alloys with emphasis on space power reactor applications
15. Tungsten as a plasma-facing material10.1016/B978-0-08-056033-5.00118-X ↗
16. Effect of neutron irradiation on thermal diffusivity of tungsten- rhenium alloys10.1016/S0022-3115(00)00170-7 ↗
17. Post irradiation testing of samples from the irradiation experiments PARIDE 3 and PARIDE 410.1016/j.jnucmat.2004.04.176 ↗
18. Krautwasser · 1990 · vol. 22 · 25
19. Neutron irradiation effects on plasma facing materials10.1016/S0022-3115(00)00203-8 ↗
20. Effects of neutron irradiation on properties of refractory metals10.1016/0022-3115(92)90799-Q ↗
21. Tensile properties of neutron irradiated TZM and tungsten10.1016/0022-3115(76)90112-4 ↗
22. Radiation damage problems in high power spallation neutron sources10.1016/0168-583X(95)00590-0 ↗
23. Operating temperature windows for fusion reactor structural materials10.1016/S0920-3796(00)00320-3 ↗
24. Assessment of tungsten for use in the ITER plasma facing components10.1016/S0022-3115(98)00285-2 ↗
25. Recrystallization behavior of hot-rolled pure tungsten and its alloy plates during high-temperature annealing10.1016/j.nme.2018.04.004 ↗
26. Transmutation of tungsten in fusion and fission nuclear environments10.13182/FST13-717 ↗
27. Spatial heterogeneity of tungsten transmutation in a fusion device10.1088/1741-4326/aa5e2e ↗
28. Irradiation hardening in pure tungsten before and after recrystallization10.1016/j.fusengdes.2015.06.192 ↗
29. Hardening of self ion implanted tungsten and tungsten 5-wt% rhenium10.1016/j.jnucmat.2012.07.044 ↗
30. Klopp · 1966
31. Identification of a beta tungsten phase in tungsten-rhenium alloys10.1038/205587b0 ↗
32. Neutron irradiation behavior of tungsten10.2320/matertrans.MG201208 ↗
33. Microstructural development of tungsten and tungsten-rhenium alloys due to neutron irradiation in HFIR10.1016/j.jnucmat.2014.08.002 ↗
34. Neutron energy spectrum influence on irradiation hardening and microstructural development of tungsten10.1016/j.jnucmat.2016.06.051 ↗
35. Microstructural evolution of pure tungsten neutron irradiated with a mixed energy spectrum10.1016/j.jnucmat.2017.04.010 ↗
36. Neutron irradiation effects on the microstructural development of tungsten and tungsten alloys10.1016/j.jnucmat.2015.10.047 ↗
37. Irradiation hardening of pure tungsten exposed to neutron irradiation10.1016/j.jnucmat.2016.08.024 ↗
38. Defect evolution in single crystalline tungsten following low temperature and low dose neutron irradiation10.1016/j.jnucmat.2015.12.040 ↗
39. Viewpoint: Nanoscale chemistry and crystallography are both the obstacle and pathway to advanced radiation-tolerant materials10.1016/j.scriptamat.2017.05.014 ↗
40. Irradiation effects in tungsten-copper laminate composite10.1016/j.jnucmat.2016.09.020 ↗
41. Mechanical properties of single crystal tungsten irradiated in a mixed spectrum fission reactor10.1016/j.jnucmat.2019.02.050 ↗
42. Anisotropy in the mechanical properties of potassium and rhenium doped tungsten alloy plates for fusion reactor application10.13182/FST14-998 ↗
43. Damage parameters of structural materials in fusion environment compared to fission reactor irradiation10.1016/j.fusengdes.2012.01.022 ↗
44. Method for analyzing passive silicon carbide thermometry with a continuous dilatometer to determine irradiation temperature10.1016/j.nimb.2016.01.005 ↗
45. FISPACT-2005: user manual
46. Mahmood · 1995
47. X-5 Monte Carlo Team · 2003
48. Atom probe characterization of precipitates in neutron-irradiated tungsten
49. Microstructural development and radiation hardening of neutron irradiated Mo-Re alloys10.1016/j.jnucmat.2003.09.007 ↗
50. Simulating irradiation hardening in tungsten under fast neutron irradiation including Re production by transmutation10.1016/j.jnucmat.2017.11.026 ↗
51. Effects of neutron irradiation on properties of refractory metals10.1016/0022-3115(92)90799-Q ↗
52. Tungsten foil laminate for structural divertor applications - joining of tungsten foils10.1016/j.jnucmat.2013.01.295 ↗
53. Cleavage anisotropy in tungsten single crystals10.1103/PhysRevLett.76.3594 ↗
54. Dose dependence of mechanical properties in tantalum and tantalum alloys after low temperature irradiation10.1016/j.jnucmat.2008.02.034 ↗
55. ASTM C1275-18, Standard Test Method for Monotonic Tensile Behavior of Continuous Fiber-Reinforced Advanced Ceramics with Solid Rectangular Cross-Section Test Specimens at Ambient Temperature, West Conshohocken, PA, (n.d).
56. Overview of recent European materials R&D activities related to ITER10.1016/j.jnucmat.2004.04.008 ↗
57. Temperature dependence of thermal conductivity in W and W-Re alloys from 300 to 1000 K10.1016/S0167-577X(02)01403-9 ↗
58. Development of tungsten armor and bonding to copper for plasma-interactive components10.1016/S0022-3115(98)00358-4 ↗
59. Effects of transmutation elements on the microstructural evolution and electrical resistivity of neutron-irradiated tungsten10.1016/j.jnucmat.2008.12.091 ↗
60. Irradiation induced precipitation in tungsten based, W-Re alloys10.1007/BF02643781 ↗
61. Thermal conductivity degradation and recovery in ion beam damaged tungsten at different temperature10.1016/j.jnucmat.2018.09.002 ↗
62. Effect of the variation of the electronic density of states of zirconium and tungsten on their respective thermal conductivity evolution with temperature10.1088/0953-8984/27/16/165501 ↗
63. Thermal conductivity of tungsten: effects of plasma-related structural defects from molecular-dynamics simulations10.1063/1.4986956 ↗
64. Calculation and analysis of lattice thermal conductivity in tungsten by molecular dynamics10.1016/j.jnucmat.2012.05.015 ↗
65. Effect of neutron irradiation on the microstructure of tungsten10.1016/j.nme.2016.09.010 ↗
66. Analysis of neutron irradiated tungsten microstructures
67. Radiation-induced precipitation in fast-neutron irradiated tungsten-rhenium alloys: an atom-probe field-ion microscope study10.1016/0168-583X(85)90544-0 ↗
68. Characterisation of radiation damage in W and W-based alloys from 2 MeV self-ion near-bulk implantations10.1016/j.actamat.2015.04.015 ↗
69. Investigation of the combined effect of neutron irradiation and electron beam exposure on pure tungsten10.1016/j.jnucmat.2016.05.008 ↗
70. “Rafting” in neutron irradiated tungsten10.1016/0022-3115(73)90139-6 ↗
71. Displacement cascades and defects annealing in tungsten, Part I: defect database from molecular dynamics simulations10.1016/j.jnucmat.2014.12.056 ↗
72. Low temperature neutron irradiation effects on microstructure and tensile properties of molybdenum10.1016/j.jnucmat.2007.12.001 ↗
73. Transmutation-induced precipitation in tungsten irradiated with A mixed energy neutron spectrum10.1016/j.actamat.2018.11.032 ↗
74. Radiation damage and stage iii defect annealing in thermal neutron irradiated tungsten10.1016/0001-6160(78)90165-7 ↗
75. Primary damage in tungsten using the binary collision approximation, molecular dynamic simulations and the density functional theory10.1088/0031-8949/T167/1/014018 ↗
76. Radiation damage production in massive cascades initiated by fusion neutrons in tungsten10.1016/j.jnucmat.2014.06.007 ↗
77. Mechanism of Re precipitation in irradiated W-Re alloys from kinetic Monte Carlo simulations10.1103/PhysRevB.96.094108 ↗
78. Microstructure of neutron-irradiated iron before and after tensile deformation10.1016/j.jnucmat.2006.02.031 ↗
79. Defect cluster formation and radiation hardening in molybdenum neutron-irradiated at 80 °C10.1016/j.jnucmat.2007.03.049 ↗
80. Microstructural evolution and hardening of neutron irradiated vanadium alloys at low temperatures in Japan material testing reactor10.1016/S0022-3115(98)00716-8 ↗
81. Viewpoint: nanoscale chemistry and crystallography are both the obstacle and pathway to advanced radiation-tolerant materials10.1016/j.scriptamat.2017.05.014 ↗
82. Applications of combined transmission kikuchi diffraction and STEM-SDD X-ray analysis in irradiated materials10.1017/S1431927618004178 ↗
83. Stability and mobility of rhenium and osmium in tungsten: first principles study10.1088/0965-0393/22/7/075006 ↗
84. The role of interstitial binding in radiation induced segregation in W-Re alloys10.1063/1.4956377 ↗
85. A first-principles model for anomalous segregation in dilute ternary tungsten-rhenium-vacancy alloys10.1088/1361-648X/aa5f37 ↗
86. Ion-irradiation-induced clustering in W-Re and W-Re-Os alloys: a comparative study using atom probe tomography and nanoindentation measurements10.1016/j.actamat.2014.12.049 ↗
87. Simulation of neutron irradiation damage in tungsten using higher energy protons10.1016/j.nme.2016.09.008 ↗