Radiation tolerance of neutron-irradiated model Fe–Cr–Al alloys

Abstract The Fe–Cr–Al alloy system has the potential to form an important class of enhanced accident-tolerant cladding materials in the nuclear power industry owing to the alloy system's higher oxidation resistance in high-temperature steam environments compared with traditional zirconium-based alloys. However, radiation tolerance of Fe–Cr–Al alloys has not been fully established. In this study, a series of Fe–Cr–Al alloys with 10–18 wt % Cr and 2.9–4.9 wt % Al were neutron irradiated at 382 °C to 1.8 dpa to investigate the irradiation-induced microstructural and mechanical property evolution as a function of alloy composition. Dislocation loops with Burgers vector of a/2〈111〉 and a〈100〉 were detected and quantified. Results indicate precipitation of Cr-rich α′ is primarily dependent on the bulk chromium composition. Mechanical testing of sub-size-irradiated tensile specimens indicates the hardening response seen after irradiation is dependent on the bulk chromium composition. A structure–property relationship was developed; it indicated that the change in yield strength after irradiation is caused by the formation of these radiation-induced defects and is dominated by the large number density of Cr-rich α′ precipitates at sufficiently high chromium contents after irradiation.