journal article·2011-12Open access

Thermodynamic modelling of advanced oxide and carbide nuclear fuels: Description of the U–Pu–O–C systems

Christine Guéneau, Nathalie Dupin, Bo Sundman, Chantal Martial, Jean-Christophe Dumas, Stéphane Gossé, Sylvie Chatain, Franck De Bruycker, Dario Manara, Rudy J.M. Konings

Journal of Nuclear Materials· Volume 419· Issue 1-3

Abstract

Abstract In the present work a thermodynamic model is derived for the (U, Pu)O 2 oxide, the (U, Pu)C carbide fuels using the Calphad method to describe consistently both phase diagrams and thermodynamic data of the phases involved in the U–Pu–O–C system. All the available thermodynamic and phase diagram data of the binary and ternary sub-systems are very well reproduced by our model. For the quaternary system, the calculated phase equilibria in the U 0.3 Pu 0.7 –C–O region are in good agreement with the experimental data.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Nuclear Materials and Properties · Nuclear reactor physics and engineering · Radioactive element chemistry and processing

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (100+)

Show source-provided references
1. Olander · J. Nucl. Mater. · 2009 · 389 · 110.1016/j.jnucmat.2009.01.297 ↗
2. Guéneau · J. Nucl. Mater. · 2002 · 304 · 16110.1016/S0022-3115(02)00878-4 ↗
3. Guéneau · J. Nucl. Mater. · 2005 · 344 · 19110.1016/j.jnucmat.2005.04.041 ↗
4. C. Guéneau, S. Chatain, J.C. Dumas, J. Lechelle, C. Rado, F. Defoort, N. Dupin, B. Sundman, H. Noel, R. Konings, in: Proceedings of HTR 2006 Conference, 1–4 October 2006, Sandton, South of Africa.
5. Guéneau · J. Nucl. Mater. · 2008 · 378 · 25710.1016/j.jnucmat.2008.06.013 ↗
6. C. Guéneau, S. Gossé, S. Chatain, C. Utton, N. Dupin, B. Sundman, C. Martial, J.C. Dumas, C. Rado, .
7. Berche · J. Nucl. Mater. · 2009 · 389 · 10110.1016/j.jnucmat.2009.01.014 ↗
8. Berche · J. Chem. Thermodyn. · 2011 · 43 · 45810.1016/j.jct.2010.10.023 ↗
9. Berche · J. Nucl. Mater. · 2011 · 411 · 13110.1016/j.jnucmat.2011.01.043 ↗
10. Potter · J. Nucl. Mater. · 1972 · 42 · 110.1016/0022-3115(72)90002-5 ↗
11. Antonysamy · J. Nucl. Mater. · 1995 · 223 · 2010.1016/0022-3115(94)00691-1 ↗
12. S. Anthonysamy, Oral Presentation at the International Exchange Meeting on Thermodynamics of Nuclear Fuels, Saclay, 2006.
13. R. Agarwal, V. Venugopal, D.D. Sood, Fuel Chemistry Division, BARC, Report BARC/1992/E022, 1992.
14. Jain · J. Nucl. Mater. · 1993 · 207 · 16910.1016/0022-3115(93)90259-2 ↗
15. Lukas · 2007
16. Devanathan · Energy Environ. Sci. · 2010 · 3 · 140610.1039/c0ee00028k ↗
17. Sundman · Calphad · 1985 · 9 · 15310.1016/0364-5916(85)90021-5 ↗
18. Dinsdale · Calphad · 1991 · 15 · 31710.1016/0364-5916(91)90030-N ↗
19. Kurata · Calphad · 1999 · 23 · 30510.1016/S0364-5916(00)00004-3 ↗
20. SGTE Substances Database Version, .
21. R.J.M. Konings, O. Benes, D. Manara, D. Sedmidubsky, L. Gorokhov, V.S. Iorish, The thermodynamic properties of f-elements. Part II. The lanthanide and actinide oxides, J. Phys. Chem. Ref. Data, submitted for publication.
22. Gotcu-Freis · J. Chem. Thermodyn. · 2011 · 43 · 49210.1016/j.jct.2010.10.027 ↗
23. Gotcu-Freis · J. Nucl. Mater. · 2011 · 414 · 40810.1016/j.jnucmat.2011.05.014 ↗
24. Hillert · J. Agren. Metall. Trans. A · 1985 · 16 · 66110.1007/BF02814240 ↗
25. Hallsted · Calphad · 1994 · 18 · 3110.1016/0364-5916(94)90005-1 ↗
26. Sundman · J. Phys. Chem. Solids · 1981 · 42 · 29710.1016/0022-3697(81)90144-X ↗
27. Park · High Temp. Sci. · 1990 · 29 · 203
28. Yakub · J. Nucl. Mater. · 2009 · 389 · 11910.1016/j.jnucmat.2009.01.029 ↗
29. Grundy · J. Phase Equilib. Diff. · 2005 · 26 · 13110.1007/s11669-005-0132-2 ↗
30. F. De Bruycker, Thesis, Orléans, France, December 2010.
31. De Bruycker · Mater. Today · 2010 · 13 · 5210.1016/S1369-7021(10)70204-2 ↗
32. Bowman · Acta Crystallogr. · 1966 · 21 · 67010.1107/S0365110X66003670 ↗
33. Chevalier · J. Nucl. Mater. · 2001 · 288 · 10010.1016/S0022-3115(00)00713-3 ↗
34. Harper · Nature · 1968 · 219 · 15110.1038/219151a0 ↗
35. D. Labroche, PhD thesis, INPG Grenoble, 2000.
36. Labroche · J. Nucl. Mater. · 2003 · 312 · 2110.1016/S0022-3115(02)01322-3 ↗
37. Labroche · J. Nucl. Mater. · 2003 · 312 · 5010.1016/S0022-3115(02)01323-5 ↗
38. M. Baichi, PhD thesis, INPG Grenoble, 2001.
39. Baichi · J. Nucl. Mater. · 2006 · 349 · 1710.1016/j.jnucmat.2005.09.001 ↗
40. Baichi · J. Nucl. Mater. · 2006 · 349 · 5710.1016/j.jnucmat.2005.10.001 ↗
41. Manara · J. Nucl. Mater. · 2005 · 342 · 14810.1016/j.jnucmat.2005.04.002 ↗
42. Schoenes · J. Appl. Phys. · 1978 · 49 · 146310.1063/1.324978 ↗
43. Matzke · J. Chem. Soc. Faraday Trans. · 1987 · 2 · 83
44. Ronchi · J. Alloys Compd. · 1994 · 213–214 · 15910.1016/0925-8388(94)90897-4 ↗
45. Fink · J. Nucl. Mater. · 2000 · 279 · 110.1016/S0022-3115(99)00273-1 ↗
46. R.J.M. Konings, in: L.R. Morss, N.M. Edelstein, J. Fuger (Eds.), The Chemistry of the Actinide and Transactinide Elements, third ed., vol. 4, Springer, 2006 (Chapter 19).
47. Kato · J. Alloys Compd. · 2008 · 452 · 4810.1016/j.jallcom.2007.01.183 ↗
48. Kato · J. Nucl. Mater. · 2008 · 373 · 23710.1016/j.jnucmat.2007.06.002 ↗
49. M. Kato, in: Proceedings of ICAPP 09, Tokyo, Japan, May 10–14, 2009, Paper 9451.
50. E.A. Aitken, S.K. Evans, USAEC, General Electric, Vallecitos Nucleonics Lab., Rep. GEAP-5672, 1968.
51. Chikalla · J. Nucl. Mater. · 1964 · 12 · 13110.1016/0022-3115(64)90132-1 ↗
52. Boivineau · J. Nucl. Mater. · 1976 · 60 · 3110.1016/0022-3115(76)90114-8 ↗
53. C. Sari, U. Benedict, H. Blank, Thermodynamics of Nuclear Materials, 1967, IAEA, Vienna, 1968, pp. 587–611.
54. Gardner · J. Inorg. Nucl. Chem. · 1965 · 27 · 54110.1016/0022-1902(65)80259-7 ↗
55. Besmann · J. Nucl. Mater. · 1987 · 144 · 14110.1016/0022-3115(87)90289-3 ↗
56. Messier · J. Am. Ceram. Soc. · 1968 · 51 · 71010.1111/j.1151-2916.1968.tb15933.x ↗
57. R.W. Ohse, C. Ciani, Thermodynamics of Nuclear Materials, 1967, IAEA, Vienna, 1968, pp. 545–557.
58. Riley · Sci. Ceram. · 1970 · 5 · 83
59. L.E. Russel, in: E. Grison, W.B.H. Lord, R.D. Fowler (Eds.), Plutonium 1960, Cleaver-Hume, London, 1961, pp. 489–492.
60. Utton · J. Nucl. Mater. · 2009 · 385 · 44310.1016/j.jnucmat.2008.12.031 ↗
61. P. Guinet, H. Vaugoyeau, P.L. Blum, CR Acad. Sci. Paris t.261 (2 aout 1965), Groupe 7, p. 1312.
62. B. Blumenthal, J. Nucl. Mater. 2(3) (1960) 197; ANL-6099 (1959) 72; TID-7523, p 1 (1956) 65.
63. T.H. Carter, Report CT 609, USAEC, Technical Information Services, Washington, DC, 1943.
64. E.K. Storms, Los Alamos Sci. Lab. Rept. LA-DC-6953, 1965.
65. Laugier · J. Nucl. Mater. · 1971 · 39 · 24510.1016/0022-3115(71)90143-7 ↗
66. T.B. Massalski and others, Binary Alloy Phase Diagrams, ASM, 1990.
67. Benz · High Temp. Sci. · 1969 · 1 · 342
68. Affortit · J. Nucl. Mater. · 1970 · 34 · 10510.1016/0022-3115(70)90014-0 ↗
69. High temperature properties of uranium carbide
70. Oetting · J. Nucl. Mater. · 1973 · 45 · 27110.1016/0022-3115(73)90161-X ↗
71. Levinson · J. Chem. Phys. · 1963 · 38 · 210510.1063/1.1733939 ↗
72. Moser · J. Appl. Phys. · 1967 · 38 · 321510.1063/1.1710092 ↗
73. Hultgren · 1973
74. Mallett · J. Electrochem. Soc. · 1952 · 98 · 50510.1149/1.2778032 ↗
75. Chiotti · J. Am. Ceram. Soc. · 1952 · 35 · 12310.1111/j.1151-2916.1952.tb13084.x ↗
76. Wilson · J. Am. Ceram. Soc. · 1960 · 43 · 7710.1111/j.1151-2916.1960.tb13644.x ↗
77. Chubb · Trans. ASM · 1961 · 53 · 465
78. Sears · J. Electrochem. Soc. · 1966 · 113 · 26910.1149/1.2423930 ↗
79. MacLeod · J. Inorg. Nucl. Chem. · 1969 · 31 · 71510.1016/0022-1902(69)80018-7 ↗
80. Leitnaker · J. Nucl. Mater. · 1967 · 21 · 17510.1016/0022-3115(67)90148-1 ↗
81. Akhachinski · Atom. Energy · 1970 · 29 · 439
82. M.C. Krupka, Unpublished Information, Los Alamos Scientific Laboratory.
83. Fischer · Comput. Coup. Phase Diag. Thermochem. · 2008 · 32 · 37110.1016/j.calphad.2007.12.004 ↗
84. J.G. Reavis, L. Reese, Differential thermal analysis. Transformations in the Pu–C system, in: Quarterly Status Report on the Advanced Plutonium Fuels Program, July 1 to September 30 (1969) LA-4307-MS, Los Alamos Scientific Laboratory, Los Alamos, NM, 1969, 9 pp.
85. J.G. Reavis, L. Reese, LA-4437-MS, Los Alamos Scientific Laboratory, Los Alamos, NM, 1970, 20–21 pp.
86. R.N.R. Mulford, F.H. Ellinger, G.S. Hendrix, E.D. Albrecht, Plutonium 1960, Cleaver Hume, London, 1961, pp. 301–331.
87. Fischer · Calphad · 2009 · 33 · 48710.1016/j.calphad.2009.01.004 ↗
88. Oetting · J. Nucl. Mater. · 1980 · 88 · 26510.1016/0022-3115(80)90282-2 ↗
89. Kruger · J. Chem. Phys. · 1964 · 40 · 332410.1063/1.1725001 ↗
90. C.E. Holley, M.H. Rand, E.K. Storms, 6.6. Plutonium–Carbon System, The Actinide Carbides, IAEA, Vienna, 1984, pp. 53–72.
91. Lorenzelli · J. Inorg. Nucl. Chem. · 1971 · 33 · 329710.1016/0022-1902(71)80650-4 ↗
92. Johnson · J. Chem. Thermodyn. · 1974 · 6 · 21910.1016/0021-9614(74)90173-6 ↗
93. C. Chatillon, C. Guéneau, in preparation.
94. K.A. Johnson, LA-3191-MS, Los Alamos Scientific Laboratory, Los Alamos, NM, 1965, 16 pp.
95. M.H. Rand, R.S. Street, Anomalous thermal expansions in the plutonium monocarbide region, in: L.E. Russell, B.T. Bradbury, J.D.L. Harrison, H.J. Hedger, P.G. Mardon (Eds.), Carbides in Nuclear Energy, Physical and Chemical Properties, Phase Diagrams, vol. 1, Macmillan & Co. Ltd., London, 1964, pp. 108–112.
96. Ogard · J. Nucl. Mater. · 1965 · 15 · 4310.1016/0022-3115(65)90107-8 ↗
97. D.F. Bowersox, J.A. Leary, LAMS-2832, 1963.
98. Bowerbox · J. Nucl. Mater. · 1967 · 21 · 21910.1016/0022-3115(67)90151-1 ↗
99. S. Rosen, M.V. Nevitt, A.W. Mitchell, The U–Pu–C ternary phase diagram below 50 atomic percent carbon, ANL-6435, Argonne National Laboratory, Argonne, Illinois 60440, USA, 1964, 7 pp.10.2172/4018869 ↗
100. Rosen · J. Nucl. Mater. · 1963 · 9 · 12810.1016/0022-3115(63)90128-4 ↗