Microstructural changes in AISI 304L stainless steel due to surface machining: Effect on its susceptibility to chloride stress corrosion cracking

Abstract This study aims to understand the mechanism of increased SCC susceptibility of machined 304L stainless steel in chloride environment. Austenitic stainless steel grade 304L was surface machined up to a depth of 0.5 mm from the surface. In depth characterization was carried out by optical, scanning electron microscopic technique, hardness measurement and by EBSD and XRD studies. The stress corrosion cracking (SCC) susceptibility was estimated by exposing constant strained samples made up of machined and unmachined stainless steel to 5 M H2SO4 + 0.5 M NaCl solution at room temperature (28 °C) until cracking. In addition strips of machined and unmachined stainless steel were exposed to boiling MgCl2 solution as per ASTM G36 to understand the effect of residual stress and strain generated due to machining on the SCC susceptibility. The study reveals that surface machining results in extensive grain refinement, strain induced martensite transformation and high magnitude of plastic deformation near the surface.